#======================================================================= data_global _audit_update_record ; 2011-09-18 # Formatted by publCIF ; #======================================================================= _audit_creation_method 'Jana2006 Version : 22/10/2010' # 1. PROCESSING SUMMARY (IUCr Office Use Only) _journal_date_recd_electronic ? _journal_date_to_coeditor ? _journal_date_from_coeditor ? _journal_date_accepted ? _journal_date_printers_first ? _journal_date_printers_final ? _journal_date_proofs_out ? _journal_date_proofs_in ? _journal_coeditor_name ? _journal_coeditor_code ? _journal_coeditor_notes ? _journal_techeditor_code ? _journal_paper_category ? _journal_techeditor_notes ? _journal_coden_ASTM ? _journal_name_full ? _journal_year ? _journal_volume ? _journal_issue ? _journal_page_first ? _journal_page_last ? _journal_suppl_publ_number ? _journal_suppl_publ_pages ? #======================================================================= # 2. SUBMISSION DETAILS _publ_contact_author_name ? _publ_contact_author_address ? _publ_contact_author_email ? _publ_contact_author_fax ? _publ_contact_author_phone ? _publ_requested_journal ? _publ_requested_category ? _publ_contact_letter ? #======================================================================= # 3. TITLE AND AUTHOR LIST _publ_section_title ; Title (type here to add) ; _publ_section_title_footnote . loop_ _publ_author_name _publ_author_footnote _publ_author_address ? # name ; ? # footnote ; ; ? # address ; #======================================================================= # 4. TEXT _publ_section_synopsis . _publ_section_abstract ; (type here to add abstract) ; _publ_section_comment ; (type here to add) ; _publ_section_introduction ? _publ_section_experimental ? _publ_section_exptl_prep ; (type here to add preparation details) ; _publ_section_exptl_refinement ; (type here to add refinement details) ; _publ_section_exptl_solution ? _publ_section_discussion ? _publ_section_acknowledgements ; ? ; _publ_section_references ; (type here to add) ; _publ_section_figure_captions ; ; _publ_section_table_legends ? #======================================================================= data_I _atom_sites_solution_secondary difmap #Added by publCIF _atom_sites_solution_primary direct #Added by publCIF _refine_ls_matrix_type full #Added by publCIF #======================================================================= # 5. CHEMICAL DATA _chemical_name_systematic ? _chemical_name_common ? _chemical_formula_moiety ? _chemical_formula_structural ? _chemical_formula_analytical ? _chemical_formula_iupac ? _chemical_formula_sum 'Cu2.936 O34 S2 U4' _chemical_formula_weight 1746.8 _chemical_melting_point ? _chemical_compound_source ? _chemical_absolute_configuration . #======================================================================= # 6. CRYSTAL DATA _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1' _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_site_id _symmetry_equiv_pos_as_xyz 1 x,y,z 2 -x,-y,-z _cell_length_a 8.6744(4) _cell_length_b 8.8692(4) _cell_length_c 10.0090(5) _cell_angle_alpha 72.105(4) _cell_angle_beta 70.544(4) _cell_angle_gamma 76.035(4) _cell_volume 682.61(6) _cell_formula_units_Z 1 _cell_measurement_reflns_used 5580 _cell_measurement_theta_min 2.8634 _cell_measurement_theta_max 29.3807 _cell_measurement_temperature 297.2 _cell_special_details ? _exptl_crystal_density_diffrn 4.2479 _exptl_crystal_density_meas ? _exptl_crystal_density_method ? _exptl_crystal_F_000 757 _exptl_absorpt_coefficient_mu 26.161 _exptl_crystal_description prismatic _exptl_crystal_size_max 0.102 _exptl_crystal_size_mid 0.069 _exptl_crystal_size_min 0.021 _exptl_crystal_size_rad ? _exptl_crystal_colour green _exptl_absorpt_correction_type analytical _exptl_absorpt_process_details 'after Clark R.C. and Reid J.S. (1995)' _exptl_absorpt_correction_T_min 0.206 _exptl_absorpt_correction_T_max 0.633 #======================================================================= # 7. EXPERIMENTAL DATA _exptl_special_details ? _diffrn_ambient_temperature 297.2 _diffrn_source ? _diffrn_source_power ? _diffrn_source_voltage ? _diffrn_source_current ? _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_source 'X-ray tube' _diffrn_radiation_wavelength 0.7107 _diffrn_radiation_monochromator graphite _diffrn_measurement_device 'four-cycle diffractometer' _diffrn_measurement_device_type 'Oxford Diffraction CCD' _diffrn_detector 'Atlas' _diffrn_detector_area_resol_mean 10.3784 _diffrn_measurement_method omega _diffrn_measurement_specimen_support ? _diffrn_reflns_number 10626 _diffrn_reflns_theta_min 2.8634 _diffrn_reflns_theta_max 29.3807 _diffrn_reflns_theta_full ? _diffrn_measured_fraction_theta_max ? _diffrn_measured_fraction_theta_full ? _diffrn_reflns_av_R_equivalents 0.0476 _diffrn_reflns_av_sigmaI/netI 0.0944 _diffrn_reflns_limit_h_min -11 _diffrn_reflns_limit_h_max 11 _diffrn_reflns_limit_k_min -12 _diffrn_reflns_limit_k_max 12 _diffrn_reflns_limit_l_min -13 _diffrn_reflns_limit_l_max 13 _diffrn_reflns_reduction_process ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? loop_ _diffrn_standard_refln_index_h _diffrn_standard_refln_index_k _diffrn_standard_refln_index_l ? ? ? #======================================================================= # 8. REFINEMENT DATA _refine_special_details ? _reflns_number_total 3335 _reflns_number_gt 2664 _reflns_threshold_expression 'I>3\s(I)' _refine_ls_structure_factor_coef Fsqd _refine_ls_R_factor_gt 