data_rey-rl 
 
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'Cr2 Mn4 O18 Pb4' 
_chemical_formula_weight          1440.52 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cr'  'Cr'   0.3209   0.6236 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Mn'  'Mn'   0.3368   0.7283 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Pb'  'Pb'  -3.3944  10.1111 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            ? 
_symmetry_space_group_name_H-M    ? 
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, -y, -z' 
 
_cell_length_a                    5.0278(7) 
_cell_length_b                    7.5865(11) 
_cell_length_c                    10.2808(15) 
_cell_angle_alpha                 91.968(12) 
_cell_angle_beta                  99.405(12) 
_cell_angle_gamma                 109.159(10) 
_cell_volume                      363.81(9) 
_cell_formula_units_Z             1 
_cell_measurement_temperature     293(2) 
_cell_measurement_reflns_used     ? 
_cell_measurement_theta_min       ? 
_cell_measurement_theta_max       ? 
 
_exptl_crystal_description        ? 
_exptl_crystal_colour             ? 
_exptl_crystal_size_max           0.03 
_exptl_crystal_size_mid           0.02 
_exptl_crystal_size_min           0.00 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     6.575 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              620 
_exptl_absorpt_coefficient_mu     50.967 
_exptl_absorpt_correction_type    ? 
_exptl_absorpt_correction_T_min   0.3623 
_exptl_absorpt_correction_T_max   0.9508 
_exptl_absorpt_process_details    ? 
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       293(2) 
_diffrn_radiation_wavelength      0.71075 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   ? 
_diffrn_measurement_method        ? 
_diffrn_detector_area_resol_mean  ? 
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             1251 
_diffrn_reflns_av_R_equivalents   0.0000 
_diffrn_reflns_av_sigmaI/netI     0.1242 
_diffrn_reflns_limit_h_min        0 
_diffrn_reflns_limit_h_max        4 
_diffrn_reflns_limit_k_min        -7 
_diffrn_reflns_limit_k_max        6 
_diffrn_reflns_limit_l_min        -9 
_diffrn_reflns_limit_l_max        9 
_diffrn_reflns_theta_min          2.02 
_diffrn_reflns_theta_max          20.02 
_reflns_number_total              1251 
_reflns_number_gt                 902 
_reflns_threshold_expression      >2sigma(I) 
 
_computing_data_collection        ? 
_computing_cell_refinement        ? 
_computing_data_reduction         ? 
_computing_structure_solution     'SHELXS-97 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 1997)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
 
_refine_special_details 
; 
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc  
_refine_ls_weighting_details 
 'calc w=1/[\s^2^(Fo^2^)+(0.1034P)^2^+28.2146P] where P=(Fo^2^+2Fc^2^)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     mixed 
_refine_ls_extinction_method      SHELXL 
_refine_ls_extinction_coef        0.010(2) 
_refine_ls_extinction_expression 
 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' 
_refine_ls_number_reflns          1251 
_refine_ls_number_parameters      56 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.1407 
_refine_ls_R_factor_gt            0.1016 
_refine_ls_wR_factor_ref          0.2277 
_refine_ls_wR_factor_gt           0.2118 
_refine_ls_goodness_of_fit_ref    1.156 
_refine_ls_restrained_S_all       1.156 
_refine_ls_shift/su_max           0.000 
_refine_ls_shift/su_mean          0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Pb1 Pb 0.1082(5) 0.0396(3) 0.7436(3) 0.0161(11) Uiso 1 1 d . . . 
Pb2 Pb 0.5013(6) 0.6126(4) 0.8184(3) 0.0260(12) Uiso 1 1 d . . . 
Mn1 Mn 0.6008(19) 0.1968(12) 0.5028(10) 0.009(2) Uiso 1 1 d . . . 
Mn2 Mn 0.1950(18) 0.3944(12) 0.4931(10) 0.015(3) Uiso 1 1 d . . . 
Cr Cr 0.807(2) 0.2354(14) 0.9544(11) 0.015(2) Uiso 1 1 d . . . 
O1 O 0.554(8) 0.325(5) 0.929(4) 0.012(10) Uiso 1 1 d . . . 
O2 O 0.053(8) 0.349(5) 0.869(4) 0.016(11) Uiso 1 1 d . . . 
O3 O 0.953(9) 0.267(6) 0.114(5) 0.026(12) Uiso 1 1 d . . . 
O4 O 0.689(9) 0.009(6) 0.886(5) 0.027(12) Uiso 1 1 d . . . 
O5 O 0.830(8) 0.384(5) 0.402(4) 0.015 Uiso 1 1 d . . . 
O6 O 0.436(8) 0.588(5) 0.401(4) 0.015 Uiso 1 1 d . . . 
O7 O 0.420(9) 0.006(6) 0.605(4) 0.023(12) Uiso 1 1 d . . . 
O8 O 0.255(9) 0.218(6) 0.390(4) 0.015 Uiso 1 1 d . . . 
O9 O 0.989(8) 0.235(5) 0.597(4) 0.011(10) Uiso 1 1 d . . . 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Pb1 O9 2.30(4) 1_455 ? 
Pb1 O7 2.35(4) . ? 
Pb1 O8 2.38(4) 2_556 ? 
Pb1 O4 2.71(4) 1_455 ? 
Pb1 O3 2.75(4) 2_656 ? 
Pb1 O2 2.75(4) . ? 
Pb1 O1 2.91(4) . ? 
Pb1 O4 3.13(5) . ? 
Pb1 Cr 3.396(12) 1_455 ? 
Pb1 O7 3.44(4) 1_455 ? 
Pb1 O6 3.55(4) 2_666 ? 
Pb1 Cr 3.619(11) . ? 
Pb1 O5 3.62(4) 2_656 ? 
Pb1 Mn1 3.736(9) . ? 
