Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:

Uptake, Site Preference and

Degradation of Monoclinic Structure

Michael E. Fleet, Xioayang Liu

and Yuanming Pan

 

 

Deposited Material

 

 

Table 5. List of observed and calculated structure factors

 

 

(a) P63/m structure of La-chlorapatite

H K L FO FC H K L FO FC H K L FO FC

0 0 2 100.1 106.0 -3 1 0 42.1 43.3 -5 4 7 0.0 6.0

0 0 4 186.1 198.3 -3 0 10 0.0 5.3 -5 4 6 0.0 14.5

0 0 6 98.0 98.7 -3 0 9 0.0 5.4 -5 4 5 0.0 0.7

0 0 8 79.4 73.3 -3 0 8 31.8 31.3 -5 4 4 47.3 47.7

0 0 10 0.0 39.9 -3 0 7 0.0 9.0 -5 4 3 17.2 18.5

-1 0 10 0.0 11.6 -3 0 6 12.1 12.1 -5 4 2 29.2 29.8

-1 0 9 0.0 2.6 -3 0 5 0.0 10.2 -5 4 1 0.0 3.6

-1 0 8 16.1 15.7 -3 0 4 73.7 73.9 -5 4 0 64.6 65.8

-1 0 7 0.0 5.4 -3 0 3 24.9 24.8 5 -3 10 0.0 1.8

-1 0 6 19.4 20.1 -3 0 2 40.1 39.4 -5 3 9 0.0 18.4

-1 0 5 0.0 7.5 -3 0 1 27.0 26.2 -5 3 8 22.5 22.1

-1 0 4 23.3 23.3 -3 0 0 158.3 153.8 -5 3 7 17.9 19.8

-1 0 3 0.0 4.0 -4 3 10 0.0 17.3 -5 3 6 0.0 5.7

-1 0 2 0.0 0.1 -4 3 9 0.0 12.4 -5 3 5 49.3 49.8

-1 0 1 15.8 15.9 -4 3 8 0.0 13.3 -5 3 4 38.2 38.7

-1 0 0 13.7 14.1 -4 3 7 24.9 24.8 -5 3 3 17.8 18.0

-2 1 10 0.0 28.3 -4 3 6 44.0 44.8 -5 3 2 14.1 14.0

-2 1 9 0.0 7.5 -4 3 5 26.7 26.3 -5 3 1 63.8 63.8

-2 1 8 0.0 0.4 -4 3 4 0.0 5.6 -5 3 0 59.8 58.7

-2 1 7 0.0 4.7 -4 3 3 39.3 39.4 5 -2 10 0.0 16.8

-2 1 6 61.8 61.3 -4 3 2 28.9 28.9 -5 2 9 0.0 16.7

-2 1 5 11.2 12.2 -4 3 1 42.9 43.2 -5 2 8 0.0 0.2

-2 1 4 0.0 7.2 -4 3 0 92.2 87.9 -5 2 7 25.6 26.1

-2 1 3 42.7 42.2 -4 2 10 0.0 24.5 -5 2 6 31.3 30.5

2 -1 2 0.0 111.8 -4 2 9 0.0 0.1 -5 2 5 28.3 28.8

-2 1 1 12.8 12.9 -4 2 8 0.0 4.4 -5 2 4 0.0 10.4

-2 1 0 0.0 0.3 -4 2 7 0.0 2.6 -5 2 3 52.4 52.7

-2 0 10 0.0 11.0 -4 2 6 47.1 47.5 -5 2 2 39.4 39.7

-2 0 9 0.0 1.4 -4 2 5 0.0 9.4 -5 2 1 51.7 51.7

-2 0 8 0.0 8.8 -4 2 4 0.0 0.1 -5 2 0 14.9 15.4

-2 0 7 0.0 1.5 -4 2 3 9.7 9.9 5 -1 10 0.0 4.7

-2 0 6 20.2 20.0 -4 2 2 116.8 115.4 -5 1 9 0.0 0.3

-2 0 5 19.3 20.2 -4 2 1 6.9 7.6 -5 1 8 0.0 18.0

-2 0 4 0.0 6.0 -4 2 0 17.5 18.4 -5 1 7 0.0 2.5

-2 0 3 26.8 26.0 -4 1 10 0.0 11.5 -5 1 6 0.0 10.9

-2 0 2 37.9 37.6 -4 1 9 0.0 13.9 -5 1 5 0.0 2.1

-2 0 1 22.9 22.6 -4 1 8 0.0 4.3 -5 1 4 49.9 50.2

-2 0 0 4.6 4.1 -4 1 7 0.0 7.2 -5 1 3 0.0 1.3

-3 2 10 0.0 6.8 -4 1 6 14.6 15.3 -5 1 2 35.7 35.7

-3 2 9 0.0 20.6 -4 1 5 0.0 5.0 -5 1 1 0.0 2.4

-3 2 8 30.8 31.9 -4 1 4 0.0 4.8 -5 1 0 93.7 93.7

-3 2 7 34.1 34.2 -4 1 3 40.9 40.7 -5 0 9 0.0 2.2

-3 2 6 14.5 15.4 -4 1 2 38.0 37.8 -5 0 8 0.0 9.3

-3 2 5 38.1 37.7 -4 1 1 8.7 7.4 -5 0 7 0.0 3.3

-3 2 4 40.7 40.8 -4 1 0 18.9 18.6 -5 0 6 34.1 33.2

-3 2 3 64.9 65.1 4 0 10 0.0 22.3 -5 0 5 23.7 25.2

-3 2 2 50.9 49.4 -4 0 9 0.0 3.0 -5 0 4 18.8 18.4

-3 2 1 68.8 69.6 -4 0 8 0.0 6.2 -5 0 3 0.0 9.0

-3 2 0 0.0 0.7 -4 0 7 0.0 9.3 -5 0 2 53.3 53.0

-3 1 10 0.0 1.3 -4 0 6 38.7 38.1 -5 0 1 33.6 33.2

-3 1 9 30.7 33.6 -4 0 5 13.1 13.4 -5 0 0 14.3 13.7

-3 1 8 21.5 21.3 -4 0 4 13.4 14.4 -6 5 9 0.0 7.9

-3 1 7 36.7 36.3 -4 0 3 0.0 3.1 -6 5 8 0.0 17.8

-3 1 6 0.0 0.1 -4 0 2 51.8 52.3 -6 5 7 0.0 18.8

-3 1 5 58.9 58.7 -4 0 1 12.5 12.8 -6 5 6 0.0 15.0

-3 1 4 29.4 29.6 -4 0 0 27.9 28.1 -6 5 5 18.8 20.0

-3 1 3 81.9 81.6 -5 4 10 0.0 6.5 -6 5 4 12.9 12.0

-3 1 2 9.5 8.4 -5 4 9 0.0 5.2 -6 5 3 18.1 19.0

-3 1 1 97.7 98.2 -5 4 8 25.2 24.8 -6 5 2 0.0 0.7

H K L FO FC H K L FO FC H K L FO FC

-6 5 1 29.4 29.7 -7 6 5 0.0 13.6 -7 0 6 25.8 26.1

-6 5 0 0.0 5.4 -7 6 4 40.9 40.8 -7 0 5 0.0 1.1

-6 4 10 0.0 4.9 -7 6 3 15.2 14.9 -7 0 4 0.0 13.2

-6 4 9 0.0 20.9 -7 6 2 33.8 34.3 -7 0 3 21.7 21.9

-6 4 8 33.4 33.0 -7 6 1 19.1 20.1 -7 0 2 35.2 35.7

-6 4 7 0.0 18.9 -7 6 0 27.6 28.1 -7 0 1 0.0 4.7

-6 4 6 0.0 15.4 -7 5 9 0.0 6.6 -7 0 0 17.1 17.5

-6 4 5 24.3 23.6 -7 5 8 0.0 7.6 8 -7 9 0.0 8.5

-6 4 4 48.7 48.2 -7 5 7 0.0 7.4 -8 7 8 32.7 31.5

-6 4 3 46.9 47.2 -7 5 6 21.4 22.1 -8 7 7 0.0 10.7

-6 4 2 38.1 38.1 -7 5 5 0.0 8.5 -8 7 6 0.0 4.8

-6 4 1 31.9 32.6 -7 5 4 0.0 5.7 -8 7 5 0.0 2.0

-6 4 0 58.0 57.4 -7 5 3 0.0 10.6 -8 7 4 53.7 52.4

-6 3 10 0.0 14.9 -7 5 2 82.2 82.0 -8 7 3 26.3 27.3

-6 3 9 0.0 9.6 -7 5 1 0.0 11.2 -8 7 2 0.0 4.3

-6 3 8 0.0 10.4 -7 5 0 47.9 47.6 -8 7 1 0.0 10.9

-6 3 7 0.0 18.1 -7 4 9 0.0 2.1 -8 7 0 66.7 64.6

-6 3 6 28.9 28.9 -7 4 8 0.0 13.2 -8 6 9 0.0 2.2

-6 3 5 29.0 29.0 -7 4 7 0.0 2.1 -8 6 8 0.0 21.9

-6 3 4 25.4 26.4 -7 4 6 42.6 41.7 -8 6 7 0.0 3.1

-6 3 3 16.2 15.1 -7 4 5 0.0 8.0 -8 6 6 0.0 1.9

-6 3 2 49.5 49.9 -7 4 4 29.1 29.5 -8 6 5 0.0 0.6

-6 3 1 39.2 39.6 -7 4 3 0.0 3.0 -8 6 4 27.6 28.1

-6 3 0 39.0 39.1 -7 4 2 61.2 61.4 -8 6 3 0.0 4.0

-6 2 10 0.0 0.7 -7 4 1 0.0 9.6 -8 6 2 0.0 13.6

-6 2 9 0.0 7.0 -7 4 0 41.8 42.5 -8 6 1 0.0 2.2

-6 2 8 38.8 37.9 -7 3 9 0.0 14.9 -8 6 0 17.1 16.3

-6 2 7 0.0 16.4 -7 3 8 0.0 13.3 -8 5 9 0.0 2.5

-6 2 6 0.0 4.9 -7 3 7 26.7 27.0 -8 5 8 0.0 13.3

-6 2 5 16.3 16.9 -7 3 6 0.0 9.5 -8 5 7 0.0 5.2

-6 2 4 44.8 44.0 -7 3 5 21.9 22.3 -8 5 6 41.1 40.8

-6 2 3 27.1 27.5 -7 3 4 17.9 19.7 -8 5 5 0.0 7.2

-6 2 2 49.5 49.3 -7 3 3 53.7 53.8 -8 5 4 26.7 26.4

-6 2 1 30.8 30.7 -7 3 2 0.0 1.3 -8 5 3 0.0 8.0

-6 2 0 10.8 9.7 -7 3 1 41.9 42.3 -8 5 2 52.7 52.1

-6 1 9 0.0 30.5 -7 3 0 16.5 15.6 -8 5 1 0.0 10.0

-6 1 8 39.0 37.8 -7 2 9 0.0 15.6 -8 5 0 38.4 37.8

-6 1 7 33.6 33.7 -7 2 8 0.0 15.6 -8 4 9 0.0 4.5

-6 1 6 0.0 9.6 -7 2 7 20.9 21.9 -8 4 8 32.9 35.1

-6 1 5 52.8 52.9 -7 2 6 0.0 2.9 -8 4 7 0.0 12.8

-6 1 4 52.8 53.1 -7 2 5 20.6 21.3 -8 4 6 0.0 6.1

-6 1 3 58.8 59.0 -7 2 4 38.6 38.7 -8 4 5 25.0 26.0

-6 1 2 48.3 48.8 -7 2 3 38.4 37.9 -8 4 4 61.6 60.6

-6 1 1 72.6 71.9 -7 2 2 27.2 27.8 -8 4 3 0.0 8.7

-6 1 0 43.1 43.0 -7 2 1 33.1 33.8 -8 4 2 0.0 5.5

-6 0 9 0.0 9.9 -7 2 0 76.3 76.5 -8 4 1 33.0 34.1

-6 0 8 0.0 7.6 -7 1 9 0.0 1.7 -8 4 0 76.1 74.7

-6 0 7 0.0 15.2 -7 1 8 0.0 15.8 8 -3 9 0.0 3.2

-6 0 6 33.0 32.9 -7 1 7 0.0 5.1 -8 3 8 0.0 3.9

-6 0 5 0.0 7.3 -7 1 6 0.0 0.9 -8 3 7 0.0 10.7

-6 0 4 15.7 17.4 -7 1 5 0.0 7.4 -8 3 6 0.0 15.7

-6 0 3 27.8 28.0 -7 1 4 23.5 23.8 -8 3 5 0.0 3.1

-6 0 2 49.2 49.3 -7 1 3 0.0 4.9 -8 3 4 0.0 2.0

-6 0 1 14.0 13.6 -7 1 2 0.0 5.0 -8 3 3 17.2 19.6

-6 0 0 21.1 22.8 -7 1 1 0.0 9.0 -8 3 2 17.3 17.8

-7 6 9 0.0 9.7 -7 1 0 29.7 30.2 -8 3 1 0.0 10.4

-7 6 8 29.4 30.7 -7 0 9 0.0 6.3 -8 3 0 0.0 0.5

-7 6 7 0.0 5.3 -7 0 8 0.0 4.9 8 -2 9 0.0 2.4

-7 6 6 0.0 3.0 -7 0 7 0.0 8.2 -8 2 8 0.0 4.0

H K L FO FC H K L FO FC H K L FO FC

-8 2 7 0.0 4.8 -9 5 3 0.0 16.7 -10 8 5 0.0 13.2

-8 2 6 0.0 12.4 -9 5 2 0.0 2.1 -10 8 4 0.0 6.4

-8 2 5 0.0 11.5 -9 5 1 26.0 26.4 -10 8 3 16.7 16.9

-8 2 4 0.0 2.8 -9 5 0 0.0 9.1 -10 8 2 49.3 46.6

-8 2 3 0.0 6.8 -9 4 8 0.0 16.0 -10 8 1 0.0 17.9

-8 2 2 16.2 18.2 -9 4 7 0.0 8.4 -10 8 0 23.5 25.9

-8 2 1 0.0 11.6 -9 4 6 0.0 17.5 -10 8 8 0.0 4.3

-8 2 0 0.0 5.5 -9 4 5 0.0 15.1 -10 7 8 0.0 6.2

8 -1 9 0.0 5.0 -9 4 4 0.0 8.0 -10 7 7 0.0 7.5

-8 1 8 0.0 8.1 -9 4 3 0.0 14.2 -10 7 6 0.0 20.3

-8 1 7 0.0 9.2 -9 4 2 0.0 3.3 -10 7 5 0.0 13.1

-8 1 6 0.0 12.1 -9 4 1 18.4 18.3 -10 7 4 0.0 2.5

-8 1 5 0.0 12.4 -9 4 0 0.0 14.7 -10 7 3 0.0 7.2

-8 1 4 24.9 24.6 -9 3 8 0.0 6.5 -10 7 2 0.0 10.5

-8 1 3 0.0 9.6 -9 3 7 34.0 35.1 -10 7 1 0.0 14.6

-8 1 2 40.4 41.4 -9 3 6 41.6 40.8 -10 7 0 17.8 16.2

-8 1 1 14.1 14.6 -9 3 5 46.0 44.9 -10 6 8 0.0 13.5

-8 1 0 47.7 46.0 -9 3 4 0.0 7.1 -10 6 7 0.0 3.5

-8 0 8 0.0 15.5 -9 3 3 46.8 46.6 -10 6 6 0.0 0.5

-8 0 7 0.0 2.8 -9 3 2 65.8 64.9 -10 6 5 0.0 4.7

-8 0 6 50.9 48.9 -9 3 1 60.8 60.6 -10 6 4 0.0 17.3

-8 0 5 0.0 3.3 -9 3 0 0.0 5.8 -10 6 3 0.0 1.0

-8 0 4 35.3 35.4 -9 2 8 0.0 18.6 -10 6 2 0.0 3.0

-8 0 3 0.0 5.0 -9 2 7 0.0 12.4 -10 6 1 0.0 1.6