0.0347 _refine_ls_wR_factor_gt 0.0705 _refine_ls_R_factor_all 0.0481 _refine_ls_wR_factor_ref 0.0772 _refine_ls_goodness_of_fit_ref 1.24 _refine_ls_goodness_of_fit_gt 1.28 _refine_ls_restrained_S_gt ? _refine_ls_restrained_S_all ? _refine_ls_number_reflns 3335 _refine_ls_number_parameters 169 _refine_ls_number_restraints 0 _refine_ls_number_constraints 0 _refine_ls_weighting_scheme sigma _refine_ls_weighting_details 'w=1/(\s^2^(I)+0.0004I^2^)' _refine_ls_hydrogen_treatment ? _refine_ls_shift/su_max 0.0120 _refine_ls_shift/su_mean 0.0006 _refine_diff_density_max 4.74 _refine_diff_density_min -2.77 _refine_ls_extinction_method 'none' _refine_ls_extinction_coef ? _refine_ls_abs_structure_details ? _refine_ls_abs_structure_Flack ? _refine_ls_abs_structure_Rogers ? loop_ _atom_type_symbol _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source Cu 0.320 1.265 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' U -9.677 9.665 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' S 0.125 0.123 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' O 0.011 0.006 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' H 0.000 0.000 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1' _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution ? _computing_structure_refinement ? _computing_molecular_graphics ? _computing_publication_material ? #======================================================================= # 9. ATOMIC COORDINATES AND DISPLACEMENT PARAMETERS loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_adp_type _atom_site_U_iso_or_equiv _atom_site_symmetry_multiplicity _atom_site_occupancy _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group U1 U 0.42802(4) 0.34306(4) 0.46462(4) Uani 0.00767(14) 2 1 d . . . U2 U 0.09013(4) 0.67616(4) 0.47194(4) Uani 0.00826(14) 2 1 d . . . Cu1 Cu 0.5 0 0 Uani 0.0145(7) 1 0.983(7) d . . . Cu2 Cu -0.00716(15) 0.16835(15) -0.00692(14) Uani 0.0167(5) 2 0.977(5) d . . . S1 S 0.7502(3) 0.0037(3) 0.4954(3) Uani 0.0103(9) 2 1 d . . . O1 O 0.5709(8) 0.0786(8) 0.1290(7) Uani 0.017(3) 2 1 d . . . O2 O 0.3516(8) 0.5917(8) 0.4981(7) Uiso 0.0116(14) 2 1 d . . . O3 O -0.1183(8) -0.0130(9) 0.1189(8) Uani 0.018(3) 2 1 d . . . O4 O 0.2056(9) 0.1178(9) 0.1158(8) Uani 0.024(3) 2 1 d . . . O5 O 0.1505(7) 0.4083(8) 0.5051(7) Uiso 0.0101(14) 2 1 d . . . O6 O 0.4796(8) 0.4253(8) 0.2692(7) Uani 0.016(3) 2 1 d . . . O7 O 0.3112(11) 0.4200(10) 0.0619(10) Uani 0.040(4) 2 1 d . . . O8 O 0.3804(8) 0.2360(8) 0.6585(7) Uani 0.014(3) 2 1 d . . . O9 O 0.4754(8) -0.2140(8) 0.1374(8) Uani 0.019(3) 2 1 d . . . O10 O -0.1603(10) 0.3206(10) 0.1013(9) Uani 0.031(3) 2 1 d . . . O11 O 0.1621(8) 0.7036(8) 0.2755(7) Uani 0.016(3) 2 1 d . . . O12 O 0.6657(8) 0.1326(8) 