Pb1 Mn2 3.745(9) 2_556 ? 
Pb2 O3 2.56(4) 2_766 ? 
Pb2 O1 2.57(4) . ? 
Pb2 O5 2.59(4) 2_666 ? 
Pb2 O2 2.62(4) . ? 
Pb2 O1 2.70(4) 2_667 ? 
Pb2 O8 2.78(4) 2_666 ? 
Pb2 O6 2.79(4) 2_666 ? 
Pb2 O4 2.86(4) 1_565 ? 
Pb2 O3 2.89(4) 2_666 ? 
Pb2 Cr 3.369(13) 2_667 ? 
Pb2 Mn2 3.544(10) . ? 
Pb2 O2 3.55(4) 2_667 ? 
Pb2 O9 3.58(4) 1_455 ? 
Pb2 Cr 3.663(11) 2_767 ? 
Pb2 Mn1 3.677(10) 2_666 ? 
Mn1 O7 1.83(4) 2_656 ? 
Mn1 O7 1.89(4) . ? 
Mn1 O9 1.96(4) . ? 
Mn1 O6 1.96(4) 2_666 ? 
Mn1 O5 1.96(4) . ? 
Mn1 O8 1.99(4) . ? 
Mn1 Mn1 2.816(17) 2_656 ? 
Mn1 Mn2 2.890(11) 1_655 ? 
Mn1 Mn2 2.893(12) . ? 
Mn1 Mn2 2.926(13) 2_666 ? 
Mn1 Pb2 3.677(10) 2_666 ? 
Mn2 O8 1.81(4) . ? 
Mn2 O9 1.82(4) 1_455 ? 
Mn2 O5 1.89(4) 1_455 ? 
Mn2 O6 1.95(4) . ? 
Mn2 O6 1.95(4) 2_666 ? 
Mn2 O5 2.02(4) 2_666 ? 
Mn2 Mn1 2.890(11) 1_455 ? 
Mn2 Mn1 2.926(13) 2_666 ? 
Mn2 Mn2 2.928(18) 2_566 ? 
Mn2 Mn2 2.935(17) 2_666 ? 
Cr O1 1.62(4) . ? 
Cr O3 1.66(5) 1_556 ? 
Cr O2 1.66(4) 1_655 ? 
Cr O4 1.71(4) . ? 
Cr Pb2 3.369(13) 2_667 ? 
Cr Pb1 3.396(12) 1_655 ? 
Cr Pb2 3.663(11) 2_767 ? 
Cr Pb1 3.844(11) 2_657 ? 
Cr Pb2 4.201(10) 1_655 ? 
Cr Pb2 4.552(11) 1_545 ? 
O1 Pb2 2.70(4) 2_667 ? 
O2 Cr 1.66(4) 1_455 ? 
O2 Pb2 3.55(4) 2_667 ? 
O2 Pb2 3.90(4) 1_455 ? 
O3 Cr 1.66(5) 1_554 ? 
O3 Pb2 2.56(4) 2_766 ? 
O3 Pb1 2.75(4) 2_656 ? 
O3 Pb2 2.89(4) 2_666 ? 
O4 Pb1 2.71(4) 1_655 ? 
O4 Pb2 2.86(4) 1_545 ? 
O4 Pb1 3.84(5) 2_657 ? 
O5 Mn2 1.89(4) 1_655 ? 
O5 Mn2 2.02(4) 2_666 ? 
O5 Pb2 2.59(4) 2_666 ? 
O5 Pb1 3.62(4) 2_656 ? 
O6 Mn2 1.95(4) 2_666 ? 
O6 Mn1 1.96(4) 2_666 ? 
O6 Pb2 2.79(4) 2_666 ? 
O6 Pb1 3.55(4) 2_666 ? 
O7 Mn1 1.83(4) 2_656 ? 
O7 Pb1 3.44(4) 1_655 ? 
O7 Pb2 3.85(4) 1_545 ? 
O7 Pb1 4.03(4) 2_556 ? 
O8 Pb1 2.38(4) 2_556 ? 
O8 Pb2 2.78(4) 2_666 ? 
O9 Mn2 1.82(4) 1_655 ? 
O9 Pb1 2.30(4) 1_655 ? 
O9 Pb2 3.58(4) 1_655 ? 
O9 Pb1 3.89(4) 2_656 ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
O9 Pb1 O7 86.6(15) 1_455 . ? 
O9 Pb1 O8 88.5(14) 1_455 2_556 ? 
O7 Pb1 O8 87.3(14) . 2_556 ? 
O9 Pb1 O4 97.2(14) 1_455 1_455 ? 
O7 Pb1 O4 168.9(13) . 1_455 ? 
O8 Pb1 O4 82.3(13) 2_556 1_455 ? 
O9 Pb1 O3 159.4(13) 1_455 2_656 ? 
O7 Pb1 O3 102.0(14) . 2_656 ? 
O8 Pb1 O3 73.5(14) 2_556 2_656 ? 
O4 Pb1 O3 71.1(13) 1_455 2_656 ? 
O9 Pb1 O2 67.6(13) 1_455 . ? 
O7 Pb1 O2 132.5(13) . . ? 
O8 Pb1 O2 128.7(13) 2_556 . ? 
O4 Pb1 O2 58.3(12) 1_455 . ? 
O3 Pb1 O2 116.2(13) 2_656 . ? 
O9 Pb1 O1 97.9(12) 1_455 . ? 
O7 Pb1 O1 94.4(13) . . ? 
O8 Pb1 O1 173.5(13) 2_556 . ? 
O4 Pb1 O1 95.5(12) 1_455 . ? 
O3 Pb1 O1 100.0(12) 2_656 . ? 
O2 Pb1 O1 53.6(11) . . ? 
O9 Pb1 O4 134.0(12) 1_455 . ? 