-8 0 2 52.9 52.9 -9 2 6 0.0 0.8 -10 6 0 17.1 17.8

-8 0 1 0.0 1.0 -9 2 5 0.0 15.3 -10 5 8 0.0 1.4

-8 0 0 57.4 57.1 -9 2 4 0.0 21.0 -10 5 7 0.0 17.6

-9 8 8 0.0 9.4 -9 2 3 0.0 16.7 -10 5 6 0.0 11.3

-9 8 7 0.0 5.6 -9 2 2 0.0 9.9 -10 5 5 24.1 24.1

-9 8 6 0.0 2.4 -9 2 1 17.7 19.1 -10 5 4 0.0 13.3

-9 8 5 0.0 3.0 -9 2 0 13.5 15.1 -10 5 3 25.3 25.7

-9 8 4 0.0 13.2 -9 1 8 0.0 10.5 -10 5 2 40.4 40.2

-9 8 3 0.0 0.0 -9 1 7 0.0 6.4 -10 5 1 30.1 31.0

-9 8 2 0.0 1.0 -9 1 6 0.0 24.9 -10 5 0 35.6 37.7

-9 8 1 0.0 7.3 -9 1 5 0.0 11.2 -10 4 8 0.0 8.9

-9 8 0 16.1 16.9 -9 1 4 0.0 3.6 -10 4 7 0.0 0.3

-9 7 8 0.0 20.4 -9 1 3 0.0 12.3 -10 4 6 0.0 17.9

-9 7 7 0.0 13.8 -9 1 2 0.0 3.0 -10 4 5 0.0 4.9

-9 7 6 0.0 6.0 -9 1 1 0.0 14.6 -10 4 4 0.0 5.0

-9 7 5 0.0 10.6 -9 1 0 20.3 22.2 -10 4 3 0.0 3.1

-9 7 4 27.1 25.5 -9 0 8 0.0 4.2 -10 4 2 0.0 6.4

-9 7 3 20.7 21.8 -9 0 7 0.0 17.0 -10 4 1 0.0 5.1

-9 7 2 16.0 15.8 -9 0 6 0.0 21.2 -10 4 0 0.0 10.2

-9 7 1 14.8 16.7 -9 0 5 0.0 15.5 -10 3 8 0.0 11.0

-9 7 0 25.1 25.5 -9 0 4 0.0 8.2 -10 3 7 0.0 13.8

-9 6 8 0.0 1.0 -9 0 3 28.4 28.5 -10 3 6 0.0 1.2

-9 6 7 0.0 8.8 -9 0 2 38.8 37.7 -10 3 5 0.0 2.8

-9 6 6 39.0 38.2 -9 0 1 24.3 24.0 -10 3 4 0.0 16.1

-9 6 5 20.0 20.9 -9 0 0 0.0 16.3 -10 3 3 23.6 25.3

-9 6 4 0.0 0.7 -10 9 7 0.0 10.4 -10 3 2 0.0 1.5

-9 6 3 0.0 0.3 -10 9 6 0.0 1.2 -10 3 1 0.0 9.7

-9 6 2 55.3 55.1 -10 9 5 0.0 9.3 -10 3 0 19.7 19.8

-9 6 1 19.2 21.6 -10 9 4 0.0 12.6 -10 2 8 0.0 13.5

-9 6 0 0.0 2.3 -10 9 3 19.8 20.6 -10 2 7 0.0 2.4

-9 5 8 0.0 12.7 -10 9 2 0.0 0.2 -10 2 6 0.0 6.5

-9 5 7 0.0 9.2 -10 9 1 0.0 12.3 -10 2 5 0.0 1.1

-9 5 6 0.0 7.1 -10 9 0 0.0 13.4 -10 2 4 24.8 25.8

-9 5 5 20.6 21.4 -10 8 7 0.0 9.7 -10 2 3 0.0 1.1

-9 5 4 0.0 13.6 -10 8 6 0.0 18.2 -10 2 2 0.0 17.0

H K L FO FC H K L FO FC H K L FO FC

-10 2 1 0.0 0.3 -11 5 5 0.0 6.3 -12 9 4 0.0 20.6

-10 2 0 39.1 38.2 -11 5 4 0.0 7.8 -12 9 3 0.0 8.2

-10 1 7 0.0 18.9 -11 5 3 0.0 16.9 -12 9 2 0.0 12.9

-10 1 6 0.0 0.7 -11 5 2 0.0 6.0 -12 9 1 0.0 8.1

-10 1 5 0.0 13.2 -11 5 1 0.0 10.1 -12 9 0 28.5 28.6

-10 1 4 0.0 17.7 -11 5 0 0.0 2.2 -12 8 6 0.0 19.3

-10 1 3 29.7 29.1 -11 4 7 0.0 7.8 -12 8 5 0.0 20.9

-10 1 2 0.0 5.0 -11 4 6 0.0 5.1 -12 8 4 0.0 10.4

-10 1 1 0.0 21.2 -11 4 5 0.0 7.7 -12 8 3 0.0 11.3

-10 1 0 0.0 14.1 -11 4 4 29.3 29.4 -12 8 2 26.4 24.4

-10 0 7 0.0 1.2 -11 4 3 0.0 10.7 -12 8 1 22.0 22.0

-10 0 6 0.0 1.5 -11 4 2 0.0 9.8 -12 8 0 0.0 12.8

-10 0 5 0.0 5.7 -11 4 1 0.0 11.4 -12 7 6 0.0 7.4

-10 0 4 0.0 11.2 -11 4 0 38.8 36.0 -12 7 5 0.0 3.1

-10 0 3 0.0 5.9 -11 3 7 0.0 13.6 -12 7 4 0.0 5.0

-10 0 2 0.0 2.6 -11 3 6 0.0 12.7 -12 7 3 0.0 3.7

-10 0 1 0.0 4.1 -11 3 5 0.0 15.4 -12 7 2 0.0 2.2

-10 0 0 0.0 10.0 -11 3 4 0.0 0.6 -12 7 1 0.0 3.2

-11 10 6 0.0 1.1 -11 3 3 0.0 13.7 -12 7 0 0.0 1.6

-11 10 5 0.0 11.2 -11 3 2 0.0 6.7 -12 6 6 0.0 14.3

-11 10 4 29.9 29.5 -11 3 1 20.9 21.2 -12 6 5 0.0 13.2

-11 10 3 0.0 12.0 -11 3 0 0.0 5.7 -12 6 4 0.0 12.7

-11 10 2 0.0 5.1 -11 2 7 0.0 7.1 -12 6 3 0.0 10.3

-11 10 1 0.0 12.3 -11 2 6 0.0 3.8 -12 6 2 26.8 28.0

-11 10 0 39.5 39.2 -11 2 5 0.0 6.1 -12 6 1 0.0 15.3

-11 9 7 0.0 19.8 -11 2 4 0.0 18.3 -12 6 0 21.4 21.8

-11 9 6 0.0 0.9 -11 2 3 0.0 16.8 -12 5 6 0.0 7.4

-11 9 5 29.1 28.0 -11 2 2 0.0 7.9 -12 5 5 0.0 19.0

-11 9 4 0.0 19.5 -11 2 1 0.0 8.8 -12 5 4 0.0 3.4

-11 9 3 29.0 27.7 -11 2 0 0.0 19.3 -12 5 3 0.0 9.5

-11 9 2 0.0 10.4 -11 1 6 0.0 18.2 -12 5 2 0.0 8.3

-11 9 1 34.4 34.9 -11 1 5 0.0 23.1 -12 5 1 23.0 21.3

-11 9 0 0.0 13.4 -11 1 4 0.0 8.7 -12 5 0 0.0 4.7

-11 8 7 0.0 2.6 -11 1 3 34.3 33.5 -12 4 6 0.0 33.3

-11 8 6 0.0 26.8 -11 1 2 27.8 29.6 -12 4 5 0.0 2.6

-11 8 5 0.0 5.2 -11 1 1 30.4 30.8 -12 4 4 0.0 20.5

-11 8 4 0.0 5.8 -11 1 0 0.0 13.0 -12 4 3 0.0 6.7

-11 8 3 0.0 5.2 11 0 6 0.0 15.6 -12 4 2 27.1 28.4

-11 8 2 16.9 15.3 -11 0 5 0.0 15.3 -12 4 1 0.0 5.5

-11 8 1 0.0 5.6 -11 0 4 0.0 2.1 -12 4 0 37.2 35.6

-11 8 0 23.3 23.8 -11 0 3 0.0 17.5 -12 3 6 0.0 8.0

-11 7 7 0.0 3.0 -11 0 2 0.0 0.7 -12 3 5 0.0 11.4

-11 7 6 0.0 4.6 -11 0 1 0.0 18.8 -12 3 4 0.0 11.5

-11 7 5 0.0 7.6 -11 0 0 0.0 11.3 -12 3 3 0.0 12.2

-11 7 4 40.9 40.2 -12 11 5 0.0 8.7 -12 3 2 27.4 27.7

-11 7 3 0.0 0.5 -12 11 4 0.0 5.1 -12 3 1 0.0 14.3

-11 7 2 0.0 3.6 -12 11 3 0.0 8.2 -12 3 0 0.0 26.8

-11 7 1 0.0 7.7 -12 11 2 0.0 3.6 -12 2 5 0.0 12.6

-11 7 0 52.4 49.9 -12 11 1 0.0 9.2 -12 2 4 0.0 9.7

-11 6 7 0.0 19.7 -12 11 0 0.0 0.7 -12 2 3 0.0 17.5

-11 6 6 0.0 11.2 -12 10 6 0.0 8.2 -12 2 2 0.0 0.8

-11 6 5 26.8 27.2 -12 10 5 0.0 14.2 -12 2 1 0.0 18.0

-11 6 4 30.8 29.6 -12 10 4 0.0 20.7 -12 2 0 0.0 10.9

-11 6 3 0.0 20.1 -12 10 3 32.8 31.4 -12 2 6 0.0 1.1

-11 6 2 19.9 20.1 -12 10 2 0.0 11.8 -12 1 5 0.0 2.0

-11 6 1 32.4 32.1 -12 10 1 0.0 22.4 -12 1 4 0.0 17.2

-11 6 0 33.1 32.5 -12 10 0 0.0 23.9 -12 1 3 0.0 2.1

-11 5 7 0.0 8.6 -12 9 6 0.0 5.6 -12 1 2 0.0 27.4

-11 5 6 0.0 9.1 -12 9 5 0.0 5.4 -12 1 1 0.0 0.8

H K L FO FC H K L FO FC H K L FO FC

-12 1 0 25.2 28.4 -13 6 0 0.0 15.3 -14 9 2 0.0 8.2

-12 0 4 0.0 22.7 -13 5 5 0.0 14.5 -14 9 1 28.5 30.2

-12 0 3 0.0 3.0 -13 5 4 0.0 23.6 -14 9 0 0.0 17.7

-12 0 2 0.0 5.5 -13 5 3 0.0 8.2 -14 8 4 0.0 13.3

-12 0 1 0.0 5.5 -13 5 2 0.0 5.7 -14 8 3 0.0 2.0

-12 0 0 35.5 36.4 -13 5 1 0.0 15.3 -14 8 2 0.0 6.6

-13 12 3 0.0 6.0 -13 5 0 28.4 30.6 -14 8 1 0.0 6.4

-13 12 2 0.0 20.7 13 -4 5 0.0 0.6 -14 8 0 0.0 7.7

-13 12 1 0.0 0.7 -13 4 4 0.0 2.1 -14 7 4 0.0 1.8

-13 12 0 0.0 13.9 -13 4 3 0.0 6.2 -14 7 3 0.0 13.6

-13 12 4 0.0 10.4 -13 4 2 0.0 10.9 -14 7 2 0.0 26.5

-13 11 4 0.0 2.1 -13 4 1 0.0 3.7 -14 7 1 0.0 18.2

-13 11 3 0.0 10.9 -13 4 0 0.0 14.5 -14 7 0 0.0 8.0

-13 11 2 0.0 31.5 -13 3 4 0.0 22.5 -14 6 3 0.0 15.2

-13 11 1 0.0 12.5 -13 3 3 0.0 8.3 -14 6 2 0.0 7.1

-13 11 0 0.0 1.6 -13 3 2 0.0 15.1 -14 6 1 0.0 22.8

-13 10 5 0.0 14.5 -13 3 1 0.0 6.2 -14 6 0 0.0 16.3

-13 10 4 0.0 0.8 -13 3 0 0.0 22.2 -14 6 4 0.0 14.1

-13 10 3 0.0 15.5 -13 3 5 0.0 4.5 -14 5 3 0.0 2.8

-13 10 2 0.0 5.6 -13 2 3 0.0 14.8 -14 5 2 0.0 15.9

-13 10 1 0.0 17.0 -13 2 2 0.0 12.4 -14 5 1 0.0 0.9

-13 10 0 0.0 8.9 -13 2 1 0.0 7.3 -14 5 0 0.0 20.5

-13 9 5 0.0 0.5 -13 2 0 0.0 18.9 -14 4 3 0.0 6.6

-13 9 4 0.0 2.3 -13 2 4 0.0 15.4 -14 4 2 0.0 22.4

-13 9 3 0.0 7.5 13 -1 3 0.0 14.0 -14 4 1 0.0 0.9

-13 9 2 0.0 11.1 -13 1 2 0.0 0.1 -14 4 0 0.0 4.8

-13 9 1 0.0 1.0 -13 1 1 0.0 9.6 -14 3 1 0.0 8.9

-13 9 0 0.0 5.0 -13 1 0 0.0 6.1 -14 3 0 0.0 4.2

-13 8 5 0.0 0.2 13 0 2 0.0 0.4 -15 10 2 0.0 3.8

-13 8 4 0.0 6.6 -13 0 1 0.0 0.1 -15 10 1 0.0 1.7

-13 8 3 0.0 0.7 -13 0 0 0.0 6.3 -15 10 0 0.0 12.3

-13 8 2 0.0 26.7 14-12 1 0.0 3.4 -15 9 2 0.0 6.2

-13 8 1 0.0 0.6 14-12 0 0.0 10.6 -15 9 1 0.0 4.6

-13 8 0 0.0 12.1 -14 12 2 0.0 4.3 -15 9 0 0.0 22.8

-13 7 5 0.0 15.5 -14 11 3 0.0 1.1 -15 8 2 0.0 8.5

-13 7 4 0.0 2.2 -14 11 2 0.0 4.2 -15 8 1 0.0 7.4

-13 7 3 0.0 15.6 -14 11 1 0.0 3.7 -15 8 0 0.0 3.4

-13 7 2 0.0 7.4 -14 11 0 0.0 0.3 -15 7 2 0.0 25.5

-13 7 1 0.0 17.7 -14 10 4 0.0 3.3 -15 7 1 0.0 0.4

-13 7 0 0.0 19.2 -14 10 3 0.0 2.7 -15 7 0 0.0 19.3

-13 6 5 0.0 5.6 -14 10 2 0.0 26.3 -15 6 2 0.0 17.2

-13 6 4 0.0 17.2 -14 10 1 0.0 1.5 -15 6 1 0.0 11.1

-13 6 3 0.0 9.7 -14 10 0 0.0 12.5 -15 6 0 0.0 19.3

-13 6 2 0.0 9.9 -14 9 4 0.0 16.2 0 0 0 0.0 0.0

-13 6 1 0.0 9.1 -14 9 3 0.0 23.9 0 0 0 0.0 0.0

 

 

 

 

 

 

 

 

 

Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:

Uptake, Site Preference and

Degradation of Monoclinic Structure

Michael E. Fleet, Xioayang Liu

and Yuanming Pan

 

 

Deposited Material

 

 

Table 5. List of observed and calculated structure factors

 

 