0.3982(7) Uiso 0.0156(15) 2 1 d . . . O13 O 0.1013(9) 0.3492(9) -0.1471(8) Uani 0.024(3) 2 1 d . . . O14 O 0.0156(8) 0.6725(9) 0.6640(8) Uani 0.019(3) 2 1 d . . . O15 O 0.7932(8) 0.0726(8) 0.5931(7) Uiso 0.0152(15) 2 1 d . . . O16 O 0.6428(8) -0.1150(8) 0.5913(7) Uiso 0.0126(14) 2 1 d . . . O17 O 0.8984(8) -0.0764(8) 0.4047(7) Uiso 0.0137(15) 2 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_type_symbol _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_12 _atom_site_aniso_U_13 _atom_site_aniso_U_23 U1 U 0.00635(18) 0.00658(18) 0.0105(2) -0.00134(13) -0.00281(13) -0.00198(15) U2 U 0.00624(18) 0.00637(18) 0.0125(2) -0.00114(13) -0.00299(13) -0.00228(15) Cu1 Cu 0.0176(10) 0.0140(10) 0.0121(10) -0.0052(7) -0.0063(7) 0.0011(8) Cu2 Cu 0.0143(7) 0.0165(7) 0.0161(8) -0.0027(5) 0.0003(5) -0.0044(6) S1 S 0.0084(11) 0.0089(11) 0.0162(13) -0.0019(9) -0.0041(10) -0.0054(11) O1 O 0.026(4) 0.017(4) 0.014(4) -0.003(3) -0.010(3) -0.005(3) O3 O 0.010(3) 0.025(4) 0.018(4) -0.002(3) -0.001(3) -0.009(3) O4 O 0.023(4) 0.025(4) 0.022(4) -0.003(3) -0.007(3) -0.005(4) O6 O 0.021(4) 0.013(3) 0.011(4) -0.006(3) -0.004(3) 0.002(3) O7 O 0.042(5) 0.034(5) 0.046(6) 0.000(4) -0.022(4) -0.007(5) O8 O 0.015(4) 0.014(3) 0.011(4) -0.004(3) -0.004(3) -0.001(3) O9 O 0.021(4) 0.016(4) 0.018(4) -0.011(3) -0.004(3) 0.002(3) O10 O 0.033(5) 0.028(4) 0.024(5) -0.004(4) 0.005(4) -0.012(4) O11 O 0.017(4) 0.015(4) 0.016(4) 0.000(3) -0.004(3) -0.005(3) O13 O 0.023(4) 0.020(4) 0.025(5) -0.005(3) -0.001(3) -0.004(4) O14 O 0.013(4) 0.025(4) 0.017(4) 0.000(3) -0.002(3) -0.005(3) #======================================================================= # 10. MOLECULAR GEOMETRY loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_site_symmetry_1 _geom_bond_site_symmetry_2 _geom_bond_distance _geom_bond_publ_flag U1 O2 . . 2.239(7) yes U1 O2 . 2_666 2.295(8) yes U1 O5 . . 2.262(6) yes U1 O6 . . 1.805(6) yes U1 O8 . . 1.833(6) yes U1 O12 . . 2.484(6) yes U1 O16 . 2_656 2.511(8) yes U2 O2 . . 2.287(7) yes U2 O5 . . 2.249(6) yes U2 O5 . 2_566 2.302(7) yes U2 O11 . . 1.810(7) yes U2 O14 . . 1.805(7) yes U2 O15 . 2_666 2.484(8) yes U2 O17 . 1_465 2.472(6) yes Cu1 O1 . . 1.955(9) yes Cu1 O1 . 2_655 1.955(9) yes Cu1 O4 . . 2.538(7) yes Cu1 O4 . 2_655 2.538(7) yes Cu1 O9 . . 1.984(6) yes Cu1 O9 . 2_655 1.984(6) yes Cu2 Cu2 . 2_555 2.921(2) yes Cu2 O3 . . 1.948(7) yes Cu2 O3 . 2_555 1.937(8) yes Cu2 O4 . . 2.426(9) yes Cu2 O10 . . 1.958(8) yes Cu2 O11 . 2_565 3.181(8) yes Cu2 O13 . . 1.973(7) yes S1 O12 . . 1.476(7) yes S1 O15 . . 1.478(9) yes S1 O16 . . 1.468(7) yes S1 O17 . . 1.469(6) yes O1 O3 . 1_655 2.598(10) yes O1 O4 . . 3.146(11) yes O1 O4 . 2_655 3.259(11) yes O1 O8 . 2_656 2.978(9) yes O1 O9 . . 2.879(12) yes O1 O9 . 2_655 2.688(10) yes O1 O12 . . 