O7 Pb1 O4 64.0(14) . . ? 
O8 Pb1 O4 122.1(13) 2_556 . ? 
O4 Pb1 O4 118.6(16) 1_455 . ? 
O3 Pb1 O4 66.0(12) 2_656 . ? 
O2 Pb1 O4 106.1(12) . . ? 
O1 Pb1 O4 53.8(11) . . ? 
O9 Pb1 Cr 85.0(10) 1_455 1_455 ? 
O7 Pb1 Cr 161.2(10) . 1_455 ? 
O8 Pb1 Cr 109.2(10) 2_556 1_455 ? 
O4 Pb1 Cr 29.9(9) 1_455 1_455 ? 
O3 Pb1 Cr 91.5(9) 2_656 1_455 ? 
O2 Pb1 Cr 29.0(8) . 1_455 ? 
O1 Pb1 Cr 70.2(8) . 1_455 ? 
O4 Pb1 Cr 111.4(8) . 1_455 ? 
O9 Pb1 O7 55.0(12) 1_455 1_455 ? 
O7 Pb1 O7 119.3(16) . 1_455 ? 
O8 Pb1 O7 51.7(13) 2_556 1_455 ? 
O4 Pb1 O7 56.4(12) 1_455 1_455 ? 
O3 Pb1 O7 104.9(11) 2_656 1_455 ? 
O2 Pb1 O7 78.2(11) . 1_455 ? 
O1 Pb1 O7 131.7(11) . 1_455 ? 
O4 Pb1 O7 170.9(11) . 1_455 ? 
Cr Pb1 O7 68.4(8) 1_455 1_455 ? 
O9 Pb1 O6 50.9(11) 1_455 2_666 ? 
O7 Pb1 O6 55.2(12) . 2_666 ? 
O8 Pb1 O6 121.4(12) 2_556 2_666 ? 
O4 Pb1 O6 134.6(12) 1_455 2_666 ? 
O3 Pb1 O6 148.3(11) 2_656 2_666 ? 
O2 Pb1 O6 78.1(11) . 2_666 ? 
O1 Pb1 O6 64.4(11) . 2_666 ? 
O4 Pb1 O6 83.1(10) . 2_666 ? 
Cr Pb1 O6 107.0(7) 1_455 2_666 ? 
O7 Pb1 O6 105.8(10) 1_455 2_666 ? 
O9 Pb1 Cr 115.2(9) 1_455 . ? 
O7 Pb1 Cr 76.9(11) . . ? 
O8 Pb1 Cr 150.2(11) 2_556 . ? 
O4 Pb1 Cr 110.5(10) 1_455 . ? 
O3 Pb1 Cr 85.2(9) 2_656 . ? 
O2 Pb1 Cr 79.2(9) . . ? 
O1 Pb1 Cr 25.8(8) . . ? 
O4 Pb1 Cr 28.2(8) . . ? 
Cr Pb1 Cr 91.5(3) 1_455 . ? 
O7 Pb1 Cr 157.4(7) 1_455 . ? 
O6 Pb1 Cr 69.2(7) 2_666 . ? 
O9 Pb1 O5 115.9(12) 1_455 2_656 ? 
O7 Pb1 O5 50.6(12) . 2_656 ? 
O8 Pb1 O5 51.2(12) 2_556 2_656 ? 
O4 Pb1 O5 118.7(11) 1_455 2_656 ? 
O3 Pb1 O5 59.9(11) 2_656 2_656 ? 
O2 Pb1 O5 176.1(11) . 2_656 ? 
O1 Pb1 O5 125.9(10) . 2_656 ? 
O4 Pb1 O5 72.7(10) . 2_656 ? 
Cr Pb1 O5 147.7(7) 1_455 2_656 ? 
O7 Pb1 O5 102.4(9) 1_455 2_656 ? 
O6 Pb1 O5 105.3(9) 2_666 2_656 ? 
Cr Pb1 O5 100.1(7) . 2_656 ? 
O9 Pb1 Mn1 65.1(10) 1_455 . ? 
O7 Pb1 Mn1 25.2(11) . . ? 
O8 Pb1 Mn1 99.4(10) 2_556 . ? 
O4 Pb1 Mn1 162.1(10) 1_455 . ? 
O3 Pb1 Mn1 126.6(9) 2_656 . ? 
O2 Pb1 Mn1 109.1(8) . . ? 
O1 Pb1 Mn1 84.6(8) . . ? 
O4 Pb1 Mn1 75.7(9) . . ? 
Cr Pb1 Mn1 137.9(2) 1_455 . ? 
O7 Pb1 Mn1 110.8(8) 1_455 . ? 
O6 Pb1 Mn1 31.0(7) 2_666 . ? 
Cr Pb1 Mn1 76.7(2) . . ? 
O5 Pb1 Mn1 74.4(6) 2_656 . ? 
O9 Pb1 Mn2 95.8(10) 1_455 2_556 ? 
O7 Pb1 Mn2 66.0(10) . 2_556 ? 
O8 Pb1 Mn2 23.1(10) 2_556 2_556 ? 
O4 Pb1 Mn2 103.1(9) 1_455 2_556 ? 
O3 Pb1 Mn2 71.5(9) 2_656 2_556 ? 
O2 Pb1 Mn2 151.0(8) . 2_556 ? 
O1 Pb1 Mn2 155.4(8) . 2_556 ? 
O4 Pb1 Mn2 102.4(8) . 2_556 ? 
Cr Pb1 Mn2 131.6(2) 1_455 2_556 ? 
O7 Pb1 Mn2 72.8(7) 1_455 2_556 ? 
O6 Pb1 Mn2 110.6(7) 2_666 2_556 ? 
Cr Pb1 Mn2 129.8(2) . 2_556 ? 