(b) P63/m structure of Nd-chlorapatite

H K L FO FC H K L FO FC H K L FO FC

0 0 2 104.1 105.3 -3 1 5 58.1 58.0 -4 0 5 13.5 13.1

0 0 4 204.3 200.3 -3 1 4 29.2 29.5 -4 0 4 14.1 15.1

0 0 6 95.2 95.2 -3 1 3 82.1 82.9 -4 0 3 0.0 3.2

0 0 8 77.8 74.5 -3 1 2 9.6 8.3 -4 0 2 54.8 54.5

0 0 10 35.5 36.5 -3 1 1 98.2 98.7 -4 0 1 12.5 12.7

-1 0 11 0.0 4.6 -3 1 0 44.9 44.9 -4 0 0 28.7 29.0

-1 0 10 0.0 10.6 -3 0 11 0.0 2.2 -5 4 9 0.0 4.9

-1 0 9 0.0 2.1 -3 0 10 0.0 2.9 -5 4 8 25.5 27.0

-1 0 8 0.0 14.2 -3 0 9 0.0 5.0 -5 4 7 0.0 6.4

-1 0 7 0.0 4.6 -3 0 8 33.1 32.9 -5 4 6 0.0 16.1

-1 0 6 18.4 19.1 -3 0 7 0.0 8.8 -5 4 5 0.0 0.7

-1 0 5 0.0 7.8 -3 0 6 0.0 9.2 -5 4 4 50.5 50.3

-1 0 4 22.3 22.5 -3 0 5 10.0 9.8 -5 4 3 17.6 18.4

-1 0 3 0.0 4.5 -3 0 4 75.1 75.2 -5 4 2 29.8 30.2

-1 0 2 0.0 0.9 -3 0 3 24.3 24.3 -5 4 1 0.0 4.1

-1 0 1 15.7 15.8 -3 0 2 41.6 40.7 -5 4 0 68.7 68.9

-1 0 0 14.1 14.0 -3 0 1 26.5 25.9 -5 4 10 0.0 7.6

-2 1 11 0.0 1.1 -3 0 0 156.5 155.1 -5 3 9 0.0 17.4

-2 1 10 0.0 28.6 -4 3 11 0.0 11.3 -5 3 8 19.8 20.8

-2 1 9 0.0 7.0 4 -3 10 0.0 16.6 -5 3 7 19.7 19.8

-2 1 8 0.0 2.1 -4 3 9 0.0 12.0 -5 3 6 0.0 6.1

-2 1 7 0.0 4.5 -4 3 8 0.0 11.4 -5 3 5 48.7 48.9

-2 1 6 64.1 62.9 -4 3 7 24.2 23.5 -5 3 4 37.3 38.5

-2 1 5 10.8 11.5 -4 3 6 42.3 44.0 -5 3 3 19.0 19.5

-2 1 4 9.6 9.4 -4 3 5 26.2 25.9 -5 3 2 13.3 13.2

-2 1 3 42.9 42.4 -4 3 4 0.0 6.5 -5 3 1 63.7 64.2

-2 1 2 113.0 113.5 -4 3 3 38.2 38.3 -5 3 0 60.2 59.6

-2 1 1 12.5 12.3 -4 3 2 31.4 30.7 -5 3 10 0.0 1.8

-2 1 0 0.0 1.4 -4 3 1 42.1 42.6 -5 2 9 0.0 16.8

-2 0 11 0.0 2.5 -4 3 0 89.8 87.8 -5 2 8 0.0 0.9

-2 0 10 0.0 10.1 -4 2 11 0.0 2.8 -5 2 7 24.7 25.2

-2 0 9 0.0 0.9 -4 2 10 0.0 25.1 -5 2 6 29.4 28.9

-2 0 8 0.0 7.8 -4 2 9 0.0 0.0 -5 2 5 29.3 29.8

-2 0 7 0.0 1.4 -4 2 8 0.0 2.1 -5 2 4 0.0 9.6

-2 0 6 19.0 18.4 -4 2 7 0.0 3.1 -5 2 3 52.4 53.4

-2 0 5 18.1 19.1 -4 2 6 49.7 49.8 -5 2 2 39.1 40.2

-2 0 4 0.0 6.5 -4 2 5 0.0 9.7 -5 2 1 52.5 52.8

-2 0 3 26.3 25.9 -4 2 4 0.0 2.0 -5 2 0 13.8 13.0

-2 0 2 37.9 37.2 -4 2 3 9.4 8.9 -5 2 10 0.0 15.7

-2 0 1 21.9 21.6 -4 2 2 117.2 117.6 -5 1 10 0.0 6.2

-2 0 0 10.2 6.6 -4 2 1 0.0 8.9 -5 1 9 0.0 0.1

-3 2 11 0.0 16.8 -4 2 0 19.6 19.7 -5 1 8 0.0 20.0

-3 2 10 0.0 6.1 -4 1 11 0.0 3.3 -5 1 7 0.0 1.7

-3 2 9 0.0 20.4 -4 1 10 0.0 10.4 -5 1 6 0.0 13.8

-3 2 8 30.8 30.0 -4 1 9 0.0 12.6 -5 1 5 0.0 1.4

-3 2 7 32.8 33.2 -4 1 8 0.0 3.8 -5 1 4 51.6 52.3

-3 2 6 0.0 13.7 -4 1 7 0.0 7.3 -5 1 3 0.0 2.4

-3 2 5 38.5 38.2 -4 1 6 14.4 14.1 -5 1 2 37.1 37.6

-3 2 4 40.2 40.3 -4 1 5 0.0 5.5 -5 1 1 0.0 1.2

-3 2 3 64.5 65.0 -4 1 4 0.0 5.2 -5 1 0 95.1 94.3

-3 2 2 49.5 48.6 -4 1 3 40.6 40.2 -5 0 9 0.0 1.7

-3 2 1 69.5 70.2 -4 1 2 38.2 38.0 -5 0 8 0.0 9.8

-3 2 0 6.0 2.6 -4 1 1 8.7 7.7 -5 0 7 0.0 3.6

-3 1 11 0.0 15.9 -4 1 0 20.6 20.1 -5 0 6 32.6 32.5

-3 1 10 0.0 1.1 -4 0 10 0.0 20.8 -5 0 5 22.7 24.0

-3 1 9 32.6 32.2 -4 0 9 0.0 3.2 -5 0 4 19.1 18.9

-3 1 8 20.8 19.9 -4 0 8 0.0 7.0 -5 0 3 0.0 9.1

-3 1 7 36.4 36.3 -4 0 7 0.0 8.7 -5 0 2 54.4 54.6

-3 1 6 0.0 1.1 -4 0 6 39.2 37.6 -5 0 1 32.5 32.2

H K L FO FC H K L FO FC H K L FO FC

-5 0 0 13.8 13.6 -6 0 6 34.0 34.8 -7 1 8 0.0 15.6

5 0 10 0.0 18.9 -6 0 5 0.0 6.6 -7 1 7 0.0 6.0

-6 5 9 0.0 7.7 -6 0 4 18.1 19.3 -7 1 6 0.0 2.0

-6 5 8 0.0 16.3 -6 0 3 25.8 26.2 -7 1 5 0.0 8.5

-6 5 7 0.0 17.8 -6 0 2 51.5 51.1 -7 1 4 24.3 25.0

-6 5 6 0.0 14.0 -6 0 1 13.0 12.9 -7 1 3 0.0 3.0

-6 5 5 18.4 20.2 -6 0 0 22.2 24.2 -7 1 2 0.0 5.1

-6 5 4 0.0 12.5 -7 6 9 0.0 9.2 -7 1 1 0.0 11.2

-6 5 3 19.0 18.9 -7 6 8 30.0 29.1 -7 1 0 31.0 33.0

-6 5 2 0.0 1.9 -7 6 7 0.0 6.1 -7 0 9 0.0 5.9

-6 5 1 29.6 30.0 -7 6 6 0.0 3.3 -7 0 8 0.0 4.7

-6 5 0 0.0 2.5 -7 6 5 0.0 13.4 -7 0 7 0.0 7.7

6 -5 10 0.0 7.3 -7 6 4 40.5 41.3 -7 0 6 26.4 24.9

-6 4 9 0.0 19.9 -7 6 3 14.5 15.9 -7 0 5 0.0 0.9

-6 4 8 30.6 31.2 -7 6 2 32.1 32.9 -7 0 4 0.0 12.1

-6 4 7 0.0 18.6 -7 6 1 20.0 20.7 -7 0 3 19.4 21.1

-6 4 6 16.4 15.9 -7 6 0 29.2 30.0 -7 0 2 36.4 36.2

-6 4 5 23.3 23.3 7 -6 10 0.0 3.1 -7 0 1 0.0 4.4

-6 4 4 48.0 47.6 -7 5 9 0.0 6.9 -7 0 0 16.7 15.4

-6 4 3 46.7 47.5 -7 5 8 0.0 5.0 -8 7 8 32.2 33.0

-6 4 2 37.0 36.7 -7 5 7 0.0 8.1 -8 7 7 0.0 10.1

-6 4 1 32.1 32.8 -7 5 6 24.6 25.3 -8 7 6 0.0 2.6

-6 4 0 59.0 58.9 -7 5 5 0.0 9.7 -8 7 5 0.0 2.1

6 -4 10 0.0 4.7 -7 5 4 0.0 7.6 -8 7 4 55.4 54.3

-6 3 9 0.0 9.5 -7 5 3 0.0 12.1 -8 7 3 25.5 26.0

-6 3 8 0.0 12.4 -7 5 2 84.8 83.8 -8 7 2 0.0 3.0

-6 3 7 0.0 17.9 -7 5 1 0.0 13.0 -8 7 1 0.0 10.6

-6 3 6 31.0 31.3 -7 5 0 46.9 47.6 -8 7 0 68.2 66.9

-6 3 5 29.3 29.5 -7 4 9 0.0 1.5 8 -7 9 0.0 7.8

-6 3 4 27.6 27.5 -7 4 8 0.0 12.5 -8 6 9 0.0 1.2

-6 3 3 16.3 15.9 -7 4 7 0.0 2.2 -8 6 8 0.0 20.6

-6 3 2 51.3 52.4 -7 4 6 40.6 39.6 -8 6 7 0.0 2.9

-6 3 1 40.8 40.8 -7 4 5 0.0 8.2 -8 6 6 0.0 1.8

-6 3 0 39.8 39.7 -7 4 4 28.5 28.0 -8 6 5 0.0 0.3

6 -3 10 0.0 16.2 -7 4 3 0.0 2.2 -8 6 4 29.1 28.3

-6 2 9 0.0 6.5 -7 4 2 60.7 60.6 -8 6 3 0.0 4.1

-6 2 8 35.6 35.7 -7 4 1 0.0 10.0 -8 6 2 0.0 12.2

-6 2 7 0.0 15.0 -7 4 0 38.9 39.7 -8 6 1 0.0 2.7

-6 2 6 0.0 4.1 -7 3 9 0.0 14.5 -8 6 0 18.6 17.8

-6 2 5 15.5 16.2 -7 3 8 0.0 12.3 -8 5 9 0.0 2.7

-6 2 4 43.7 43.8 -7 3 7 26.2 26.4 -8 5 8 0.0 12.7

-6 2 3 25.7 26.1 -7 3 6 0.0 9.3 -8 5 7 0.0 4.3

-6 2 2 47.1 47.3 -7 3 5 22.3 22.4 -8 5 6 40.3 39.4

-6 2 1 29.5 29.6 -7 3 4 18.5 20.0 -8 5 5 0.0 6.8

-6 2 0 11.5 11.8 -7 3 3 52.8 52.8 -8 5 4 25.8 25.5

-6 1 9 0.0 29.0 -7 3 2 0.0 0.4 -8 5 3 0.0 7.5

-6 1 8 36.5 36.1 -7 3 1 41.8 42.4 -8 5 2 53.3 52.6

-6 1 7 33.4 33.2 -7 3 0 16.2 16.3 -8 5 1 0.0 8.9

-6 1 6 0.0 10.3 -7 2 9 0.0 15.0 -8 5 0 36.2 35.9

-6 1 5 52.8 51.8 -7 2 8 0.0 17.6 -8 4 9 0.0 4.3

-6 1 4 52.8 52.6 -7 2 7 21.7 21.7 -8 4 8 34.2 36.7

-6 1 3 59.5 59.3 -7 2 6 0.0 5.6 -8 4 7 0.0 12.2

-6 1 2 47.4 47.9 -7 2 5 21.4 21.9 -8 4 6 0.0 4.0

-6 1 1 71.9 71.5 -7 2 4 40.0 40.2 -8 4 5 25.4 24.8

-6 1 0 44.7 44.6 -7 2 3 37.7 38.0 -8 4 4 62.4 63.1

-6 0 10 0.0 17.7 -7 2 2 29.7 29.9 -8 4 3 0.0 8.1

-6 0 9 0.0 8.7 -7 2 1 33.3 34.9 -8 4 2 0.0 5.2

-6 0 8 0.0 9.8 -7 2 0 75.7 77.5 -8 4 1 32.4 32.8

-6 0 7 0.0 14.3 -7 1 9 0.0 1.1 -8 4 0 78.8 77.2

H K L FO FC H K L FO FC H K L FO FC

-8 3 9 0.0 3.4 -9 6 5 20.1 21.1 -9 0 1 23.2 23.4

-8 3 8 0.0 2.5 -9 6 4 0.0 1.3 -9 0 0 17.9 18.8

-8 3 7 0.0 9.7 -9 6 3 0.0 2.1 -10 9 7 0.0 10.6

-8 3 6 0.0 16.1 -9 6 2 57.9 57.0 -10 9 6 0.0 1.4

-8 3 5 0.0 3.5 -9 6 1 21.5 22.7 -10 9 5 0.0 9.2

-8 3 4 0.0 1.0 -9 6 0 0.0 1.0 -10 9 4 0.0 13.6

-8 3 3 18.6 18.7 -9 5 9 0.0 9.3 -10 9 3 20.2 20.5

-8 3 2 20.2 20.5 -9 5 8 0.0 11.3 -10 9 2 0.0 0.9

-8 3 1 0.0 10.2 -9 5 7 0.0 9.0 -10 9 1 0.0 12.9

-8 3 0 0.0 0.7 -9 5 6 0.0 7.5 -10 9 0 15.8 15.3

-8 2 8 0.0 3.5 -9 5 5 20.7 21.1 10 -9 8 0.0 9.8

-8 2 7 0.0 4.0 -9 5 4 0.0 13.3 -10 8 7 0.0 9.1

-8 2 6 0.0 12.0 -9 5 3 0.0 16.9 -10 8 6 0.0 20.9

-8 2 5 0.0 11.3 -9 5 2 0.0 0.8 -10 8 5 0.0 12.6

-8 2 4 0.0 3.6 -9 5 1 25.5 26.0 -10 8 4 0.0 8.1

-8 2 3 0.0 6.5 -9 5 0 0.0 9.9 -10 8 3 16.5 16.0

-8 2 2 18.3 19.1 -9 4 8 0.0 14.3 -10 8 2 48.3 47.8

-8 2 1 0.0 11.2 -9 4 7 0.0 8.3 -10 8 1 17.6 17.1

-8 2 0 0.0 7.4 -9 4 6 0.0 17.0 -10 8 0 26.2 26.0

-8 1 8 0.0 10.4 -9 4 5 0.0 14.7 10 -8 8 0.0 1.6

-8 1 7 0.0 8.7 -9 4 4 0.0 7.5 -10 7 8 0.0 6.4

-8 1 6 0.0 15.0 -9 4 3 0.0 14.4 -10 7 7 0.0 7.7

-8 1 5 0.0 11.4 -9 4 2 0.0 0.6 -10 7 6 0.0 18.4

-8 1 4 26.3 26.7 -9 4 1 18.1 18.1 -10 7 5 0.0 13.0

-8 1 3 0.0 8.8 -9 4 0 13.3 12.8 -10 7 4 0.0 1.1

-8 1 2 42.3 42.1 -9 3 8 0.0 3.5 -10 7 3 0.0 7.7

-8 1 1 14.1 13.9 -9 3 7 34.8 33.6 -10 7 2 0.0 10.8

-8 1 0 47.7 46.6 -9 3 6 42.5 42.0 -10 7 1 0.0 15.0

-8 0 8 0.0 15.5 -9 3 5 44.3 43.5 -10 7 0 15.5 12.5

-8 0 7 0.0 2.4 -9 3 4 0.0 3.6 -10 6 9 0.0 3.2

-8 0 6 50.6 47.8 -9 3 3 45.9 45.1 -10 6 8 0.0 13.3

-8 0 5 0.0 3.0 -9 3 2 67.0 65.4 -10 6 7 0.0 3.9

-8 0 4 35.5 35.4 -9 3 1 60.0 59.4 -10 6 6 0.0 0.9

-8 0 3 0.0 4.8 -9 3 0 0.0 3.0 -10 6 5 0.0 2.9

-8 0 2 54.5 54.5 -9 2 8 0.0 17.8 -10 6 4 0.0 18.7

-8 0 1 0.0 1.0 -9 2 7 0.0 12.9 -10 6 3 0.0 2.0

-8 0 0 57.5 55.6 -9 2 6 0.0 0.5 -10 6 2 0.0 2.7

-9 8 8 0.0 7.8 -9 2 5 0.0 15.9 -10 6 1 0.0 0.2

-9 8 7 0.0 5.1 -9 2 4 0.0 22.1 -10 6 0 19.2 20.2

-9 8 6 0.0 4.0 -9 2 3 18.7 17.8 -10 5 8 0.0 3.8

-9 8 5 0.0 2.6 -9 2 2 0.0 8.8 -10 5 7 0.0 16.9

-9 8 4 0.0 11.8 -9 2 1 20.2 20.5 -10 5 6 0.0 14.0

-9 8 3 0.0 1.0 -9 2 0 17.0 17.6 -10 5 5 23.4 23.8