3.260(12) yes O1 O16 . 2_656 2.861(9) yes O2 O2 . 2_666 2.698(8) yes O2 O5 . . 2.629(11) yes O2 O6 . . 2.873(11) yes O2 O6 . 2_666 3.089(12) yes O2 O8 . . 3.061(9) yes O2 O8 . 2_666 2.831(9) yes O2 O11 . . 2.990(11) yes O2 O12 . 2_666 2.891(11) yes O2 O14 . . 2.875(8) yes O2 O15 . 2_666 2.927(9) yes O3 O3 . 2_555 2.562(8) yes O3 O4 . . 3.276(12) yes O3 O4 . 2_555 3.134(13) yes O3 O8 . 2_556 3.183(9) yes O3 O10 . . 2.849(12) yes O3 O12 . 1_455 3.249(10) yes O3 O13 . 2_555 2.880(11) yes O3 O17 . 1_455 2.787(11) yes O4 O7 . . 2.878(13) yes O4 O9 . . 3.287(9) yes O4 O9 . 2_655 3.154(9) yes O4 O10 . . 3.275(11) yes O4 O13 . . 3.054(11) yes O4 O14 . 2_566 3.159(11) yes O4 O15 . 2_656 2.886(10) yes O5 O5 . 2_566 2.738(8) yes O5 O6 . . 3.041(8) yes O5 O8 . . 2.793(10) yes O5 O11 . . 2.902(8) yes O5 O11 . 2_566 3.025(8) yes O5 O13 . 1_556 3.252(11) yes O5 O14 . . 3.020(11) yes O5 O14 . 2_566 2.885(13) yes O5 O16 . 2_656 3.009(9) yes O5 O17 . 2_656 2.894(10) yes O6 O7 . . 2.924(15) yes O6 O7 . 2_665 3.249(10) yes O6 O9 . 1_565 3.059(9) yes O6 O10 . 1_655 3.083(9) yes O6 O11 . . 3.222(9) yes O6 O12 . . 2.885(9) yes O6 O16 . 2_656 2.952(10) yes O7 O9 . 2_655 2.982(12) yes O7 O10 . 2_565 2.708(11) yes O7 O14 . 2_566 3.285(10) yes O8 O9 . 2_656 2.668(12) yes O8 O12 . . 3.135(9) yes O8 O13 . 1_556 2.747(9) yes O8 O16 . 2_656 3.087(12) yes O9 O11 . 1_545 2.769(10) yes O9 O15 . 2_656 3.281(10) yes O10 O12 . 1_455 3.012(9) yes O10 O13 . . 2.744(9) yes O10 O13 . 2_565 3.279(13) yes O10 O14 . 2_566 3.031(14) yes O11 O13 . 2_565 3.153(13) yes O11 O15 . 2_666 2.852(12) yes O11 O17 . 1_465 2.853(9) yes O12 O15 . . 2.414(12) yes O12 O16 . . 2.438(8) yes O12 O16 . 2_656 2.684(11) yes O12 O17 . . 2.392(9) yes O13 O14 . 1_554 2.987(9) yes O14 O15 . 2_666 3.142(9) yes O14 O17 . 1_465 3.137(10) yes O15 O16 . . 2.356(12) yes O15 O17 . . 2.436(11) yes O15 O17 . 2_756 2.691(11) yes O16 O17 . . 2.395(8) yes loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_2 _geom_angle_site_symmetry_3 _geom_angle _geom_angle_publ_flag ? ? ? ? ? ? ? ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion _geom_torsion_publ_flag ? ? ? ? ? ? ? ? ? ? loop_ _geom_hbond_atom_site_label_D _geom_hbond_atom_site_label_H _geom_hbond_atom_site_label_A _geom_hbond_site_symmetry_D _geom_hbond_site_symmetry_H _geom_hbond_site_symmetry_A _geom_hbond_distance_DH _geom_hbond_distance_HA _geom_hbond_distance_DA _geom_hbond_angle_DHA _geom_hbond_publ_flag ? ? ? ? ? ? ? ? ? ? ? #======================================================================= # 11. STRUCTURE-FACTOR LIST loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 34742.12 34665.68 565.98 o 3 0 0 2202.43 2484.16 122.89 o 4 0 0 4405.54 4381.37 182.56 o 5 0 0 397.05 470.73 66.69 o 6 0 0 