O5 Pb1 Mn2 29.7(7) 2_656 2_556 ? 
Mn1 Pb1 Mn2 82.7(2) . 2_556 ? 
O3 Pb2 O1 82.3(13) 2_766 . ? 
O3 Pb2 O5 131.3(14) 2_766 2_666 ? 
O1 Pb2 O5 127.3(12) . 2_666 ? 
O3 Pb2 O2 139.9(14) 2_766 . ? 
O1 Pb2 O2 59.2(12) . . ? 
O5 Pb2 O2 84.9(13) 2_666 . ? 
O3 Pb2 O1 90.7(14) 2_766 2_667 ? 
O1 Pb2 O1 75.7(13) . 2_667 ? 
O5 Pb2 O1 130.1(12) 2_666 2_667 ? 
O2 Pb2 O1 70.6(12) . 2_667 ? 
O3 Pb2 O8 70.4(13) 2_766 2_666 ? 
O1 Pb2 O8 129.0(12) . 2_666 ? 
O5 Pb2 O8 61.0(12) 2_666 2_666 ? 
O2 Pb2 O8 142.2(12) . 2_666 ? 
O1 Pb2 O8 143.7(12) 2_667 2_666 ? 
O3 Pb2 O6 87.9(13) 2_766 2_666 ? 
O1 Pb2 O6 80.9(12) . 2_666 ? 
O5 Pb2 O6 64.7(12) 2_666 2_666 ? 
O2 Pb2 O6 95.9(12) . 2_666 ? 
O1 Pb2 O6 156.6(12) 2_667 2_666 ? 
O8 Pb2 O6 56.5(12) 2_666 2_666 ? 
O3 Pb2 O4 71.5(13) 2_766 1_565 ? 
O1 Pb2 O4 137.2(13) . 1_565 ? 
O5 Pb2 O4 95.1(13) 2_666 1_565 ? 
O2 Pb2 O4 129.5(13) . 1_565 ? 
O1 Pb2 O4 71.5(13) 2_667 1_565 ? 
O8 Pb2 O4 73.1(12) 2_666 1_565 ? 
O6 Pb2 O4 129.6(12) 2_666 1_565 ? 
O3 Pb2 O3 134.4(17) 2_766 2_666 ? 
O1 Pb2 O3 114.8(13) . 2_666 ? 
O5 Pb2 O3 73.0(13) 2_666 2_666 ? 
O2 Pb2 O3 63.9(12) . 2_666 ? 
O1 Pb2 O3 57.3(12) 2_667 2_666 ? 
O8 Pb2 O3 115.1(13) 2_666 2_666 ? 
O6 Pb2 O3 134.7(12) 2_666 2_666 ? 
O4 Pb2 O3 68.0(12) 1_565 2_666 ? 
O3 Pb2 Cr 111.2(10) 2_766 2_667 ? 
O1 Pb2 Cr 97.8(9) . 2_667 ? 
O5 Pb2 Cr 102.5(9) 2_666 2_667 ? 
O2 Pb2 Cr 67.6(9) . 2_667 ? 
O1 Pb2 Cr 28.2(9) 2_667 2_667 ? 
O8 Pb2 Cr 131.8(9) 2_666 2_667 ? 
O6 Pb2 Cr 160.7(9) 2_666 2_667 ? 
O4 Pb2 Cr 63.2(9) 1_565 2_667 ? 
O3 Pb2 Cr 29.5(9) 2_666 2_667 ? 
O3 Pb2 Mn2 118.3(10) 2_766 . ? 
O1 Pb2 Mn2 98.2(9) . . ? 
O5 Pb2 Mn2 34.1(9) 2_666 . ? 
O2 Pb2 Mn2 80.7(9) . . ? 
O1 Pb2 Mn2 149.6(8) 2_667 . ? 
O8 Pb2 Mn2 62.1(8) 2_666 . ? 
O6 Pb2 Mn2 33.3(9) 2_666 . ? 
O4 Pb2 Mn2 123.8(10) 1_565 . ? 
O3 Pb2 Mn2 101.4(9) 2_666 . ? 
Cr Pb2 Mn2 129.5(2) 2_667 . ? 
O3 Pb2 O2 49.3(12) 2_766 2_667 ? 
O1 Pb2 O2 57.8(11) . 2_667 ? 
O5 Pb2 O2 174.1(11) 2_666 2_667 ? 
O2 Pb2 O2 96.6(10) . 2_667 ? 
O1 Pb2 O2 45.9(11) 2_667 2_667 ? 
O8 Pb2 O2 119.1(11) 2_666 2_667 ? 
O6 Pb2 O2 120.6(11) 2_666 2_667 ? 
O4 Pb2 O2 79.6(11) 1_565 2_667 ? 
O3 Pb2 O2 102.5(11) 2_666 2_667 ? 
Cr Pb2 O2 73.0(7) 2_667 2_667 ? 
Mn2 Pb2 O2 151.7(6) . 2_667 ? 
O3 Pb2 O9 134.9(11) 2_766 1_455 ? 
O1 Pb2 O9 78.0(11) . 1_455 ? 
O5 Pb2 O9 49.4(11) 2_666 1_455 ? 
O2 Pb2 O9 51.6(11) . 1_455 ? 
O1 Pb2 O9 122.2(10) 2_667 1_455 ? 
O8 Pb2 O9 91.6(10) 2_666 1_455 ? 
O6 Pb2 O9 49.4(10) 2_666 1_455 ? 
O4 Pb2 O9 143.6(11) 1_565 1_455 ? 
O3 Pb2 O9 90.7(11) 2_666 1_455 ? 
Cr Pb2 O9 111.4(7) 2_667 1_455 ? 
Mn2 Pb2 O9 29.5(6) . 1_455 ? 
O2 Pb2 O9 135.4(9) 2_667 1_455 ? 