-9 8 2 0.0 4.7 -9 1 7 0.0 6.0 -10 5 4 0.0 14.7

-9 8 1 0.0 6.5 -9 1 6 0.0 23.9 -10 5 3 25.7 25.7

-9 8 0 16.4 16.0 -9 1 5 0.0 10.5 -10 5 2 41.4 41.9

-9 7 8 0.0 18.9 -9 1 4 0.0 4.3 -10 5 1 29.6 31.0

-9 7 7 0.0 13.6 -9 1 3 0.0 11.6 -10 5 0 36.9 37.9

-9 7 6 0.0 5.8 -9 1 2 0.0 4.7 -10 4 8 0.0 9.1

-9 7 5 0.0 10.5 -9 1 1 0.0 13.9 -10 4 7 0.0 0.0

-9 7 4 26.2 25.7 -9 1 0 19.2 19.6 -10 4 6 0.0 16.3

-9 7 3 21.0 21.3 9 -1 8 0.0 9.7 -10 4 5 0.0 4.2

-9 7 2 13.8 13.8 -9 0 8 0.0 6.6 -10 4 4 0.0 6.4

-9 7 1 15.9 16.9 -9 0 7 0.0 15.8 -10 4 3 0.0 2.7

-9 7 0 26.6 27.4 -9 0 6 0.0 22.7 -10 4 2 0.0 6.5

9 -7 9 0.0 8.1 -9 0 5 0.0 15.1 -10 4 1 0.0 4.5

-9 6 8 0.0 1.2 -9 0 4 0.0 11.3 -10 4 0 0.0 6.8

-9 6 7 0.0 9.3 -9 0 3 28.0 27.0 -10 3 7 0.0 13.8

-9 6 6 39.7 40.2 -9 0 2 38.9 38.3 -10 3 6 0.0 1.7

H K L FO FC H K L FO FC H K L FO FC

-10 3 5 0.0 4.2 -11 7 7 0.0 2.9 -11 1 1 32.2 31.1

-10 3 4 0.0 17.5 -11 7 6 0.0 1.8 -11 1 0 0.0 12.9

-10 3 3 23.4 25.4 -11 7 5 0.0 6.8 -11 0 7 0.0 8.3

-10 3 2 0.0 1.2 -11 7 4 41.9 41.7 -11 0 6 0.0 15.0

-10 3 1 0.0 11.2 -11 7 3 0.0 0.7 -11 0 5 0.0 14.0

-10 3 0 22.5 22.4 -11 7 2 0.0 1.4 -11 0 4 0.0 2.6

10 -3 8 0.0 11.0 -11 7 1 0.0 7.1 -11 0 3 0.0 16.1

-10 2 7 0.0 1.3 -11 7 0 52.6 50.9 -11 0 2 0.0 3.1

-10 2 6 0.0 9.4 -11 6 8 0.0 18.5 -11 0 1 0.0 17.3

-10 2 5 0.0 0.7 -11 6 7 0.0 18.8 -11 0 0 0.0 8.8

-10 2 4 26.6 26.7 -11 6 6 0.0 10.3 -12 11 7 0.0 3.2

-10 2 3 0.0 2.0 -11 6 5 0.0 26.9 -12 11 6 0.0 8.9

-10 2 2 0.0 19.5 -11 6 4 30.6 29.6 -12 11 5 0.0 8.1

-10 2 1 0.0 0.5 -11 6 3 0.0 20.6 -12 11 4 0.0 4.4

-10 2 0 39.7 38.7 -11 6 2 0.0 17.8 -12 11 3 0.0 8.1

10 -2 8 0.0 15.0 -11 6 1 32.9 32.2 -12 11 2 0.0 6.4

-10 1 7 0.0 18.6 -11 6 0 33.0 33.3 -12 11 1 0.0 8.7

-10 1 6 0.0 0.9 -11 5 8 0.0 6.5 -12 11 0 0.0 1.1

-10 1 5 0.0 13.6 -11 5 7 0.0 9.1 -12 10 7 0.0 15.6

-10 1 4 0.0 18.3 -11 5 6 0.0 8.9 -12 10 6 0.0 7.2

-10 1 3 29.0 28.6 -11 5 5 0.0 7.6 -12 10 5 0.0 12.8

-10 1 2 0.0 3.6 -11 5 4 0.0 8.5 -12 10 4 0.0 21.0

-10 1 1 22.9 21.9 -11 5 3 0.0 17.5 -12 10 3 31.3 28.8

-10 1 0 0.0 15.8 -11 5 2 0.0 7.2 -12 10 2 0.0 9.7

-10 0 8 0.0 10.7 -11 5 1 0.0 11.7 -12 10 1 20.7 20.5

-10 0 7 0.0 0.4 -11 5 0 0.0 3.9 -12 10 0 23.8 24.9

-10 0 6 0.0 0.7 -11 4 7 0.0 8.2 -12 9 8 0.0 14.2

-10 0 5 0.0 5.5 -11 4 6 0.0 7.7 -12 9 7 0.0 4.7

-10 0 4 0.0 12.8 -11 4 5 0.0 7.7 -12 9 6 0.0 7.7

-10 0 3 0.0 5.1 -11 4 4 30.3 30.8 -12 9 5 0.0 5.9

-10 0 2 0.0 2.0 -11 4 3 0.0 10.7 -12 9 4 0.0 22.6

-10 0 1 0.0 4.4 -11 4 2 0.0 11.6 -12 9 3 0.0 8.3

-10 0 0 0.0 13.2 -11 4 1 0.0 11.9 -12 9 2 0.0 14.1

-11 10 7 0.0 7.2 -11 4 0 37.6 36.8 -12 9 1 0.0 8.3

-11 10 6 0.0 4.0 11 -4 8 0.0 19.3 -12 9 0 31.4 30.1

-11 10 5 0.0 11.0 -11 3 7 0.0 12.7 -12 8 8 0.0 7.0

-11 10 4 27.6 30.8 -11 3 6 0.0 12.7 -12 8 7 0.0 7.4

-11 10 3 0.0 12.2 -11 3 5 0.0 14.7 -12 8 6 0.0 19.9

-11 10 2 0.0 7.6 -11 3 4 0.0 0.6 -12 8 5 0.0 19.7

-11 10 1 0.0 12.6 -11 3 3 0.0 13.1 -12 8 4 0.0 10.3

-11 10 0 41.2 39.7 -11 3 2 0.0 9.3 -12 8 3 0.0 11.3

-11 9 7 0.0 19.6 -11 3 1 0.0 20.3 -12 8 2 25.5 26.7

-11 9 6 0.0 0.6 -11 3 0 0.0 4.3 -12 8 1 0.0 20.9

-11 9 5 0.0 27.7 11 -3 8 0.0 4.3 -12 8 0 0.0 12.1

-11 9 4 0.0 20.9 -11 2 7 0.0 7.1 -12 7 8 0.0 5.8

-11 9 3 27.6 28.2 -11 2 6 0.0 2.9 -12 7 7 0.0 0.2

-11 9 2 0.0 9.6 -11 2 5 0.0 6.6 -12 7 6 0.0 8.3

-11 9 1 35.6 35.0 -11 2 4 0.0 17.8 -12 7 5 0.0 3.0

-11 9 0 0.0 16.0 -11 2 3 0.0 16.9 -12 7 4 0.0 4.7

-11 8 8 0.0 1.1 -11 2 2 0.0 5.7 -12 7 3 0.0 3.3

-11 8 7 0.0 2.6 -11 2 1 0.0 9.4 -12 7 2 0.0 5.5

-11 8 6 0.0 25.6 -11 2 0 17.5 19.8 -12 7 1 0.0 3.2

-11 8 5 0.0 5.3 11 -2 8 0.0 12.4 -12 7 0 0.0 2.4

-11 8 4 0.0 5.0 -11 1 7 0.0 19.0 -12 6 7 0.0 7.9

-11 8 3 0.0 5.1 -11 1 6 0.0 20.8 -12 6 6 0.0 16.8

-11 8 2 0.0 16.7 -11 1 5 0.0 23.0 -12 6 5 0.0 11.8

-11 8 1 0.0 5.8 -11 1 4 0.0 9.6 -12 6 4 0.0 14.6

-11 8 0 23.0 21.3 -11 1 3 32.9 33.4 -12 6 3 0.0 9.3

-11 7 8 0.0 25.6 -11 1 2 32.0 31.8 -12 6 2 28.7 29.6

H K L FO FC H K L FO FC H K L FO FC

-12 6 1 0.0 14.2 -13 11 3 0.0 11.9 -13 3 6 0.0 7.4

-12 6 0 19.8 22.3 -13 11 2 0.0 32.2 -13 3 5 0.0 5.2

-12 5 7 0.0 9.7 -13 11 1 0.0 13.4 -13 3 4 0.0 22.8

-12 5 6 0.0 7.2 -13 11 0 0.0 0.4 -13 3 3 0.0 8.9

-12 5 5 0.0 18.2 -13 10 7 0.0 9.7 -13 3 2 0.0 13.4

-12 5 4 0.0 4.6 -13 10 6 0.0 10.2 -13 3 1 0.0 7.0

-12 5 3 0.0 9.3 -13 10 5 0.0 14.3 -13 3 0 0.0 23.8

-12 5 2 0.0 9.2 -13 10 4 0.0 1.3 13 -3 7 0.0 6.5

-12 5 1 20.3 20.6 -13 10 3 0.0 15.4 -13 2 6 0.0 10.6

-12 5 0 0.0 6.6 -13 10 2 0.0 6.2 -13 2 4 0.0 16.7

-12 4 7 0.0 4.0 -13 10 1 0.0 17.1 -13 2 3 0.0 15.5

-12 4 6 34.8 32.9 -13 10 0 0.0 4.8 -13 2 2 0.0 14.2

-12 4 5 0.0 2.3 -13 9 7 0.0 0.4 -13 2 1 0.0 8.8

-12 4 4 0.0 19.9 -13 9 6 0.0 10.4 -13 2 0 0.0 19.7

-12 4 3 0.0 6.0 -13 9 5 0.0 0.3 13 -2 5 0.0 5.6

-12 4 2 31.0 31.0 -13 9 4 0.0 1.3 -13 1 6 0.0 3.7

-12 4 1 0.0 4.7 -13 9 3 0.0 6.2 -13 1 4 0.0 8.4

-12 4 0 35.7 33.7 -13 9 2 0.0 12.1 -13 1 3 0.0 12.3

-12 3 7 0.0 8.1 -13 9 1 0.0 0.0 -13 1 2 0.0 1.6

-12 3 6 0.0 9.8 -13 9 0 0.0 2.9 -13 1 1 0.0 8.5

-12 3 5 0.0 10.7 -13 8 7 0.0 0.4 -13 1 0 0.0 7.1

-12 3 4 0.0 14.9 -13 8 6 0.0 15.7 13 -1 5 0.0 4.4

-12 3 3 0.0 11.5 -13 8 5 0.0 0.3 -13 0 3 0.0 2.8

-12 3 2 28.5 27.7 -13 8 4 0.0 9.6 -13 0 2 0.0 2.0

-12 3 1 0.0 13.8 -13 8 3 0.0 0.6 -13 0 1 0.0 0.5

-12 3 0 29.1 28.7 -13 8 2 26.5 26.6 -13 0 0 0.0 7.2

-12 2 7 0.0 11.2 -13 8 1 0.0 0.8 13 0 4 0.0 7.3

-12 2 6 0.0 1.5 -13 8 0 0.0 14.9 13 0 5 0.0 0.1

-12 2 5 0.0 11.9 -13 7 7 0.0 10.5 -14 13 1 0.0 13.2

-12 2 4 0.0 10.3 -13 7 6 0.0 17.9 -14 13 0 0.0 8.8

-12 2 3 0.0 16.1 -13 7 5 0.0 15.4 -14 13 2 0.0 23.5

-12 2 2 0.0 2.2 -13 7 4 0.0 1.1 -14 12 3 0.0 6.7

-12 2 1 0.0 17.1 -13 7 3 0.0 15.9 -14 12 2 0.0 2.7

-12 2 0 0.0 12.2 -13 7 2 0.0 8.9 -14 12 1 0.0 3.6

-12 1 7 0.0 1.9 -13 7 1 0.0 18.1 -14 12 0 0.0 11.8

-12 1 6 0.0 26.0 -13 7 0 0.0 15.9 -14 11 5 0.0 2.7

-12 1 5 0.0 1.8 -13 6 7 0.0 9.3 -14 11 4 0.0 9.7

-12 1 4 0.0 14.9 -13 6 5 0.0 6.6 -14 11 3 0.0 0.2

-12 1 3 0.0 2.3 -13 6 4 0.0 17.8 -14 11 2 0.0 2.8

-12 1 2 27.4 27.7 -13 6 3 0.0 10.4 -14 11 1 0.0 2.3

-12 1 1 0.0 0.4 -13 6 2 0.0 8.7 -14 11 0 0.0 2.5

-12 1 0 25.2 24.9 -13 6 1 0.0 10.3 -14 10 6 0.0 13.7

-12 0 6 0.0 3.4 -13 6 0 0.0 17.3 -14 10 5 0.0 1.0

-12 0 5 0.0 5.2 13 -6 6 0.0 2.6 -14 10 4 0.0 5.5

-12 0 4 0.0 25.2 -13 5 6 0.0 4.5 -14 10 3 0.0 1.8

-12 0 3 0.0 3.2 -13 5 5 0.0 12.4 -14 10 2 0.0 27.5

-12 0 2 0.0 6.0 -13 5 4 0.0 25.0 -14 10 1 0.0 0.8

-12 0 1 0.0 5.5 -13 5 3 0.0 6.7 -14 10 0 0.0 13.4

-12 0 0 34.0 38.0 -13 5 2 0.0 7.5 -14 9 6 0.0 4.8

-13 12 6 0.0 15.7 -13 5 1 0.0 12.9 -14 9 5 0.0 24.3

-13 12 5 0.0 0.5 -13 5 0 32.4 31.8 -14 9 4 0.0 16.8

-13 12 4 0.0 9.3 -13 4 6 0.0 17.8 -14 9 3 0.0 23.4

-13 12 3 0.0 5.3 -13 4 5 0.0 0.9 -14 9 2 0.0 6.8

-13 12 2 0.0 21.8 -13 4 4 0.0 1.5 -14 9 1 29.4 29.2

-13 12 1 0.0 0.7 -13 4 3 0.0 5.7 -14 9 0 0.0 18.9

-13 12 0 0.0 11.9 -13 4 2 0.0 12.7 -14 8 4 0.0 14.4

-13 11 6 0.0 23.2 -13 4 1 0.0 3.7 -14 8 3 0.0 2.6

-13 11 5 0.0 12.4 -13 4 0 0.0 12.6 -14 8 2 0.0 5.3

-13 11 4 0.0 0.3 13 -4 7 0.0 4.2 -14 8 1 0.0 6.8

H K L FO FC H K L FO FC H K L FO FC

-14 8 0 0.0 10.0 -14 4 3 0.0 6.8 15-10 3 0.0 0.8

14 -8 5 0.0 6.8 -14 4 2 0.0 23.8 -15 10 2 0.0 2.3

-14 7 5 0.0 15.3 -14 4 1 0.0 0.3 -15 10 1 0.0 2.8

-14 7 4 0.0 3.7 -14 4 0 0.0 6.3 -15 10 0 0.0 13.5

-14 7 3 0.0 13.9 -14 3 3 0.0 9.1 -15 9 3 0.0 1.4

-14 7 2 0.0 28.2 -14 3 2 0.0 1.1 -15 9 2 0.0 8.4

-14 7 1 0.0 17.8 -14 3 1 0.0 8.9 -15 9 1 0.0 6.2

-14 7 0 0.0 9.0 -14 3 0 0.0 7.2 -15 9 0 0.0 22.7

-14 6 4 0.0 15.0 14 -3 4 0.0 8.2 -15 8 3 0.0 0.4

-14 6 3 0.0 14.3 -14 2 2 0.0 6.7 -15 8 2 0.0 9.7

-14 6 2 0.0 5.7 -14 2 1 0.0 0.7 -15 8 1 0.0 6.7

-14 6 1 0.0 21.3 -14 2 0 0.0 9.0 -15 8 0 0.0 1.6

-14 6 0 0.0 18.1 14 -2 3 0.0 1.8 -15 7 3 0.0 2.2

14 -6 5 0.0 17.0 14 -2 5 0.0 0.1 -15 7 2 0.0 26.0

14 -6 6 0.0 4.2 14 -1 1 0.0 14.2 -15 7 1 0.0 0.6

-14 5 4 0.0 20.9 14 0 1 0.0 8.2 -15 7 0 0.0 16.5

-14 5 3 0.0 1.7 14 0 0 0.0 10.0 -15 6 2 0.0 18.3

-14 5 2 0.0 13.8 -15 12 0 0.0 25.9 -15 6 1 0.0 11.4

-14 5 1 0.0 0.2 -15 12 1 0.0 4.1 -15 6 0 0.0 19.5

-14 5 0 0.0 21.7 15-11 3 0.0 3.0 -15 5 1 0.0 2.7

14 -5 5 0.0 1.6 15-11 2 0.0 10.8 -15 5 0 0.0 5.5

-14 4 5 0.0 1.8 15-11 1 0.0 5.6 0 0 0 0.0 0.0

-14 4 4 0.0 4.9 -15 11 0 0.0 6.2 0 0 0 0.0 0.0

 