15965.47 15824.64 378.47 o 7 0 0 974.06 877.66 130.38 o 8 0 0 2241.29 1851.49 210.78 o 9 0 0 7087.80 7618.91 552.28 o 10 0 0 2474.11 2340.07 344.04 o -10 1 0 4523.40 4235.21 559.19 o -9 1 0 678.61 463.71 180.37 < -8 1 0 23843.07 24358.75 944.23 o -7 1 0 33.44 71.99 59.43 < -6 1 0 4432.56 4350.50 246.71 o -5 1 0 1984.93 1804.26 113.91 o -4 1 0 5889.04 6446.62 319.73 o -3 1 0 97.92 135.91 36.86 o -2 1 0 68379.66 66908.82 990.76 o -1 1 0 8.73 66.80 40.54 < 1 1 0 1149.06 1137.50 131.42 o 2 1 0 21203.10 20736.87 374.33 o 3 1 0 432.79 367.53 53.90 o 4 1 0 71857.66 68539.40 735.07 o 5 1 0 201.28 307.18 52.87 o 6 1 0 10235.86 9845.07 238.30 o 7 1 0 4581.40 4910.61 239.80 o 8 1 0 277.70 172.31 60.93 < 9 1 0 745.82 713.87 171.73 o 10 1 0 7182.08 8446.57 645.00 o 11 1 0 664.12 467.05 188.55 < -9 2 0 1336.43 1545.34 285.30 o -8 2 0 2612.74 3414.33 372.60 o -7 2 0 5752.11 6136.45 322.15 o -6 2 0 8183.37 8336.92 346.46 o -5 2 0 5312.76 5374.43 214.46 o -4 2 0 49703.19 45699.73 1092.12 o -3 2 0 1573.28 1612.95 101.24 o -2 2 0 9293.17 9539.15 204.44 o -1 2 0 4103.45 4231.52 93.75 o 0 2 0 11343.14 11664.53 306.72 o 1 2 0 5063.59 5092.82 136.14 o 2 2 0 89122.64 87937.20 2449.95 o 3 2 0 209.62 354.29 74.75 o 4 2 0 10810.63 10729.40 306.95 o 5 2 0 3371.94 3479.30 254.08 o 6 2 0 1306.32 1205.22 117.14 o 7 2 0 1314.90 1310.15 93.52 o 8 2 0 20692.71 20598.77 433.76 o 9 2 0 1377.57 1452.97 254.54 o 10 2 0 3760.57 4151.13 572.55 o 11 2 0 8396.36 8718.28 777.34 o -9 3 0 1694.30 1458.04 391.03 o -8 3 0 5466.67 5553.88 497.68 o -7 3 0 16.57 -47.91 153.53 < -6 3 0 43107.16 44499.92 1661.90 o -5 3 0 2986.79 2881.41 171.96 o -4 3 0 10411.31 10720.07 314.44 o -3 3 0 3615.42 3724.62 158.02 o -2 3 0 16999.01 17136.17 331.83 o -1 3 0 336.47 545.37 58.63 o 0 3 0 76001.10 75962.62 639.35 o 1 3 0 3232.27 3187.09 109.53 o 2 3 0 2409.26 2264.40 116.91 o 3 3 0 27119.90 28303.48 609.87 o 4 3 0 10579.60 10313.38 341.73 o 5 3 0 8502.99 8427.34 286.68 o 6 3 0 27508.40 27581.20 528.90 o 7 3 0 1318.26 770.19 250.63 o 8 3 0 4345.54 4361.10 235.77 o 9 3 0 3939.15 3922.61 309.25 o 10 3 0 707.77 1346.08 253.62 o -8 4 0 18124.53 21188.13 1014.83 o -7 4 0 9.13 -33.40 90.99 < -6 4 0 2727.90 2774.41 213.08 o -5 4 0 187.94 350.26 90.65 o -4 4 0 3583.83 3543.45 176.11 o -3 4 0 1201.30 1188.87 106.65 o -2 4 0 57703.98 52124.58 1709.47 o -1 4 0 1220.21 1257.97 114.03 o 0 4 0 17416.45 17721.85 280.00 o 1 4 0 2563.25 2693.67 114.26 o 2 4 0 10714.16 11329.82 605.84 o 3 4 0 712.69 380.20 197.53 < 4 4 0 31517.19 31504.16 522.22 o 5 4 0 5661.01 5885.82 211.58 o 6 4 0 4089.38 4117.38 241.53 o 7 4 0 10737.96 10289.65 412.68 o 8 4 0 373.06 329.87 81.43 o 9 4 0 7050.23 7455.58 420.28 o 10 4 0 8865.74 9251.78 1109.51 o -8 5 0 258.44 -86.84 153.53 < -7 5 0 29.98 17.51 