O3 Pb2 Cr 23.3(11) 2_766 2_767 ? 
O1 Pb2 Cr 72.5(9) . 2_767 ? 
O5 Pb2 Cr 152.9(9) 2_666 2_767 ? 
O2 Pb2 Cr 122.1(9) . 2_767 ? 
O1 Pb2 Cr 68.0(9) 2_667 2_767 ? 
O8 Pb2 Cr 92.5(9) 2_666 2_767 ? 
O6 Pb2 Cr 106.6(9) 2_666 2_767 ? 
O4 Pb2 Cr 70.2(9) 1_565 2_767 ? 
O3 Pb2 Cr 118.6(9) 2_666 2_767 ? 
Cr Pb2 Cr 91.2(3) 2_667 2_767 ? 
Mn2 Pb2 Cr 139.4(3) . 2_767 ? 
O2 Pb2 Cr 26.6(7) 2_667 2_767 ? 
O9 Pb2 Cr 145.0(7) 1_455 2_767 ? 
O3 Pb2 Mn1 101.8(11) 2_766 2_666 ? 
O1 Pb2 Mn1 143.7(9) . 2_666 ? 
O5 Pb2 Mn1 30.6(8) 2_666 2_666 ? 
O2 Pb2 Mn1 115.6(9) . 2_666 ? 
O1 Pb2 Mn1 139.5(9) 2_667 2_666 ? 
O8 Pb2 Mn1 32.2(9) 2_666 2_666 ? 
O6 Pb2 Mn1 63.4(9) 2_666 2_666 ? 
O4 Pb2 Mn1 76.2(10) 1_565 2_666 ? 
O3 Pb2 Mn1 88.2(9) 2_666 2_666 ? 
Cr Pb2 Mn1 113.5(2) 2_667 2_666 ? 
Mn2 Pb2 Mn1 47.8(2) . 2_666 ? 
O2 Pb2 Mn1 147.5(6) 2_667 2_666 ? 
O9 Pb2 Mn1 73.9(7) 1_455 2_666 ? 
Cr Pb2 Mn1 122.3(2) 2_767 2_666 ? 
O7 Mn1 O7 82(2) 2_656 . ? 
O7 Mn1 O9 94.8(18) 2_656 . ? 
O7 Mn1 O9 94.9(18) . . ? 
O7 Mn1 O6 170(2) 2_656 2_666 ? 
O7 Mn1 O6 99.3(18) . 2_666 ? 
O9 Mn1 O6 94.6(17) . 2_666 ? 
O7 Mn1 O5 95.3(18) 2_656 . ? 
O7 Mn1 O5 172.6(18) . . ? 
O9 Mn1 O5 78.7(17) . . ? 
O6 Mn1 O5 84.9(17) 2_666 . ? 
O7 Mn1 O8 90.6(19) 2_656 . ? 
O7 Mn1 O8 99.1(18) . . ? 
O9 Mn1 O8 165.7(17) . . ? 
O6 Mn1 O8 79.9(17) 2_666 . ? 
O5 Mn1 O8 87.6(17) . . ? 
O7 Mn1 Mn1 41.7(14) 2_656 2_656 ? 
O7 Mn1 Mn1 39.9(13) . 2_656 ? 
O9 Mn1 Mn1 96.4(12) . 2_656 ? 
O6 Mn1 Mn1 138.4(13) 2_666 2_656 ? 
O5 Mn1 Mn1 136.6(13) . 2_656 ? 
O8 Mn1 Mn1 96.4(13) . 2_656 ? 
O7 Mn1 Mn2 93.9(14) 2_656 1_655 ? 
O7 Mn1 Mn2 132.7(14) . 1_655 ? 
O9 Mn1 Mn2 38.2(12) . 1_655 ? 
O6 Mn1 Mn2 92.4(12) 2_666 1_655 ? 
O5 Mn1 Mn2 40.6(12) . 1_655 ? 
O8 Mn1 Mn2 128.2(12) . 1_655 ? 
Mn1 Mn1 Mn2 120.0(5) 2_656 1_655 ? 
O7 Mn1 Mn2 128.3(15) 2_656 . ? 
O7 Mn1 Mn2 97.1(14) . . ? 
O9 Mn1 Mn2 136.5(12) . . ? 
O6 Mn1 Mn2 42.2(12) 2_666 . ? 
O5 Mn1 Mn2 90.1(12) . . ? 
O8 Mn1 Mn2 38.2(12) . . ? 
Mn1 Mn1 Mn2 119.0(5) 2_656 . ? 
Mn2 Mn1 Mn2 120.8(4) 1_655 . ? 
O7 Mn1 Mn2 138.3(15) 2_656 2_666 ? 
O7 Mn1 Mn2 140.1(14) . 2_666 ? 
O9 Mn1 Mn2 84.2(12) . 2_666 ? 
O6 Mn1 Mn2 41.5(12) 2_666 2_666 ? 
O5 Mn1 Mn2 43.4(12) . 2_666 ? 
O8 Mn1 Mn2 83.0(12) . 2_666 ? 
Mn1 Mn1 Mn2 179.5(6) 2_656 2_666 ? 
Mn2 Mn1 Mn2 60.5(4) 1_655 2_666 ? 
Mn2 Mn1 Mn2 60.6(3) . 2_666 ? 
O7 Mn1 Pb2 81.3(15) 2_656 2_666 ? 
O7 Mn1 Pb2 142.7(14) . 2_666 ? 
O9 Mn1 Pb2 119.5(12) . 2_666 ? 
O6 Mn1 Pb2 92.6(13) 2_666 2_666 ? 
O5 Mn1 Pb2 42.3(12) . 2_666 ? 
O8 Mn1 Pb2 48.3(12) . 2_666 ? 