 

 

 

 

 

 

 

 

Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:

Uptake, Site Preference and

Degradation of Monoclinic Structure

Michael E. Fleet, Xioayang Liu

and Yuanming Pan

 

 

Deposited Material

 

 

Table 5. List of observed and calculated structure factors

 

 

(c) P63/m structure of Sm-chlorapatite

H K L FO FC H K L FO FC H K L FO FC

0 0 2 102.4 102.5 -3 1 5 59.7 59.3 -4 0 6 38.6 38.2

0 0 4 211.3 204.9 -3 1 4 29.3 29.2 -4 0 5 13.4 14.3

0 0 6 98.6 98.1 -3 1 3 83.1 82.6 -4 0 4 14.7 14.7

0 0 8 80.8 79.2 -3 1 2 10.2 9.2 -4 0 3 0.0 3.0

0 0 10 40.6 42.4 -3 1 1 97.5 98.3 -4 0 2 53.4 53.7

-1 0 11 0.0 5.1 -3 1 0 43.3 44.9 -4 0 1 12.9 13.3

-1 0 10 0.0 12.1 -3 0 11 0.0 2.6 -4 0 0 26.0 26.7

-1 0 9 0.0 2.4 -3 0 10 0.0 4.3 5 -4 11 0.0 0.6

-1 0 8 15.9 16.1 -3 0 9 0.0 5.7 -5 4 10 0.0 7.8

-1 0 7 0.0 4.7 -3 0 8 35.3 34.4 -5 4 9 0.0 5.7

-1 0 6 19.1 19.3 -3 0 7 0.0 9.5 -5 4 8 26.9 28.2

-1 0 5 0.0 8.1 -3 0 6 8.7 8.6 -5 4 7 0.0 6.6

-1 0 4 23.1 23.1 -3 0 5 9.8 10.4 -5 4 6 16.8 17.8

-1 0 3 5.1 4.6 -3 0 4 78.3 78.0 -5 4 5 0.0 0.9

-1 0 2 0.0 0.5 -3 0 3 25.2 25.1 -5 4 4 52.4 52.1

-1 0 1 16.1 16.2 -3 0 2 44.4 43.4 -5 4 3 18.6 19.1

-1 0 0 15.2 15.6 -3 0 1 27.0 26.4 -5 4 2 32.4 32.8

-2 1 11 0.0 1.5 -3 0 0 153.9 156.4 -5 4 1 0.0 4.1

-2 1 10 29.0 31.0 -4 3 11 0.0 13.0 -5 4 0 67.7 69.3

-2 1 9 0.0 7.5 -4 3 10 0.0 19.0 5 -3 11 0.0 16.7

-2 1 8 0.0 1.9 -4 3 9 0.0 13.6 -5 3 10 0.0 2.0

-2 1 7 0.0 4.6 -4 3 8 12.6 13.2 -5 3 9 0.0 18.8

-2 1 6 66.7 66.0 -4 3 7 24.7 25.2 -5 3 8 22.5 22.9

-2 1 5 12.3 12.8 -4 3 6 44.8 45.3 -5 3 7 20.3 20.7

-2 1 4 11.5 11.2 -4 3 5 27.9 27.4 -5 3 6 0.0 6.7

-2 1 3 42.9 42.2 -4 3 4 0.0 5.9 -5 3 5 50.3 50.5

-2 1 2 115.1 115.7 -4 3 3 39.5 39.4 -5 3 4 38.6 39.2

-2 1 1 12.7 13.0 -4 3 2 29.7 29.5 -5 3 3 18.7 18.7

-2 1 0 3.5 2.7 -4 3 1 43.0 43.7 -5 3 2 13.3 13.3

-2 0 11 0.0 3.3 -4 3 0 88.4 85.8 -5 3 1 64.0 64.3

-2 0 10 0.0 12.1 -4 2 11 0.0 2.8 -5 3 0 60.8 60.5

-2 0 9 0.0 1.0 -4 2 10 24.7 27.3 5 -2 11 0.0 14.7

-2 0 8 0.0 8.4 -4 2 9 0.0 0.4 -5 2 10 0.0 18.6

-2 0 7 0.0 1.0 -4 2 8 0.0 2.7 -5 2 9 0.0 18.1

-2 0 6 20.0 19.9 -4 2 7 0.0 2.6 -5 2 8 0.0 1.0

-2 0 5 19.6 20.1 -4 2 6 52.2 52.1 -5 2 7 24.8 26.3

-2 0 4 0.0 5.3 -4 2 5 9.3 9.5 -5 2 6 31.8 31.0

-2 0 3 26.3 25.6 -4 2 4 0.0 3.7 -5 2 5 29.8 29.9

-2 0 2 38.8 38.5 -4 2 3 9.7 9.6 -5 2 4 11.3 11.2

-2 0 1 22.9 22.7 -4 2 2 120.3 119.0 -5 2 3 52.8 52.7

-2 0 0 6.0 5.3 -4 2 1 7.8 8.2 -5 2 2 40.7 40.8

-3 2 11 0.0 19.5 -4 2 0 20.5 21.7 -5 2 1 51.6 52.0

-3 2 10 0.0 7.2 -4 1 11 0.0 3.9 -5 2 0 14.1 14.3

-3 2 9 21.7 22.7 -4 1 10 0.0 12.3 5 -1 11 0.0 1.5

-3 2 8 32.8 33.2 -4 1 9 0.0 13.9 -5 1 10 0.0 5.4

-3 2 7 35.0 35.2 -4 1 8 0.0 4.1 -5 1 9 0.0 0.4

-3 2 6 14.0 14.5 -4 1 7 0.0 7.8 -5 1 8 19.4 21.2

-3 2 5 39.4 39.3 -4 1 6 14.6 14.9 -5 1 7 0.0 2.7

-3 2 4 41.1 40.9 -4 1 5 0.0 5.8 -5 1 6 14.6 13.9

-3 2 3 65.6 65.3 -4 1 4 0.0 4.5 -5 1 5 0.0 2.3

-3 2 2 50.6 49.4 -4 1 3 41.8 41.2 -5 1 4 54.7 55.2

-3 2 1 69.0 70.1 -4 1 2 38.9 39.0 -5 1 3 0.0 1.0

-3 2 0 0.0 2.4 -4 1 1 9.1 7.6 -5 1 2 38.5 38.9

-3 1 11 0.0 18.3 -4 1 0 20.2 19.9 -5 1 1 0.0 2.8

-3 1 10 0.0 2.1 4 0 11 0.0 8.3 -5 1 0 96.9 97.6

-3 1 9 34.5 35.0 -4 0 10 22.0 23.6 -5 0 10 21.5 21.4

-3 1 8 21.7 21.3 -4 0 9 0.0 3.7 -5 0 9 0.0 2.3

-3 1 7 37.7 38.0 -4 0 8 0.0 6.8 -5 0 8 0.0 10.2

-3 1 6 0.0 0.6 -4 0 7 0.0 9.0 -5 0 7 0.0 4.5

H K L FO FC H K L FO FC H K L FO FC

-5 0 6 34.3 33.7 -6 1 2 48.5 48.6 -7 2 9 0.0 16.7

-5 0 5 24.7 25.7 -6 1 1 72.9 71.9 -7 2 8 18.9 18.8

-5 0 4 19.1 19.4 -6 1 0 44.6 44.8 -7 2 7 22.5 23.3

-5 0 3 7.8 8.4 -6 0 10 0.0 19.0 -7 2 6 0.0 5.5

-5 0 2 54.9 54.8 -6 0 9 0.0 10.7 -7 2 5 21.6 22.1

-5 0 1 33.8 33.5 -6 0 8 0.0 10.0 -7 2 4 43.9 42.8

-5 0 0 12.6 13.1 -6 0 7 16.6 16.5 -7 2 3 38.9 38.9

-6 5 10 0.0 8.8 -6 0 6 36.8 37.0 -7 2 2 30.5 30.5

-6 5 9 0.0 8.4 -6 0 5 0.0 7.9 -7 2 1 34.4 34.6

-6 5 8 17.8 18.4 -6 0 4 19.6 20.5 -7 2 0 79.5 79.8

-6 5 7 17.2 18.8 -6 0 3 28.9 29.2 -7 1 10 0.0 1.0

-6 5 6 13.5 14.9 -6 0 2 54.1 53.4 -7 1 9 0.0 1.6

-6 5 5 19.9 20.5 -6 0 1 14.4 14.7 -7 1 8 14.9 16.6

-6 5 4 11.7 11.8 -6 0 0 23.7 24.6 -7 1 7 0.0 5.2

-6 5 3 18.6 18.7 -7 6 10 0.0 3.2 -7 1 6 0.0 1.5

-6 5 2 0.0 1.5 -7 6 9 0.0 10.1 -7 1 5 0.0 8.1

-6 5 1 29.6 29.9 -7 6 8 31.8 32.4 -7 1 4 23.9 24.2

-6 5 0 0.0 4.2 -7 6 7 0.0 6.0 -7 1 3 0.0 4.7

-6 4 10 0.0 5.1 -7 6 6 0.0 4.0 -7 1 2 0.0 4.2

-6 4 9 20.7 21.6 -7 6 5 12.6 13.7 -7 1 1 9.5 9.8

-6 4 8 34.7 34.5 -7 6 4 42.5 42.2 -7 1 0 31.3 31.6

-6 4 7 19.6 19.7 -7 6 3 13.9 15.3 -7 0 10 0.0 18.3

-6 4 6 16.4 16.8 -7 6 2 33.6 34.2 -7 0 9 0.0 7.1

-6 4 5 24.1 23.7 -7 6 1 19.8 20.1 -7 0 8 0.0 5.3

-6 4 4 49.4 48.8 -7 6 0 30.0 30.5 -7 0 7 0.0 8.2

-6 4 3 47.6 47.9 -7 5 10 0.0 16.6 -7 0 6 26.6 26.5

-6 4 2 38.0 37.9 -7 5 9 0.0 7.0 -7 0 5 0.0 1.5

-6 4 1 32.0 32.7 -7 5 8 0.0 6.2 -7 0 4 13.2 13.6

-6 4 0 59.1 59.2 -7 5 7 0.0 7.7 -7 0 3 21.9 22.1

-6 3 10 0.0 17.2 -7 5 6 25.2 25.8 -7 0 2 36.9 37.0

-6 3 9 0.0 10.1 -7 5 5 0.0 8.7 -7 0 1 0.0 5.0

-6 3 8 0.0 12.6 -7 5 4 9.4 9.2 -7 0 0 16.1 16.5

-6 3 7 18.0 19.0 -7 5 3 10.8 10.6 -8 7 10 0.0 1.2

-6 3 6 33.3 33.1 -7 5 2 86.1 85.7 -8 7 9 0.0 9.2

-6 3 5 30.8 29.8 -7 5 1 11.1 11.2 -8 7 8 35.2 35.0

-6 3 4 29.5 29.7 -7 5 0 50.1 50.6 -8 7 7 0.0 11.5

-6 3 3 16.2 15.7 -7 4 10 24.6 26.0 -8 7 6 0.0 2.2

-6 3 2 53.7 53.8 -7 4 9 0.0 1.8 -8 7 5 0.0 2.0

-6 3 1 40.0 40.4 -7 4 8 0.0 14.7 -8 7 4 57.6 56.4

-6 3 0 41.2 41.5 -7 4 7 0.0 1.7 -8 7 3 26.7 27.7

-6 2 10 0.0 1.0 -7 4 6 44.0 43.0 -8 7 2 0.0 1.9

-6 2 9 0.0 7.7 -7 4 5 0.0 8.5 -8 7 1 10.6 10.9

-6 2 8 40.5 39.6 -7 4 4 30.4 30.6 -8 7 0 69.4 67.8

-6 2 7 16.6 16.5 -7 4 3 0.0 3.4 -8 6 10 0.0 1.9

-6 2 6 0.0 4.2 -7 4 2 62.6 63.1 -8 6 9 0.0 1.3

-6 2 5 17.3 17.6 -7 4 1 9.6 9.6 -8 6 8 22.1 22.8

-6 2 4 45.3 44.7 -7 4 0 41.1 41.7 -8 6 7 0.0 3.5

-6 2 3 27.3 27.5 -7 3 10 0.0 6.2 -8 6 6 0.0 1.5

-6 2 2 49.2 49.2 -7 3 9 0.0 16.4 -8 6 5 0.0 0.4

-6 2 1 30.8 31.0 -7 3 8 14.1 14.2 -8 6 4 29.3 29.0

-6 2 0 11.9 11.6 -7 3 7 27.9 28.0 -8 6 3 0.0 4.7

-6 1 10 0.0 6.5 -7 3 6 0.0 8.6 -8 6 2 13.2 13.1

-6 1 9 30.2 32.1 -7 3 5 22.4 23.2 -8 6 1 0.0 3.1

-6 1 8 40.4 39.7 -7 3 4 20.5 20.8 -8 6 0 18.4 18.2

-6 1 7 35.3 35.4 -7 3 3 53.9 54.1 -8 5 10 0.0 23.7

-6 1 6 0.0 10.8 -7 3 2 0.0 0.9 -8 5 9 0.0 3.2

-6 1 5 54.4 53.8 -7 3 1 42.4 42.5 -8 5 8 0.0 14.5

-6 1 4 54.0 54.0 -7 3 0 17.6 18.0 -8 5 7 0.0 4.8

-6 1 3 60.3 59.6 -7 2 10 0.0 8.5 -8 5 6 43.4 42.4

H K L FO FC H K L FO FC H K L FO FC

-8 5 5 0.0 7.8 -8 0 0 57.0 57.0 -9 3 8 0.0 5.4

-8 5 4 28.1 27.8 8 0 10 27.8 30.6 -9 3 7 36.9 37.5

-8 5 3 0.0 7.4 -9 8 10 0.0 4.1 -9 3 6 45.8 45.2

-8 5 2 54.7 54.6 -9 8 9 0.0 3.7 -9 3 5 47.6 46.7

-8 5 1 8.7 9.7 -9 8 8 0.0 10.0 -9 3 4 0.0 4.5

-8 5 0 38.6 38.0 -9 8 7 0.0 5.5 -9 3 3 49.4 48.3

-8 4 10 0.0 6.2 -9 8 6 0.0 2.2 -9 3 2 71.0 68.7

-8 4 9 0.0 5.2 -9 8 5 0.0 2.6 -9 3 1 63.1 62.1

-8 4 8 39.0 38.7 -9 8 4 12.3 13.6 -9 3 0 0.0 3.7

-8 4 7 0.0 13.9 -9 8 3 0.0 0.9 -9 2 9 0.0 10.8

-8 4 6 0.0 3.6 -9 8 2 0.0 1.9 -9 2 8 17.7 19.4

-8 4 5 26.6 26.9 -9 8 1 0.0 6.4 -9 2 7 0.0 13.4

-8 4 4 66.2 65.1 -9 8 0 17.4 18.3 -9 2 6 0.0 0.8

-8 4 3 8.8 9.0 -9 7 10 0.0 0.8 -9 2 5 14.7 15.7

-8 4 2 0.0 3.0 -9 7 9 0.0 10.0 -9 2 4 20.9 21.3

-8 4 1 33.8 34.5 -9 7 8 23.3 21.4 -9 2 3 18.0 17.6

