Volume 84: High Temperature Gas–Solid Reactions in Earth and Planetary Processes

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Volume 84: High Temperature Gas–Solid Reactions in Earth and Planetary Processes
Penelope L. King, Bruce Fegley, Jr. and Terry Seward, editors

2018, i-xiv + 514 pages. ISBN 978-0-946850-00-3

Gas mixtures play a crucial role in distributing elements between different parts of Earth and planet-forming systems over a range of settings and temperatures. Despite the fundamental role of gases in geochemical cycles and their prevalence both in the crust and the early solar system, we are unaware of any reviews on this topic. This volume arose from an interest in promoting further research into the role of gases in geologic systems on Earth and beyond, with an aim to illuminate the gaps in our knowledge.

We focus on high temperature interactions here because at low temperatures, low density, very low dielectric constant gas mixtures rather loosely 'physisorb' onto natural materials. In contrast, at higher temperatures solids volatilize and condense, lose/gain volatile components and heterogeneous chemisorption reactions occur between gases and solid surfaces. These reactions have previously had very little attention, but recent research has laid foundations for understanding these processes and their application to Earth and planetary environments.

The volume is divided into five main topics:

• 1. Experimental and analytical approaches to characterising gas–solid reactions.
• 2. Modelling approaches to examining gas-solid reactions.
• 3. Terrestrial volcanic systems.
• 4. Planetary systems.
• 5. Industrial processes.

Contents of Volume 84: High Temperature Gas–Solid Reactions in Earth and Planetary Processes

Title Page
p. i

Errata for Title Page as a pdf (Download (84 KB))

Copyright
p. ii

Title
p. iii

Preface & Dedication
p. iv

Table of Contents
p. v-xiv

Chapter 1. Gas–solid reactions: Theory, experiments and case studies relevant to Earth and planetary processes
by Penelope L. King, Vincent W. Wheeler, Christian J. Renggli, Andrew B. Palm, Siobhan A. Wilson, Anna L. Harrison, Bree Morgan, Hanna Nekvasil, Ulrike Troitzsch, Terrence Mernagh, Lindsey Yue, Alicia Bayon, Nicholas J. DiFrancesco, Riley Baile, Peter Kreider, Wojciech Lipiński, p. 1–56

Chapter 2. Molecular clusters and solvation in volcanic and hydrothermal vapors
by Kono H. Lemke and Terry M. Seward, p. 57–83

Chapter 3. Reaction mechanisms and solid–gas phase reactions: Theory and density functional theory simulations
by James D. Kubicki and Heath D. Watts, p. 85–101

Chapter 4. Analytical techniques for probing small-scale layers that preserve information on gas–solid interactions
by Kim N. Dalby, Jeff. A. Berger, Helen E.A. Brand, Julie M. Cairney, Katja Eder, Stephen M. Eggins, Anna Herring, Richard L. Hervig, Peter B. Krieder, Terrence P. Mernagh, Andrew B. Palm, Christian J. Renggli, Ulrike Troitzsch, Lindsey Yue, Penelope L. King, p. 103–175

Chapter 5. Using infrared and Raman spectroscopy to analyze gas–solid reactions
by Terrence P. Mernagh, Penelope L. King, Paul F. McMillan, Jeff. A. Berger, Kim N. Dalby, p. 177–228

Chapter 6. SO2 gas reactions with silicate glasses
by Christian J. Renggli and Penelope L. King, p. 229–255

Chapter 7. Unravelling the consequences of SO2–basalt reactions for geochemical fractionation and mineral formation
by Andrew B. Palm, Penelope L. King, Christian J. Renggli, Richard L. Hervig, Kim N. Dalby, Anna Herring, Terrence P. Mernagh, Stephen M. Eggins, Ulrike Troitzsch, Levi Beeching, Leslie Kinsley, Paul Guagliardo, p. 257–283

Supplemental Data for Chapter 7

Chapter 8. High temperature reactions between gases and ash particles in volcanic eruption plumes
by Pierre Delmelle, Fabian B. Wadsworth, Elena C. Maters, Paul M. Ayris, p. 285–308

Chapter 9. Gas–solid reactions in arc volcanoes: ancient and modern
by Richard W. Henley, Terry M. Seward, p. 309–349

Supplemental Data for Chapter 9
Errata for Chapter 9 as a pdf (Download (84 KB))

Chapter 10. Gas–solid interactions on Venus and other Solar System bodies
by Mikhail Yu. Zolotov, p. 351–392

Chapter 11. Thermodynamics of element volatility and its application to planetary processes
by Paolo A. Sossi, Bruce Fegley, Jr., p. 393–459

Errata for Chapter 11 as a pdf (Download (84 KB))

Chapter 12. Kinetics of gas–solid reactions in the Solar System and beyond
by Hiroko Nagahara, p. 461–497

Chapter 13. High-temperature gas–solid reactions in industrial processes
by Kreider P and Lipiński W, p. 499–514

Supplemental Data for High Temperature Gas–Solid Reactions in Earth and Planetary Processes

Supporting Data Tables for Chapter 7. Unravelling the consequences of SO2–basalt reactions for geochemical fractionation and mineral formation by Andrew B. Palm, Penelope L. King, Christian J. Renggli, Richard L. Hervig, Kim N. Dalby, Anna Herring, Terrence P. Mernagh, Stephen M. Eggins, Ulrike Troitzsch, Levi Beeching, Leslie Kinsley, Paul Guagliardo.

• Analytical Methods. MicroSoft Word file. (32KB)

Supporting Data Tables for Chapter 9. Gas–solid reactions in arc volcanoes: ancient and modern by Richard W. Henley, Terry M. Seward, each a link to a down-loadable Pdf or MicroSoft Excel file.

• Supplement Table 1. Wahrenberger (1997) Compilation of published fumarole gas analyses from Kudryavy Volcano, Russia volcanic gases. (40 KB)
• Supplement 2a. Speciation plots for the Kudryavy 920 °C fumarole gas sample over the range 500–1100°C at 100 kPa. Gas species only. Mol % (140 KB)
• Supplement 2b. Speciation plots for the Kudryavy 920°C fumarole gas sample over the range 500–1100°C at 20 MPa. Gas species only. Mol %(3.2 MB)
• Supplement 2c. Speciation plots for the Kudryavy 920°C fumarole gas sample over the range 500–1100°C at 100 kPa. Gas plus solid species. Mol %. (3.28 MB)
• Supplement 2c. Speciation plots for the Kudryavy 920°C fumarole gas sample over the range 500–1100°C at 20 MPa. Gas plus solid species. Mol %. (3.28 MB)
• Supplement 3a. Database of volcanic gas analyses containing independently analyzed SO2(g) and H2S(g). (xx MB)
• Supplement 3b. Database of Vulcano, Italy, volcanic gas analyses containing independently analyzed SO2(g) and H2S(g). Data kindly compiled by Giovanni Chiodini from his paper (Chiodini et al. 1995). (xx KB)