Mn1 Mn1 Pb2 115.9(5) 2_656 2_666 ? 
Mn2 Mn1 Pb2 81.5(3) 1_655 2_666 ? 
Mn2 Mn1 Pb2 68.9(3) . 2_666 ? 
Mn2 Mn1 Pb2 63.7(3) 2_666 2_666 ? 
O7 Mn1 Pb1 109.3(14) 2_656 . ? 
O7 Mn1 Pb1 31.9(13) . . ? 
O9 Mn1 Pb1 107.3(12) . . ? 
O6 Mn1 Pb1 69.3(12) 2_666 . ? 
O5 Mn1 Pb1 153.7(12) . . ? 
O8 Mn1 Pb1 83.3(12) . . ? 
Mn1 Mn1 Pb1 69.1(3) 2_656 . ? 
Mn2 Mn1 Pb1 141.3(4) 1_655 . ? 
Mn2 Mn1 Pb1 67.7(3) . . ? 
Mn2 Mn1 Pb1 110.8(3) 2_666 . ? 
Pb2 Mn1 Pb1 131.2(3) 2_666 . ? 
O8 Mn2 O9 96.8(18) . 1_455 ? 
O8 Mn2 O5 99.4(19) . 1_455 ? 
O9 Mn2 O5 84.0(18) 1_455 1_455 ? 
O8 Mn2 O6 89.0(18) . . ? 
O9 Mn2 O6 172.9(18) 1_455 . ? 
O5 Mn2 O6 99.1(18) 1_455 . ? 
O8 Mn2 O6 84.5(18) . 2_666 ? 
O9 Mn2 O6 93.9(18) 1_455 2_666 ? 
O5 Mn2 O6 175.8(18) 1_455 2_666 ? 
O6 Mn2 O6 82.6(19) . 2_666 ? 
O8 Mn2 O5 172.3(18) . 2_666 ? 
O9 Mn2 O5 90.6(17) 1_455 2_666 ? 
O5 Mn2 O5 83.2(18) 1_455 2_666 ? 
O6 Mn2 O5 83.4(17) . 2_666 ? 
O6 Mn2 O5 93.2(17) 2_666 2_666 ? 
O8 Mn2 Mn1 98.1(13) . 1_455 ? 
O9 Mn2 Mn1 41.8(13) 1_455 1_455 ? 
O5 Mn2 Mn1 42.3(12) 1_455 1_455 ? 
O6 Mn2 Mn1 141.4(13) . 1_455 ? 
O6 Mn2 Mn1 135.7(13) 2_666 1_455 ? 
O5 Mn2 Mn1 88.7(11) 2_666 1_455 ? 
O8 Mn2 Mn1 42.7(14) . . ? 
O9 Mn2 Mn1 91.9(13) 1_455 . ? 
O5 Mn2 Mn1 141.2(13) 1_455 . ? 
O6 Mn2 Mn1 89.7(12) . . ? 
O6 Mn2 Mn1 42.4(12) 2_666 . ? 
O5 Mn2 Mn1 135.6(12) 2_666 . ? 
Mn1 Mn2 Mn1 120.8(4) 1_455 . ? 
O8 Mn2 Mn1 130.6(14) . 2_666 ? 
O9 Mn2 Mn1 132.5(13) 1_455 2_666 ? 
O5 Mn2 Mn1 90.1(12) 1_455 2_666 ? 
O6 Mn2 Mn1 41.6(12) . 2_666 ? 
O6 Mn2 Mn1 88.7(12) 2_666 2_666 ? 
O5 Mn2 Mn1 41.8(11) 2_666 2_666 ? 
Mn1 Mn2 Mn1 119.5(3) 1_455 2_666 ? 
Mn1 Mn2 Mn1 119.4(3) . 2_666 ? 
O8 Mn2 Mn2 142.1(15) . 2_566 ? 
O9 Mn2 Mn2 86.5(13) 1_455 2_566 ? 
O5 Mn2 Mn2 43.2(12) 1_455 2_566 ? 
O6 Mn2 Mn2 91.4(13) . 2_566 ? 
O6 Mn2 Mn2 133.1(13) 2_666 2_566 ? 
O5 Mn2 Mn2 40.0(12) 2_666 2_566 ? 
Mn1 Mn2 Mn2 60.4(3) 1_455 2_566 ? 
Mn1 Mn2 Mn2 175.2(6) . 2_566 ? 
Mn1 Mn2 Mn2 59.2(3) 2_666 2_566 ? 
O8 Mn2 Mn2 85.7(14) . 2_666 ? 
O9 Mn2 Mn2 134.9(14) 1_455 2_666 ? 
O5 Mn2 Mn2 140.3(14) 1_455 2_666 ? 
O6 Mn2 Mn2 41.3(13) . 2_666 ? 
O6 Mn2 Mn2 41.3(12) 2_666 2_666 ? 
O5 Mn2 Mn2 87.8(12) 2_666 2_666 ? 
Mn1 Mn2 Mn2 175.2(6) 1_455 2_666 ? 
Mn1 Mn2 Mn2 60.3(3) . 2_666 ? 
Mn1 Mn2 Mn2 59.2(3) 2_666 2_666 ? 
Mn2 Mn2 Mn2 118.1(6) 2_566 2_666 ? 
O8 Mn2 Pb2 134.2(15) . . ? 
O9 Mn2 Pb2 76.3(12) 1_455 . ? 
O5 Mn2 Pb2 124.0(13) 1_455 . ? 
O6 Mn2 Pb2 96.7(13) . . ? 
O6 Mn2 Pb2 51.8(12) 2_666 . ? 
O5 Mn2 Pb2 46.1(12) 2_666 . ? 
Mn1 Mn2 Pb2 104.7(3) 1_455 . ? 
Mn1 Mn2 Pb2 91.9(3) . . ? 