-8 4 0 79.3 78.4 -9 7 7 0.0 14.8 -9 2 2 0.0 8.7

-8 3 10 0.0 11.3 -9 7 6 0.0 6.7 -9 2 1 19.3 19.9

-8 3 9 0.0 4.0 -9 7 5 0.0 11.8 -9 2 0 15.8 16.3

-8 3 8 0.0 3.9 -9 7 4 27.4 26.4 -9 1 9 0.0 7.1

-8 3 7 0.0 10.9 -9 7 3 22.5 22.9 -9 1 8 0.0 10.7

-8 3 6 14.5 15.6 -9 7 2 16.4 15.9 -9 1 7 0.0 6.7

-8 3 5 0.0 3.6 -9 7 1 17.6 17.9 -9 1 6 26.6 26.1

-8 3 4 0.0 2.2 -9 7 0 27.7 27.5 -9 1 5 0.0 10.8

-8 3 3 19.0 19.7 -9 6 10 0.0 22.1 -9 1 4 0.0 3.4

-8 3 2 18.1 18.4 -9 6 9 0.0 4.5 -9 1 3 10.8 12.2

-8 3 1 10.4 10.6 -9 6 8 0.0 0.6 -9 1 2 0.0 4.5

-8 3 0 0.0 1.2 -9 6 7 0.0 9.2 -9 1 1 13.9 14.2

-8 2 10 0.0 8.7 -9 6 6 42.0 42.4 -9 1 0 21.6 21.6

-8 2 9 0.0 2.5 -9 6 5 21.2 21.4 9 -1 10 0.0 12.8

-8 2 8 0.0 3.8 -9 6 4 0.0 2.0 -9 0 9 0.0 12.5

-8 2 7 0.0 4.2 -9 6 3 0.0 0.3 -9 0 8 0.0 6.1

-8 2 6 12.8 12.7 -9 6 2 59.8 58.8 -9 0 7 18.7 18.4

-8 2 5 12.2 11.7 -9 6 1 20.8 21.8 -9 0 6 24.0 24.5

-8 2 4 0.0 2.7 -9 6 0 0.0 0.1 -9 0 5 15.3 16.6

-8 2 3 0.0 7.7 -9 5 10 0.0 7.0 -9 0 4 0.0 11.0

-8 2 2 18.7 19.4 -9 5 9 0.0 10.0 -9 0 3 30.3 30.0

-8 2 1 11.1 11.2 -9 5 8 0.0 13.2 -9 0 2 41.6 40.8

-8 2 0 7.2 6.7 -9 5 7 0.0 10.2 -9 0 1 25.5 25.4

-8 1 10 0.0 5.1 -9 5 6 0.0 7.1 -9 0 0 18.3 18.8

-8 1 9 0.0 5.4 -9 5 5 22.2 22.3 -10 9 9 0.0 14.1

-8 1 8 0.0 10.2 -9 5 4 13.7 14.0 -10 9 8 0.0 10.6

-8 1 7 0.0 10.0 -9 5 3 17.2 17.6 -10 9 7 0.0 11.6

-8 1 6 15.1 15.3 -9 5 2 0.0 1.3 -10 9 6 0.0 1.4

-8 1 5 13.1 13.0 -9 5 1 26.7 27.0 -10 9 5 0.0 9.8

-8 1 4 28.3 28.3 -9 5 0 9.6 10.6 -10 9 4 12.5 13.0

-8 1 3 10.0 10.4 -9 4 10 0.0 11.6 -10 9 3 21.7 21.7

-8 1 2 44.1 44.7 -9 4 9 0.0 9.0 -10 9 2 0.0 0.9

-8 1 1 15.6 15.4 -9 4 8 16.9 16.5 -10 9 1 13.2 13.1

-8 1 0 51.0 49.2 -9 4 7 0.0 8.9 -10 9 0 15.2 14.7

-8 0 9 0.0 0.3 -9 4 6 17.0 18.2 -10 8 9 0.0 8.1

-8 0 8 0.0 16.7 -9 4 5 14.8 15.1 -10 8 8 0.0 2.9

-8 0 7 0.0 2.6 -9 4 4 0.0 7.4 -10 8 7 0.0 10.7

-8 0 6 52.4 50.8 -9 4 3 14.0 14.4 -10 8 6 20.6 21.2

-8 0 5 0.0 3.1 -9 4 2 0.0 2.0 -10 8 5 0.0 14.2

-8 0 4 37.2 36.7 -9 4 1 18.3 18.3 -10 8 4 0.0 9.4

-8 0 3 0.0 4.8 -9 4 0 12.7 14.3 -10 8 3 17.6 17.8

-8 0 2 55.7 54.9 -9 3 10 0.0 24.0 -10 8 2 51.2 49.6

-8 0 1 0.0 0.9 -9 3 9 0.0 23.6 -10 8 1 19.2 18.7

H K L FO FC H K L FO FC H K L FO FC

-10 8 0 28.0 28.7 -10 2 3 0.0 0.8 -11 7 3 0.0 0.5

-10 7 9 0.0 7.1 -10 2 2 18.4 19.4 -11 7 2 0.0 1.0

-10 7 8 0.0 6.6 -10 2 1 0.0 0.7 -11 7 1 0.0 7.7

-10 7 7 0.0 8.4 -10 2 0 41.6 41.1 -11 7 0 54.3 52.5

-10 7 6 21.3 21.0 -10 1 9 0.0 12.6 -11 6 9 0.0 11.3

-10 7 5 13.7 13.4 -10 1 8 0.0 13.7 -11 6 8 21.9 21.4

-10 7 4 0.0 2.9 -10 1 7 19.9 20.0 -11 6 7 21.1 21.0

-10 7 3 0.0 7.9 -10 1 6 0.0 0.7 -11 6 6 0.0 12.4

-10 7 2 11.2 11.8 -10 1 5 0.0 14.0 -11 6 5 29.8 29.3

-10 7 1 14.6 15.0 -10 1 4 18.8 18.5 -11 6 4 32.5 31.2

-10 7 0 15.6 15.7 -10 1 3 31.1 30.0 -11 6 3 21.3 21.8

-10 6 10 0.0 0.0 -10 1 2 0.0 4.2 -11 6 2 20.0 20.2

-10 6 9 0.0 4.6 -10 1 1 22.4 22.0 -11 6 1 35.3 34.3

-10 6 8 0.0 14.6 -10 1 0 15.6 15.4 -11 6 0 36.5 34.8

-10 6 7 0.0 3.2 -10 0 9 0.0 1.1 -11 5 9 0.0 9.9

-10 6 6 0.0 1.2 -10 0 8 0.0 11.8 -11 5 8 0.0 7.0

-10 6 5 0.0 5.0 -10 0 7 0.0 1.1 -11 5 7 0.0 9.5

-10 6 4 17.7 18.4 -10 0 6 0.0 1.1 -11 5 6 0.0 9.4

-10 6 3 0.0 0.7 -10 0 5 0.0 5.4 -11 5 5 0.0 6.4

-10 6 2 0.0 2.8 -10 0 4 0.0 12.0 -11 5 4 0.0 8.1

-10 6 1 0.0 1.8 -10 0 3 0.0 6.2 -11 5 3 15.7 17.5

-10 6 0 18.5 20.0 -10 0 2 0.0 2.3 -11 5 2 0.0 7.2

-10 5 10 0.0 11.5 -10 0 1 0.0 3.9 -11 5 1 0.0 10.3

-10 5 9 0.0 14.3 -10 0 0 11.5 11.5 -11 5 0 0.0 3.2

-10 5 8 0.0 3.5 -11 10 8 0.0 17.7 -11 4 9 0.0 4.4

-10 5 7 19.1 18.3 -11 10 7 0.0 7.5 -11 4 8 0.0 20.8

-10 5 6 0.0 14.0 -11 10 6 0.0 3.5 -11 4 7 0.0 8.6

-10 5 5 24.6 24.8 -11 10 5 0.0 11.9 -11 4 6 0.0 7.6

-10 5 4 15.8 16.3 -11 10 4 33.2 32.7 -11 4 5 0.0 8.1

-10 5 3 25.8 26.1 -11 10 3 0.0 12.5 -11 4 4 33.2 32.8

-10 5 2 44.0 43.2 -11 10 2 0.0 7.7 -11 4 3 12.5 11.3

-10 5 1 31.4 31.4 -11 10 1 0.0 12.9 -11 4 2 0.0 12.3

-10 5 0 39.7 40.3 -11 10 0 43.2 41.7 -11 4 1 0.0 12.0

-10 4 9 0.0 4.0 -11 9 9 0.0 14.8 -11 4 0 39.7 38.9

-10 4 8 0.0 9.5 -11 9 8 0.0 15.7 -11 3 9 0.0 5.0

-10 4 7 0.0 0.7 -11 9 7 0.0 20.9 -11 3 8 0.0 6.1

-10 4 6 18.1 18.3 -11 9 6 0.0 0.8 -11 3 7 0.0 14.4

-10 4 5 0.0 5.1 -11 9 5 30.0 29.8 -11 3 6 0.0 12.5

-10 4 4 0.0 5.3 -11 9 4 20.7 20.6 -11 3 5 0.0 16.3

-10 4 3 0.0 3.6 -11 9 3 29.0 28.7 -11 3 4 0.0 1.3

-10 4 2 0.0 7.4 -11 9 2 0.0 9.9 -11 3 3 0.0 14.2

-10 4 1 0.0 5.5 -11 9 1 36.6 36.1 -11 3 2 0.0 6.9

-10 4 0 0.0 9.1 -11 9 0 15.8 15.3 -11 3 1 22.1 21.8

-10 3 9 0.0 9.7 -11 8 9 0.0 4.4 -11 3 0 0.0 4.0

-10 3 8 0.0 11.9 -11 8 8 0.0 1.1 -11 2 8 0.0 14.7

-10 3 7 0.0 14.3 -11 8 7 0.0 3.2 -11 2 7 0.0 7.8

-10 3 6 0.0 2.0 -11 8 6 26.7 27.8 -11 2 6 0.0 4.6

-10 3 5 0.0 3.1 -11 8 5 0.0 5.4 -11 2 5 0.0 6.4

-10 3 4 17.4 17.5 -11 8 4 0.0 5.7 -11 2 4 18.7 19.5

-10 3 3 25.2 25.7 -11 8 3 0.0 5.8 -11 2 3 16.8 17.4

-10 3 2 0.0 1.7 -11 8 2 16.6 16.5 -11 2 2 0.0 7.9

-10 3 1 0.0 10.0 -11 8 1 0.0 6.0 -11 2 1 0.0 9.1

-10 3 0 22.6 22.4 -11 8 0 23.3 23.0 -11 2 0 21.1 21.4

10 -2 9 0.0 0.1 -11 7 9 0.0 0.1 -11 1 8 0.0 5.1

-10 2 8 0.0 16.1 -11 7 8 0.0 27.7 -11 1 7 19.2 20.8

-10 2 7 0.0 2.5 -11 7 7 0.0 3.3 -11 1 6 0.0 21.4

-10 2 6 0.0 9.2 -11 7 6 0.0 2.3 -11 1 5 25.0 24.9

-10 2 5 0.0 1.3 -11 7 5 0.0 7.7 -11 1 4 0.0 11.0

-10 2 4 28.8 29.2 -11 7 4 44.7 43.7 -11 1 3 36.2 35.6

H K L FO FC H K L FO FC H K L FO FC

-11 1 2 34.0 33.0 -12 6 8 0.0 5.4 -12 0 3 0.0 3.4

-11 1 1 33.1 32.6 -12 6 7 0.0 8.9 -12 0 2 0.0 7.2

-11 1 0 13.9 14.8 -12 6 6 0.0 17.1 -12 0 1 0.0 6.0

-11 0 8 0.0 9.1 -12 6 5 0.0 13.4 -12 0 0 38.7 39.4

-11 0 7 0.0 10.3 -12 6 4 0.0 15.6 -13 12 6 0.0 17.5

-11 0 6 0.0 15.9 -12 6 3 0.0 10.5 -13 12 5 0.0 1.3

-11 0 5 0.0 16.2 -12 6 2 31.2 31.0 -13 12 4 0.0 11.3

-11 0 4 0.0 2.9 -12 6 1 13.9 15.5 -13 12 3 0.0 5.8

-11 0 3 18.2 18.4 -12 6 0 24.2 24.3 -13 12 2 22.2 23.0

-11 0 2 0.0 1.0 -12 5 9 0.0 6.7 -13 12 1 0.0 0.2

-11 0 1 18.5 19.6 -12 5 8 0.0 2.3 -13 12 0 0.0 14.3

-11 0 0 0.0 9.9 -12 5 7 0.0 11.2 -13 11 7 0.0 8.0

-12 11 7 0.0 4.0 -12 5 6 0.0 8.0 -13 11 6 0.0 25.6

-12 11 6 0.0 8.4 -12 5 5 18.9 19.5 -13 11 5 0.0 13.1

-12 11 5 0.0 9.4 -12 5 4 0.0 3.4 -13 11 4 0.0 0.6

-12 11 4 0.0 5.5 -12 5 3 0.0 9.9 -13 11 3 0.0 12.0

-12 11 3 0.0 8.8 -12 5 2 0.0 9.7 -13 11 2 34.9 35.0

-12 11 2 0.0 4.5 -12 5 1 21.8 21.7 -13 11 1 0.0 13.6

-12 11 1 0.0 9.9 -12 5 0 0.0 5.5 -13 11 0 0.0 0.5

-12 11 0 0.0 1.8 -12 4 9 0.0 1.0 -13 10 7 0.0 10.4

12-11 8 0.0 5.5 -12 4 8 0.0 8.3 -13 10 6 0.0 12.0

-12 10 7 0.0 18.6 -12 4 7 0.0 4.9 -13 10 5 0.0 15.0

-12 10 6 0.0 8.9 -12 4 6 35.2 35.7 -13 10 4 0.0 0.4

-12 10 5 0.0 15.4 -12 4 5 0.0 3.0 -13 10 3 0.0 16.1

-12 10 4 21.6 22.1 -12 4 4 21.9 22.1 -13 10 2 0.0 6.2

-12 10 3 33.1 32.6 -12 4 3 0.0 6.9 -13 10 1 15.9 17.4

-12 10 2 0.0 11.6 -12 4 2 31.4 31.3 -13 10 0 0.0 7.8

-12 10 1 23.9 23.3 -12 4 1 0.0 5.7 -13 9 7 0.0 0.5

-12 10 0 25.1 25.9 -12 4 0 37.7 36.7 -13 9 6 0.0 11.7

12-10 8 0.0 15.1 -12 3 8 0.0 3.6 -13 9 5 0.0 0.8

-12 9 8 0.0 15.5 -12 3 7 0.0 9.2 -13 9 4 0.0 2.8

-12 9 7 0.0 5.7 -12 3 6 0.0 10.5 -13 9 3 0.0 8.2

-12 9 6 0.0 7.2 -12 3 5 0.0 11.9 -13 9 2 0.0 12.8

-12 9 5 0.0 6.4 -12 3 4 0.0 14.4 -13 9 1 0.0 1.5

-12 9 4 24.4 24.6 -12 3 3 0.0 12.7 -13 9 0 0.0 4.9

-12 9 3 0.0 9.1 -12 3 2 31.8 30.4 -13 8 7 0.0 0.8