125.31 < -6 5 0 9271.13 8795.22 472.11 o -5 5 0 257.46 319.96 88.69 o -4 5 0 50032.72 52490.27 753.95 o -3 5 0 4.49 -9.79 52.18 < -2 5 0 13711.10 13697.65 404.97 o -1 5 0 3864.41 4023.86 163.32 o 0 5 0 3426.04 3529.63 141.78 o 1 5 0 3437.60 3522.26 142.94 o 2 5 0 30897.60 35193.54 722.17 o 3 5 0 1044.91 1167.79 120.48 o 4 5 0 3888.31 3915.36 184.17 o 5 5 0 7560.24 7822.43 434.22 o 6 5 0 5000.15 5261.79 287.94 o 7 5 0 2662.36 2651.97 220.80 o 8 5 0 17086.86 17675.55 504.36 o 9 5 0 2460.83 2520.90 360.51 o -7 6 0 239.29 325.15 223.10 < -6 6 0 17436.89 17982.27 924.99 o -5 6 0 15.21 35.59 100.78 < -4 6 0 567.19 599.04 122.66 o -3 6 0 2785.94 2913.20 158.72 o -2 6 0 19531.34 20124.81 470.73 o -1 6 0 4401.83 4412.81 191.89 o 0 6 0 44718.04 44601.05 590.52 o 1 6 0 310.75 46.65 51.02 < 2 6 0 11819.42 12448.66 585.91 o 3 6 0 8018.11 7942.09 319.39 o 4 6 0 374.39 279.19 95.25 < 5 6 0 1349.93 1073.00 149.39 o 6 6 0 13646.69 15565.26 1266.27 o 7 6 0 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3791.43 557.69 o 1 3 12 2143.22 2673.51 380.55 o 2 3 12 906.50 1058.60 208.01 o 3 3 12 6835.27 6296.78 471.77 o 4 3 12 1742.33 1377.30 248.32 o 5 3 12 175.36 245.90 142.71 < 6 3 12 1245.52 1357.95 233.24 o -1 4 12 6773.65 5904.14 827.90 o 0 4 12 164.01 18.66 167.35 < 1 4 12 12704.06 12410.08 809.59 o 2 4 12 1177.36 973.48 365.57 < 3 4 12 3121.34 2722.58 404.50 o 4 4 12 900.89 1043.17 267.21 o 5 4 12 3250.32 3287.98 332.40 o 6 4 12 698.74 830.09 192.92 o -1 5 12 5357.76 5030.86 735.99 o 0 5 12 2246.22 2020.11 494.23 o 1 5 12 281.18 198.34 198.57 < 2 5 12 2176.61 3578.81 656.97 o 3 5 12 6649.37 7054.42 917.05 o 4 5 12 566.77 293.47 159.06 < 5 5 12 12994.55 12951.53 820.07 o 6 5 12 330.25 116.44 370.99 < 7 5 12 1484.42 1530.02 367.42 o 0 6 12 969.04 881.80 355.90 < 1 6 12 4959.67 5401.15 570.48 o 2 6 12 42.07 -23.73 134.99 < 3 6 12 12127.01 12061.78 840.22 o 4 6 12 2522.06 2444.31 382.51 o 5 6 12 1494.56 1175.28 261.80 o 6 6 12 124.98 106.77 147.08 < 7 6 12 3700.40 2868.85 528.90 o 8 6 12 306.81 270.09 179.68 < 1 7 12 8587.75 8031.13 775.95 o 2 7 12 32.82 -55.52 178.07 < 3 7 12 376.15 346.80 157.10 < 4 7 12 195.47 -44.80 147.66 < 5 7 12 5306.16 5073.59 730.46 o 6 7 12 1.86 124.97 206.74 < 7 7 12 10418.56 10106.75 1019.67 o 2 8 12 177.21 -81.66 268.36 < 3 8 12 3863.61 6507.78 1500.19 o 1 1 13 3035.01 3107.16 659.74 o 2 1 13 4705.67 4678.07 781.37 o 3 1 13 283.20 -131.42 239.11 < 4 1 13 6295.72 5866.13 936.63 o 5 1 13 2402.92 2043.83 634.86 o 3 2 13 1894.19 2133.56 517.26 o 4 2 13 62.78 -412.80 313.63 < 5 2 13 6397.62 5543.63 843.91 o 6 2 13 2107.12 1492.48 419.71 o 5 5 13 8383.18 8239.25 923.61 o 6 5 13 995.62 990.18 321.92 o 4 6 13 1176.38 609.98 277.58 < 5 6 13 402.37 83.73 139.48 < 6 6 13 241.50 390.45 230.47 <