Mn1 Mn2 Pb2 68.5(3) 2_666 . ? 
Mn2 Mn2 Pb2 83.3(4) 2_566 . ? 
Mn2 Mn2 Pb2 70.5(4) 2_666 . ? 
O1 Cr O3 110(2) . 1_556 ? 
O1 Cr O2 107(2) . 1_655 ? 
O3 Cr O2 109(2) 1_556 1_655 ? 
O1 Cr O4 111(2) . . ? 
O3 Cr O4 115(2) 1_556 . ? 
O2 Cr O4 104(2) 1_655 . ? 
O1 Cr Pb2 52.3(15) . 2_667 ? 
O3 Cr Pb2 59.2(15) 1_556 2_667 ? 
O2 Cr Pb2 131.9(14) 1_655 2_667 ? 
O4 Cr Pb2 123.1(15) . 2_667 ? 
O1 Cr Pb1 131.9(16) . 1_655 ? 
O3 Cr Pb1 117.5(16) 1_556 1_655 ? 
O2 Cr Pb1 53.5(14) 1_655 1_655 ? 
O4 Cr Pb1 52.3(15) . 1_655 ? 
Pb2 Cr Pb1 173.7(4) 2_667 1_655 ? 
O1 Cr Pb1 51.7(14) . . ? 
O3 Cr Pb1 139.3(16) 1_556 . ? 
O2 Cr Pb1 111.3(15) 1_655 . ? 
O4 Cr Pb1 59.8(16) . . ? 
Pb2 Cr Pb1 88.9(3) 2_667 . ? 
Pb1 Cr Pb1 91.5(3) 1_655 . ? 
O1 Cr Pb2 132.0(15) . 2_767 ? 
O3 Cr Pb2 37.6(15) 1_556 2_767 ? 
O2 Cr Pb2 72.8(15) 1_655 2_767 ? 
O4 Cr Pb2 115.6(16) . 2_767 ? 
Pb2 Cr Pb2 91.2(3) 2_667 2_767 ? 
Pb1 Cr Pb2 87.8(3) 1_655 2_767 ? 
Pb1 Cr Pb2 174.2(3) . 2_767 ? 
O1 Cr Pb1 120.7(15) . 2_657 ? 
O3 Cr Pb1 38.6(15) 1_556 2_657 ? 
O2 Cr Pb1 128.6(15) 1_655 2_657 ? 
O4 Cr Pb1 77.1(16) . 2_657 ? 
Pb2 Cr Pb1 73.7(2) 2_667 2_657 ? 
Pb1 Cr Pb1 100.3(3) 1_655 2_657 ? 
Pb1 Cr Pb1 112.8(3) . 2_657 ? 
Pb2 Cr Pb1 61.70(19) 2_767 2_657 ? 
O1 Cr Pb2 28.5(14) . . ? 
O3 Cr Pb2 116.7(16) 1_556 . ? 
O2 Cr Pb2 78.8(14) 1_655 . ? 
O4 Cr Pb2 123.7(16) . . ? 
Pb2 Cr Pb2 69.8(2) 2_667 . ? 
Pb1 Cr Pb2 116.1(3) 1_655 . ? 
Pb1 Cr Pb2 66.8(2) . . ? 
Pb2 Cr Pb2 118.6(3) 2_767 . ? 
Pb1 Cr Pb2 143.5(3) 2_657 . ? 
O1 Cr Pb2 105.4(15) . 1_655 ? 
O3 Cr Pb2 97.6(15) 1_556 1_655 ? 
O2 Cr Pb2 13.5(14) 1_655 1_655 ? 
O4 Cr Pb2 116.7(16) . 1_655 ? 
Pb2 Cr Pb2 120.1(3) 2_667 1_655 ? 
Pb1 Cr Pb2 64.79(19) 1_655 1_655 ? 
Pb1 Cr Pb2 121.3(3) . 1_655 ? 
Pb2 Cr Pb2 63.42(17) 2_767 1_655 ? 
Pb1 Cr Pb2 123.5(3) 2_657 1_655 ? 
Pb2 Cr Pb2 76.97(19) . 1_655 ? 
O1 Cr Pb2 113.0(14) . 1_545 ? 
O3 Cr Pb2 108.8(15) 1_556 1_545 ? 
O2 Cr Pb2 108.8(14) 1_655 1_545 ? 
O4 Cr Pb2 6.3(16) . 1_545 ? 
Pb2 Cr Pb2 119.2(3) 2_667 1_545 ? 
Pb1 Cr Pb2 55.74(16) 1_655 1_545 ? 
Pb1 Cr Pb2 63.02(16) . 1_545 ? 
Pb2 Cr Pb2 112.0(3) 2_767 1_545 ? 
Pb1 Cr Pb2 70.79(17) 2_657 1_545 ? 
Pb2 Cr Pb2 128.4(3) . 1_545 ? 
Pb2 Cr Pb2 120.5(3) 1_655 1_545 ? 
Cr O1 Pb2 134(2) . . ? 
Cr O1 Pb2 99.5(19) . 2_667 ? 
Pb2 O1 Pb2 104.3(13) . 2_667 ? 
Cr O1 Pb1 102.5(17) . . ? 
Pb2 O1 Pb1 97.7(13) . . ? 
Pb2 O1 Pb1 121.6(14) 2_667 . ? 
Cr O2 Pb2 158(2) 1_455 . ? 
Cr O2 Pb1 97.5(16) 1_455 . ? 
Pb2 O2 Pb1 100.4(13) . . ? 
Cr O2 Pb2 80.7(16) 1_455 2_667 ? 
Pb2 O2 Pb2 83.4(10) . 2_667 ? 
Pb1 O2 Pb2 101.3(12) . 2_667 ? 
Cr O2 Pb2 76.5(14) 1_455 1_455 ? 