-12 9 2 0.0 14.3 -12 3 1 13.8 14.8 -13 8 6 0.0 17.6

-12 9 1 0.0 9.0 -12 3 0 29.6 29.4 -13 8 5 0.0 0.0

-12 9 0 33.9 32.5 -12 2 8 0.0 7.3 -13 8 4 0.0 8.9

-12 8 8 0.0 7.6 -12 2 7 0.0 13.2 -13 8 3 0.0 0.6

-12 8 7 0.0 9.0 -12 2 6 0.0 1.8 -13 8 2 29.2 29.5

-12 8 6 0.0 20.6 -12 2 5 0.0 12.8 -13 8 1 0.0 0.8

-12 8 5 22.8 22.3 -12 2 4 0.0 9.6 -13 8 0 0.0 14.1

-12 8 4 0.0 10.8 -12 2 3 17.9 18.0 13 -8 8 0.0 3.9

-12 8 3 0.0 12.4 -12 2 2 0.0 2.4 -13 7 8 0.0 7.2

-12 8 2 26.3 26.2 -12 2 1 17.7 18.3 -13 7 7 0.0 11.7

-12 8 1 22.7 23.2 -12 2 0 0.0 11.3 -13 7 6 0.0 20.3

-12 8 0 0.0 12.4 -12 1 7 0.0 1.5 -13 7 5 0.0 16.6

-12 7 9 0.0 1.3 -12 1 6 28.3 29.6 -13 7 4 0.0 2.6

-12 7 8 0.0 7.7 -12 1 5 0.0 2.0 -13 7 3 16.6 16.9

-12 7 7 0.0 0.6 -12 1 4 0.0 18.5 -13 7 2 0.0 9.1

-12 7 6 0.0 7.7 -12 1 3 0.0 2.1 -13 7 1 19.3 18.9

-12 7 5 0.0 2.6 -12 1 2 31.0 30.3 -13 7 0 18.9 19.2

-12 7 4 0.0 5.3 -12 1 1 0.0 0.6 -13 6 8 0.0 14.7

-12 7 3 0.0 4.2 -12 1 0 28.4 29.2 -13 6 7 0.0 9.4

-12 7 2 0.0 3.1 -12 0 7 0.0 2.6 -13 6 6 0.0 2.8

-12 7 1 0.0 2.7 -12 0 6 0.0 4.1 -13 6 5 0.0 5.7

-12 7 0 0.0 2.5 -12 0 5 0.0 5.8 -13 6 4 17.6 18.3

-12 6 9 0.0 6.1 -12 0 4 23.8 25.9 -13 6 3 0.0 9.7

H K L FO FC H K L FO FC H K L FO FC

-13 6 2 0.0 9.6 -14 12 4 0.0 11.1 -14 5 0 22.7 22.5

-13 6 1 0.0 9.1 -14 12 3 0.0 6.5 -14 4 7 0.0 1.6

-13 6 0 17.2 17.0 -14 12 2 0.0 3.5 -14 4 6 0.0 18.7

-13 5 8 0.0 16.3 -14 12 1 0.0 3.2 -14 4 5 0.0 3.5

-13 5 7 0.0 6.8 -14 12 0 0.0 11.8 -14 4 4 0.0 5.1

-13 5 6 0.0 4.4 14-11 7 0.0 0.2 -14 4 3 0.0 6.3

-13 5 5 0.0 15.0 -14 11 6 0.0 6.4 -14 4 2 23.7 24.8

-13 5 4 25.8 26.8 -14 11 5 0.0 4.2 -14 4 1 0.0 1.4

-13 5 3 0.0 8.2 -14 11 4 0.0 9.6 -14 4 0 0.0 6.8

-13 5 2 0.0 7.6 -14 11 3 0.0 1.4 -14 3 6 0.0 1.8

-13 5 1 14.6 15.3 -14 11 2 0.0 3.8 -14 3 5 0.0 8.7

-13 5 0 34.1 33.5 -14 11 1 0.0 4.0 -14 3 4 0.0 8.0

-13 4 8 0.0 2.1 -14 11 0 0.0 1.0 -14 3 3 0.0 10.0

-13 4 7 0.0 4.5 -14 10 6 0.0 14.4 -14 3 2 0.0 2.4

-13 4 6 0.0 19.1 -14 10 5 0.0 1.2 -14 3 1 0.0 9.8

-13 4 5 0.0 0.3 -14 10 4 0.0 4.8 -14 3 0 0.0 6.0

-13 4 4 0.0 2.0 -14 10 3 0.0 2.3 -14 2 5 0.0 0.1

-13 4 3 0.0 5.9 -14 10 2 28.8 29.8 -14 2 4 0.0 12.9

-13 4 2 0.0 12.2 -14 10 1 0.0 1.1 -14 2 3 0.0 2.0

-13 4 1 0.0 3.3 -14 10 0 0.0 13.8 -14 2 2 0.0 8.9

-13 4 0 0.0 13.9 -14 9 7 0.0 19.6 -14 2 1 0.0 0.7

-13 3 7 0.0 6.7 -14 9 6 0.0 6.2 -14 2 0 0.0 9.0

-13 3 6 0.0 8.9 -14 9 5 0.0 27.5 -14 1 5 0.0 11.9

-13 3 5 0.0 4.7 -14 9 4 0.0 17.7 -14 1 4 0.0 8.0

-13 3 4 23.8 24.4 -14 9 3 24.0 25.3 -14 1 3 0.0 17.6

-13 3 3 0.0 8.3 -14 9 2 0.0 8.2 -14 1 2 0.0 16.9

-13 3 2 17.1 15.6 -14 9 1 32.0 31.8 -14 1 1 0.0 14.6

-13 3 1 0.0 6.1 -14 9 0 18.3 19.8 -14 1 0 0.0 8.9

-13 3 0 25.2 24.6 -14 8 7 0.0 1.4 -14 0 4 0.0 11.4

-13 2 7 0.0 7.9 -14 8 6 0.0 1.7 -14 0 3 0.0 8.6

-13 2 6 0.0 10.6 -14 8 5 0.0 6.4 -14 0 2 0.0 7.1

-13 2 5 0.0 5.2 -14 8 4 0.0 14.7 -14 0 1 0.0 10.4

-13 2 4 0.0 18.3 -14 8 3 0.0 1.8 -14 0 0 0.0 9.3

-13 2 3 0.0 15.9 -14 8 2 0.0 6.5 15-14 2 0.0 4.1

-13 2 2 0.0 14.6 -14 8 1 0.0 6.1 -15 14 1 0.0 11.7

-13 2 1 0.0 8.2 -14 8 0 0.0 9.6 -15 14 0 0.0 1.7

-13 2 0 21.9 21.4 -14 7 7 0.0 10.5 15-14 3 0.0 11.5

-13 1 6 0.0 3.5 -14 7 6 0.0 17.9 15-14 4 0.0 8.2

-13 1 5 0.0 5.7 -14 7 5 0.0 17.2 15-13 5 0.0 0.5

-13 1 4 0.0 8.5 -14 7 4 0.0 3.1 -15 13 4 0.0 8.1

-13 1 3 0.0 14.9 -14 7 3 0.0 14.5 15-13 3 0.0 4.7

-13 1 2 0.0 0.8 -14 7 2 29.2 30.1 15-13 2 0.0 1.3

-13 1 1 0.0 10.4 -14 7 1 19.5 19.2 -15 13 1 0.0 2.7

-13 1 0 0.0 7.2 -14 7 0 0.0 9.1 -15 13 0 0.0 7.7

-13 0 6 0.0 1.8 -14 6 7 0.0 15.6 -15 12 5 0.0 4.7

-13 0 5 0.0 1.0 -14 6 6 0.0 5.2 -15 12 4 0.0 23.3

-13 0 4 0.0 7.7 -14 6 5 0.0 20.0 -15 12 3 0.0 2.2

-13 0 3 0.0 2.5 -14 6 4 0.0 15.5 -15 12 2 0.0 0.5

-13 0 2 0.0 0.4 -14 6 3 0.0 16.3 -15 12 1 0.0 3.5

-13 0 1 0.0 0.6 -14 6 2 0.0 7.3 -15 12 0 29.1 29.0

-13 0 0 0.0 7.2 -14 6 1 23.9 24.1 15-11 6 0.0 13.0

-14 13 5 0.0 11.5 -14 6 0 17.2 18.3 -15 11 5 0.0 6.1

14-13 4 0.0 4.4 -14 5 7 0.0 0.2 -15 11 4 0.0 1.9

-14 13 3 0.0 17.3 -14 5 6 0.0 8.9 -15 11 3 0.0 2.8

-14 13 2 23.4 25.8 -14 5 5 0.0 0.4 -15 11 2 0.0 10.5

-14 13 1 0.0 14.4 -14 5 4 0.0 22.2 -15 11 1 0.0 5.9

-14 13 0 0.0 9.2 -14 5 3 0.0 3.1 -15 11 0 0.0 7.4

14-12 6 0.0 1.3 -14 5 2 0.0 16.1 15-10 6 0.0 2.7

-14 12 5 0.0 2.2 -14 5 1 0.0 1.2 -15 10 5 0.0 2.0

H K L FO FC H K L FO FC H K L FO FC

-15 10 4 0.0 12.1 -15 2 2 0.0 1.3 -16 8 0 0.0 19.8

-15 10 3 0.0 0.3 -15 2 1 0.0 15.4 -16 7 4 0.0 2.9

-15 10 2 0.0 3.6 -15 2 0 0.0 1.8 -16 7 3 0.0 12.2

-15 10 1 0.0 1.9 -15 1 3 0.0 1.3 -16 7 2 0.0 3.3

-15 10 0 0.0 14.0 -15 1 2 0.0 9.3 -16 7 1 0.0 11.9

-15 9 6 0.0 3.8 -15 1 1 0.0 3.1 -16 7 0 0.0 2.1

-15 9 5 0.0 5.6 -15 1 0 0.0 1.2 -16 6 4 0.0 14.4

-15 9 4 0.0 21.3 -15 0 3 0.0 6.1 -16 6 3 0.0 6.4

-15 9 3 0.0 0.1 -15 0 2 0.0 3.0 -16 6 2 0.0 9.6

-15 9 2 0.0 7.0 -15 0 1 0.0 5.4 -16 6 1 0.0 6.3

-15 9 1 0.0 5.6 15 0 0 0.0 22.5 -16 6 0 0.0 8.7

-15 9 0 24.5 26.5 16-15 1 0.0 2.2 -16 5 4 0.0 17.9

-15 8 6 0.0 9.7 16-15 2 0.0 12.1 -16 5 3 0.0 6.1

-15 8 5 0.0 8.5 -16 14 1 0.0 8.3 -16 5 2 0.0 3.8

-15 8 4 0.0 1.0 -16 14 0 0.0 7.9 -16 5 1 0.0 3.3

-15 8 3 0.0 0.6 16-14 2 0.0 12.5 -16 5 0 0.0 19.9

-15 8 2 0.0 9.7 16-14 3 0.0 5.9 -16 4 3 0.0 1.5

-15 8 1 0.0 7.8 16-13 4 0.0 0.6 -16 4 2 0.0 14.6

-15 8 0 0.0 2.9 -16 13 2 0.0 7.5 -16 4 1 0.0 0.7

-15 7 6 0.0 21.1 -16 13 1 0.0 0.5 -16 4 0 0.0 10.3

-15 7 5 0.0 0.1 -16 13 0 0.0 0.7 -16 3 3 0.0 7.8

-15 7 4 0.0 16.4 16-13 3 0.0 2.3 -16 3 2 0.0 0.9

-15 7 3 0.0 2.7 16-12 5 0.0 1.6 -16 3 1 0.0 5.3

-15 7 2 25.7 27.4 16-12 4 0.0 15.3 -16 3 0 0.0 4.9

-15 7 1 0.0 0.4 -16 12 3 0.0 2.3 -16 2 3 0.0 11.2

-15 7 0 19.0 19.2 -16 12 2 0.0 22.3 -16 2 2 0.0 15.9

-15 6 6 0.0 7.9 -16 12 1 0.0 1.8 -16 2 1 0.0 9.8

-15 6 5 0.0 10.2 -16 12 0 0.0 20.0 -16 2 0 0.0 5.9

-15 6 4 0.0 12.7 16-11 5 0.0 1.0 -16 1 2 0.0 5.6

-15 6 3 0.0 9.3 -16 11 4 0.0 14.2 -16 1 1 0.0 3.9

-15 6 2 19.2 19.7 -16 11 3 0.0 5.9 -16 1 0 0.0 2.4

-15 6 1 0.0 12.4 -16 11 2 0.0 8.0 17-14 1 0.0 1.2

-15 6 0 20.9 21.5 -16 11 1 0.0 1.0 17-12 3 0.0 0.1

-15 5 5 0.0 1.2 -16 11 0 0.0 15.6 17-11 3 0.0 9.7

-15 5 4 0.0 6.3 16-10 5 0.0 3.0 17-11 2 0.0 7.7

-15 5 3 0.0 6.5 -16 10 4 0.0 7.3 17-10 4 0.0 0.7

-15 5 2 0.0 0.7 -16 10 3 0.0 3.1 17-10 3 0.0 15.8

-15 5 1 0.0 2.4 -16 10 2 0.0 2.4 17-10 2 0.0 22.1

-15 5 0 0.0 4.2 -16 10 1 0.0 2.5 17 -9 3 0.0 4.9

-15 4 5 0.0 4.6 -16 10 0 0.0 4.5 -17 9 2 0.0 3.8

-15 4 4 0.0 19.3 16 -9 6 0.0 15.2 -17 9 1 0.0 4.6

-15 4 3 0.0 3.8 16 -9 5 0.0 0.6 -17 9 0 0.0 1.5

-15 4 2 0.0 30.0 -16 9 4 0.0 5.9 -17 8 2 0.0 0.4

-15 4 1 0.0 4.0 -16 9 3 0.0 0.1 -17 8 1 0.0 2.7

-15 4 0 18.7 22.5 -16 9 2 0.0 10.8 -17 8 0 0.0 6.6

-15 3 4 0.0 10.5 -16 9 1 0.0 0.9 -17 7 2 0.0 19.8

-15 3 3 0.0 1.0 -16 9 0 0.0 12.9 -17 7 1 0.0 16.2

-15 3 2 0.0 17.7 -16 8 4 0.0 17.9 -17 5 1 0.0 1.6

-15 3 1 0.0 0.9 -16 8 3 0.0 11.9 -17 4 2 0.0 9.8

-15 3 0 19.1 20.4 -16 8 2 0.0 5.5 -17 4 1 0.0 3.3

-15 2 3 0.0 14.9 -16 8 1 0.0 11.0 -17 3 1 0.0 15.4

 

 

 

 

 

 

 

 

 

Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:

Uptake, Site Preference and

Degradation of Monoclinic Structure

Michael E. Fleet, Xioayang Liu

and Yuanming Pan

 

 

Deposited Material

 

 

Table 5. List of observed and calculated structure factors

 

 