Pb2 O2 Pb2 99.1(11) . 1_455 ? 
Pb1 O2 Pb2 135.2(13) . 1_455 ? 
Pb2 O2 Pb2 120.8(11) 2_667 1_455 ? 
Cr O3 Pb2 119(2) 1_554 2_766 ? 
Cr O3 Pb1 119(2) 1_554 2_656 ? 
Pb2 O3 Pb1 93.1(14) 2_766 2_656 ? 
Cr O3 Pb2 91.3(18) 1_554 2_666 ? 
Pb2 O3 Pb2 134.4(17) 2_766 2_666 ? 
Pb1 O3 Pb2 100.6(13) 2_656 2_666 ? 
Cr O4 Pb1 97.8(18) . 1_655 ? 
Cr O4 Pb2 170(3) . 1_545 ? 
Pb1 O4 Pb2 87.5(13) 1_655 1_545 ? 
Cr O4 Pb1 92.1(18) . . ? 
Pb1 O4 Pb1 118.6(16) 1_655 . ? 
Pb2 O4 Pb1 92.9(12) 1_545 . ? 
Cr O4 Pb1 77.3(16) . 2_657 ? 
Pb1 O4 Pb1 115.3(14) 1_655 2_657 ? 
Pb2 O4 Pb1 92.7(12) 1_545 2_657 ? 
Pb1 O4 Pb1 125.9(13) . 2_657 ? 
Mn2 O5 Mn1 97(2) 1_655 . ? 
Mn2 O5 Mn2 96.8(18) 1_655 2_666 ? 
Mn1 O5 Mn2 94.7(18) . 2_666 ? 
Mn2 O5 Pb2 149(2) 1_655 2_666 ? 
Mn1 O5 Pb2 107.0(16) . 2_666 ? 
Mn2 O5 Pb2 99.8(16) 2_666 2_666 ? 
Mn2 O5 Pb1 78.7(13) 1_655 2_656 ? 
Mn1 O5 Pb1 79.6(12) . 2_656 ? 
Mn2 O5 Pb1 172.2(19) 2_666 2_656 ? 
Pb2 O5 Pb1 87.1(11) 2_666 2_656 ? 
Mn2 O6 Mn2 97.4(19) . 2_666 ? 
Mn2 O6 Mn1 96.9(18) . 2_666 ? 
Mn2 O6 Mn1 95.4(18) 2_666 2_666 ? 
Mn2 O6 Pb2 103.8(16) . 2_666 ? 
Mn2 O6 Pb2 94.9(15) 2_666 2_666 ? 
Mn1 O6 Pb2 155(2) 2_666 2_666 ? 
Mn2 O6 Pb1 175.7(19) . 2_666 ? 
Mn2 O6 Pb1 80.5(12) 2_666 2_666 ? 
Mn1 O6 Pb1 79.7(12) 2_666 2_666 ? 
Pb2 O6 Pb1 80.1(10) 2_666 2_666 ? 
Mn1 O7 Mn1 98(2) 2_656 . ? 
Mn1 O7 Pb1 130(2) 2_656 . ? 
Mn1 O7 Pb1 123(2) . . ? 
Mn1 O7 Pb1 88.7(16) 2_656 1_655 ? 
Mn1 O7 Pb1 84.6(14) . 1_655 ? 
Pb1 O7 Pb1 119.3(16) . 1_655 ? 
Mn1 O7 Pb2 70.7(13) 2_656 1_545 ? 
Mn1 O7 Pb2 145.9(19) . 1_545 ? 
Pb1 O7 Pb2 85.3(12) . 1_545 ? 
Pb1 O7 Pb2 63.5(8) 1_655 1_545 ? 
Mn1 O7 Pb1 68.6(13) 2_656 2_556 ? 
Mn1 O7 Pb1 71.1(13) . 2_556 ? 
Pb1 O7 Pb1 97.5(13) . 2_556 ? 
Pb1 O7 Pb1 143.1(13) 1_655 2_556 ? 
Pb2 O7 Pb1 128.4(11) 1_545 2_556 ? 
Mn2 O8 Mn1 99(2) . . ? 
Mn2 O8 Pb1 126(2) . 2_556 ? 
Mn1 O8 Pb1 124(2) . 2_556 ? 
Mn2 O8 Pb2 108.5(18) . 2_666 ? 
Mn1 O8 Pb2 99.5(15) . 2_666 ? 
Pb1 O8 Pb2 96.1(14) 2_556 2_666 ? 
Mn2 O8 Pb1 68.6(13) . . ? 
Mn1 O8 Pb1 67.3(12) . . ? 
Pb1 O8 Pb1 97.1(12) 2_556 . ? 
Pb2 O8 Pb1 165.1(14) 2_666 . ? 
Mn2 O9 Mn1 100(2) 1_655 . ? 
Mn2 O9 Pb1 132(2) 1_655 1_655 ? 
Mn1 O9 Pb1 124.6(18) . 1_655 ? 
Mn2 O9 Pb2 74.2(12) 1_655 1_655 ? 
Mn1 O9 Pb2 132.5(17) . 1_655 ? 
Pb1 O9 Pb2 86.3(11) 1_655 1_655 ? 
Mn2 O9 Pb1 71.9(12) 1_655 2_656 ? 
Mn1 O9 Pb1 72.6(11) . 2_656 ? 
Pb1 O9 Pb1 102.4(12) 1_655 2_656 ? 
Pb2 O9 Pb1 141.0(11) 1_655 2_656 ? 
 
_diffrn_measured_fraction_theta_max    0.981 
_diffrn_reflns_theta_full              20.02 
_diffrn_measured_fraction_theta_full   0.981 
_refine_diff_density_max    3.222 
_refine_diff_density_min   -3.035 
_refine_diff_density_rms    0.773