(d) P63/m structure of Dy-chlorapatite

H K L FO FC H K L FO FC H K L FO FC

0 0 2 98.9 100.8 1 -3 0 0.0 2.4 4 -5 3 0.0 0.7

0 0 4 206.7 202.6 -3 0 10 0.0 3.8 4 -5 2 37.9 38.2

0 0 6 95.9 95.2 -3 0 9 0.0 5.5 4 -5 1 0.0 3.1

0 0 8 82.0 76.5 -3 0 8 33.1 33.9 4 -5 0 96.9 97.6

0 0 10 37.0 39.3 -3 0 7 0.0 9.2 3 -5 9 0.0 16.6

-1 0 10 0.0 11.5 -3 0 6 0.0 7.9 3 -5 8 0.0 1.6

-1 0 9 0.0 2.5 -3 0 5 0.0 10.2 3 -5 7 23.7 25.2

-1 0 8 0.0 15.5 -3 0 4 77.9 77.2 3 -5 6 30.7 30.7

-1 0 7 0.0 5.1 -3 0 3 25.1 25.1 3 -5 5 28.0 28.3

-1 0 6 19.4 19.1 -3 0 2 44.9 44.2 3 -5 4 0.0 11.4

-1 0 5 0.0 7.9 -3 0 1 26.9 26.4 3 -5 3 51.4 51.3

-1 0 4 23.6 23.4 -3 0 0 155.7 155.4 3 -5 2 41.1 41.4

-1 0 3 0.0 4.2 3 -4 9 0.0 13.9 3 -5 1 50.2 50.6

-1 0 2 0.0 0.5 3 -4 8 0.0 3.7 3 -5 0 15.3 14.7

-1 0 1 16.2 16.3 3 -4 7 0.0 7.6 2 -5 9 0.0 18.1

-1 0 0 15.9 16.2 3 -4 6 0.0 14.6 2 -5 8 0.0 21.8

1 -2 10 0.0 30.4 3 -4 5 0.0 5.6 2 -5 7 0.0 19.6

1 -2 9 0.0 6.9 3 -4 4 0.0 4.5 2 -5 6 0.0 6.5

1 -2 8 0.0 2.7 3 -4 3 41.3 40.9 2 -5 5 49.1 49.8

1 -2 7 0.0 4.2 3 -4 2 39.5 39.4 2 -5 4 38.7 39.1

1 -2 6 66.5 65.3 3 -4 1 9.6 7.7 2 -5 3 17.2 17.8

1 -2 5 0.0 13.2 3 -4 0 19.6 19.6 2 -5 2 12.8 13.2

1 -2 4 11.8 11.8 2 -4 10 0.0 26.5 2 -5 1 63.6 63.6

1 -2 3 42.2 41.6 2 -4 9 0.0 0.1 2 -5 0 61.3 60.7

1 -2 2 113.8 114.9 2 -4 8 0.0 1.7 1 -5 9 0.0 5.6

1 -2 1 13.0 13.4 2 -4 7 0.0 2.6 1 -5 8 25.6 27.8

1 -2 0 0.0 3.8 2 -4 6 51.3 51.0 1 -5 7 0.0 6.2

-2 0 10 0.0 11.5 2 -4 5 0.0 9.7 1 -5 6 16.3 18.1

-2 0 9 0.0 1.3 2 -4 4 0.0 3.9 1 -5 5 0.0 0.7

-2 0 8 0.0 7.8 2 -4 3 9.4 9.6 1 -5 4 51.5 51.1

-2 0 7 0.0 1.1 2 -4 2 119.5 118.4 1 -5 3 17.7 18.8

-2 0 6 20.2 19.7 2 -4 1 0.0 8.0 1 -5 2 32.8 33.1

-2 0 5 19.4 20.6 2 -4 0 21.9 22.2 1 -5 1 0.0 3.7

-2 0 4 0.0 5.4 1 -4 9 0.0 13.0 1 -5 0 67.6 68.1

-2 0 3 26.1 25.4 1 -4 8 0.0 13.7 -5 0 9 0.0 2.0

-2 0 2 39.5 39.0 1 -4 7 24.1 24.9 -5 0 8 0.0 10.3

-2 0 1 23.4 23.2 1 -4 6 43.1 43.8 -5 0 7 0.0 3.7

-2 0 0 6.3 5.2 1 -4 5 27.3 26.8 -5 0 6 34.4 33.0

2 -3 10 0.0 1.4 1 -4 4 0.0 4.9 -5 0 5 24.4 25.5

2 -3 9 0.0 33.8 1 -4 3 39.6 39.2 -5 0 4 18.8 18.8

2 -3 8 0.0 20.7 1 -4 2 29.3 29.0 -5 0 3 0.0 8.8

2 -3 7 35.5 36.5 1 -4 1 43.1 43.2 -5 0 2 54.7 54.4

2 -3 6 0.0 0.7 1 -4 0 88.9 85.1 -5 0 1 33.5 33.2

2 -3 5 58.7 58.3 -4 0 9 0.0 3.7 -5 0 0 12.3 12.8

2 -3 4 29.3 29.4 -4 0 8 0.0 6.4 5 -6 9 0.0 30.6

2 -3 3 81.2 81.3 -4 0 7 0.0 9.3 5 -6 8 38.2 37.8

2 -3 2 9.9 9.5 -4 0 6 36.2 37.0 5 -6 7 32.7 33.6

2 -3 1 96.5 97.4 -4 0 5 12.5 14.1 5 -6 6 0.0 9.8

2 -3 0 43.2 44.7 -4 0 4 14.1 13.8 5 -6 5 52.7 52.3

1 -3 10 0.0 7.2 -4 0 3 0.0 3.4 5 -6 4 53.0 52.9

1 -3 9 0.0 21.3 -4 0 2 52.5 52.8 5 -6 3 58.7 57.9

1 -3 8 30.5 31.8 -4 0 1 13.1 13.1 5 -6 2 46.6 47.5

1 -3 7 34.7 34.4 -4 0 0 25.2 25.5 5 -6 1 71.0 70.4

1 -3 6 0.0 14.9 4 -5 9 0.0 0.5 5 -6 0 43.2 43.6

1 -3 5 38.7 38.2 4 -5 8 0.0 20.9 4 -6 9 0.0 7.1

1 -3 4 40.6 40.6 4 -5 7 0.0 3.0 4 -6 8 37.7 38.2

1 -3 3 64.6 64.8 4 -5 6 0.0 13.9 4 -6 7 0.0 16.1

1 -3 2 50.3 48.8 4 -5 5 0.0 2.5 4 -6 6 0.0 4.5

1 -3 1 68.4 69.5 4 -5 4 54.3 54.6 4 -6 5 17.5 16.9

H K L FO FC H K L FO FC H K L FO FC

4 -6 4 44.1 44.0 5 -7 4 42.2 42.0 7 -8 2 42.1 43.4

4 -6 3 26.9 27.2 5 -7 3 38.0 37.9 7 -8 1 15.8 15.2

4 -6 2 48.3 48.6 5 -7 2 30.2 30.0 7 -8 0 49.1 48.7

4 -6 1 30.7 30.5 5 -7 1 33.4 33.9 6 -8 8 0.0 3.6

4 -6 0 0.0 11.3 5 -7 0 78.6 79.1 6 -8 7 0.0 4.1

3 -6 9 0.0 9.5 -4 7 9 0.0 15.3 6 -8 6 0.0 11.7

3 -6 8 0.0 12.7 4 -7 8 0.0 13.6 6 -8 5 0.0 11.2

3 -6 7 0.0 18.3 4 -7 7 25.7 26.9 6 -8 4 0.0 3.4

3 -6 6 32.7 32.8 4 -7 6 0.0 8.1 6 -8 3 0.0 7.9

3 -6 5 28.1 29.2 4 -7 5 20.6 21.9 6 -8 2 18.3 18.4

3 -6 4 28.4 29.4 4 -7 4 21.2 20.8 6 -8 1 0.0 10.8

3 -6 3 15.5 15.0 4 -7 3 51.7 53.1 6 -8 0 0.0 7.5

3 -6 2 52.7 53.4 4 -7 2 0.0 1.2 5 -8 8 0.0 4.1

3 -6 1 39.5 39.9 4 -7 1 41.6 41.5 5 -8 7 0.0 11.2

3 -6 0 41.0 41.4 4 -7 0 19.3 18.4 5 -8 6 0.0 14.2

2 -6 9 0.0 20.8 -3 7 9 0.0 2.2 5 -8 5 0.0 3.6

2 -6 8 31.3 32.8 3 -7 8 0.0 14.0 5 -8 4 0.0 3.3

2 -6 7 0.0 18.7 3 -7 7 0.0 1.4 5 -8 3 18.8 19.8

2 -6 6 0.0 16.0 3 -7 6 42.8 41.7 5 -8 2 16.2 17.2

2 -6 5 22.7 22.7 3 -7 5 0.0 8.0 5 -8 1 0.0 11.0

2 -6 4 48.4 47.9 3 -7 4 29.5 29.7 5 -8 0 0.0 2.6

2 -6 3 45.7 46.2 3 -7 3 0.0 3.7 4 -8 8 0.0 37.4

2 -6 2 36.4 36.8 3 -7 2 62.2 62.4 4 -8 7 0.0 13.2

2 -6 1 31.0 31.4 3 -7 1 0.0 9.0 4 -8 6 0.0 2.9

2 -6 0 58.6 58.3 3 -7 0 39.9 41.5 4 -8 5 24.4 26.3

1 -6 9 0.0 7.6 -2 7 9 0.0 6.2 4 -8 4 63.3 63.4

1 -6 8 0.0 17.6 2 -7 8 0.0 5.5 4 -8 3 0.0 8.8

1 -6 7 0.0 18.3 2 -7 7 0.0 6.8 4 -8 2 0.0 2.7

1 -6 6 0.0 14.6 2 -7 6 22.9 24.7 4 -8 1 33.3 34.0

1 -6 5 19.6 19.6 2 -7 5 0.0 7.8 4 -8 0 78.7 76.8

1 -6 4 12.5 11.6 2 -7 4 0.0 9.2 3 -8 8 0.0 14.0

1 -6 3 18.2 18.1 2 -7 3 0.0 9.5 3 -8 7 0.0 4.8

1 -6 2 0.0 1.7 2 -7 2 84.2 84.4 3 -8 6 42.2 40.9

1 -6 1 28.3 29.1 2 -7 1 0.0 10.1 3 -8 5 0.0 7.3

1 -6 0 0.0 4.3 2 -7 0 49.7 50.6 3 -8 4 26.3 26.4

6 0 9 0.0 10.8 1 -7 8 31.5 31.0 3 -8 3 0.0 7.5

-6 0 8 0.0 10.0 1 -7 7 0.0 5.5 3 -8 2 53.0 53.0

-6 0 7 0.0 16.5 -1 7 6 0.0 3.7 3 -8 1 0.0 9.6

6 0 6 35.7 36.3 1 -7 5 0.0 13.6 3 -8 0 37.7 36.8

-6 0 5 0.0 8.1 1 -7 4 40.7 41.3 2 -8 8 0.0 21.5

-6 0 4 18.9 20.3 1 -7 3 0.0 15.6 2 -8 7 0.0 3.6

-6 0 3 29.2 29.5 1 -7 2 32.6 33.7 2 -8 6 0.0 1.8

-6 0 2 53.5 52.4 1 -7 1 19.4 20.5 2 -8 5 0.0 0.2

-6 0 1 14.2 15.0 1 -7 0 29.6 30.0 2 -8 4 27.3 28.0

-6 0 0 23.7 25.0 -7 0 8 0.0 5.1 2 -8 3 0.0 4.6

6 -7 8 0.0 15.3 -7 0 7 0.0 8.2 2 -8 2 0.0 12.0

6 -7 7 0.0 4.8 7 0 6 26.0 25.4 2 -8 1 0.0 3.0

6 -7 6 0.0 1.1 -7 0 5 0.0 1.4 2 -8 0 18.1 17.1

6 -7 5 0.0 7.6 -7 0 4 0.0 12.9 1 -8 8 0.0 33.5

6 -7 4 23.2 23.5 -7 0 3 21.6 22.0 1 -8 7 0.0 10.8

6 -7 3 0.0 4.9 -7 0 2 36.0 36.3 -1 8 6 0.0 1.3

6 -7 2 0.0 3.5 -7 0 1 0.0 4.8 1 -8 5 0.0 1.5

6 -7 1 0.0 9.2 -7 0 0 15.9 15.9 1 -8 4 55.0 54.1

6 -7 0 30.8 30.9 7 -8 8 0.0 10.2 1 -8 3 25.9 26.9

-5 7 9 0.0 15.7 7 -8 7 0.0 9.9 1 -8 2 0.0 0.8

5 -7 8 0.0 18.3 7 -8 6 0.0 14.6 1 -8 1 0.0 10.5

5 -7 7 0.0 22.2 7 -8 5 0.0 13.0 1 -8 0 67.2 65.2

5 -7 6 0.0 5.6 7 -8 4 28.5 28.0 -8 0 8 0.0 15.4

5 -7 5 20.0 21.3 7 -8 3 0.0 10.6 -8 0 7 0.0 2.7

H K L FO FC H K L FO FC H K L FO FC

8 0 6 50.3 48.5 3 -9 0 0.0 0.5 5-10 5 0.0 23.7

-8 0 5 0.0 3.4 2 -9 8 0.0 20.3 5-10 4 0.0 15.7

-8 0 4 35.6 34.8 2 -9 7 0.0 14.2 5-10 3 24.3 25.3

-8 0 3 0.0 4.8 2 -9 6 0.0 6.8 5-10 2 42.9 42.3

-8 0 2 53.1 52.8 2 -9 5 0.0 11.4 5-10 1 31.1 30.5

-8 0 1 0.0 1.1 2 -9 4 26.2 25.8 5-10 0 39.3 39.2

-8 0 0 56.5 55.3 2 -9 3 0.0 22.8 4-10 7 0.0 3.0

8 -9 7 0.0 6.3 2 -9 2 15.2 15.4 4-10 6 0.0 0.5

8 -9 6 24.6 25.7 2 -9 1 0.0 17.6 4-10 5 0.0 5.6

8 -9 5 0.0 10.8 2 -9 0 26.2 27.1 4-10 4 0.0 17.0

8 -9 4 0.0 2.8 1 -9 7 0.0 5.4 4-10 3 0.0 0.2

8 -9 3 0.0 11.9 -1 9 6 0.0 1.6 4-10 2 0.0 1.7

8 -9 2 0.0 4.9 1 -9 5 0.0 2.6 4-10 1 0.0 2.7

8 -9 1 0.0 14.1 1 -9 4 0.0 13.9 4-10 0 0.0 18.3

8 -9 0 21.4 22.0 1 -9 3 0.0 0.6 3-10 7 0.0 8.0

-7 9 8 0.0 18.2 1 -9 2 0.0 1.1 3-10 6 0.0 20.2

7 -9 7 0.0 12.6 1 -9 1 0.0 6.7 3-10 5 0.0 13.1

7 -9 6 0.0 1.2 1 -9 0 15.7 18.4 3-10 4 0.0 2.5

7 -9 5 0.0 14.9 9 0 7 0.0 17.5 3-10 3 0.0 7.8

7 -9 4 0.0 20.1 9 0 6 0.0 23.2 3-10 2 0.0 11.0

7 -9 3 0.0 16.6 9 0 5 0.0 15.6 3-10 1 0.0 14.7

7 -9 2 0.0 8.0 -9 0 4 0.0 10.7 3-10 0 0.0 15.1

7 -9 1 17.1 18.9 -9 0 3 30.4 28.7 2-10 7 0.0 10.4

7 -9 0 0.0 15.0 -9 0 2 40.7 39.2 -2 10 6 0.0 20.3

-6 9 8 0.0 4.7 -9 0 1 24.7 24.2 2-10 5 0.0 14.1

6 -9 7 33.7 35.6 -9 0 0 0.0 18.7 2-10 4 0.0 9.2

6 -9 6 44.8 43.4 9-10 6 0.0 1.1 2-10 3 0.0 17.6

6 -9 5 45.6 44.8 9-10 5 0.0 13.1 2-10 2 49.2 48.1

6 -9 4 0.0 4.4 9-10 4 0.0 17.1 2-10 1 20.4 18.6

6 -9 3 46.3 46.5 9-10 3 30.2 28.9 2-10 0 26.3 28.3

6 -9 2 68.6 67.1 9-10 2 0.0 3.1 -1 10 6 0.0 1.4

6 -9 1 60.8 60.3 9-10 1 22.2 21.1 -1 10 5 0.0 9.3

6 -9 0 0.0 3.3 9-10 0 0.0 14.1 1-10 4 0.0 12.3

-5 9 8 0.0 15.9 8-10 7 0.0 2.7 1-10 3 20.4 21.1

5 -9 7 0.0 8.0 8-10 6 0.0 9.1 1-10 2 0.0 1.0

5 -9 6 0.0 17.7 8-10 5 0.0 1.3 1-10 1 0.0 12.5

5 -9 5 0.0 14.1 8-10 4 27.8 27.8 1-10 0 0.0 13.9

5 -9 4 0.0 7.2 8-10 3 0.0 1.1 10 0 6 0.0 1.2

5 -9 3 0.0 13.2 8-10 2 0.0 19.3 10 0 5 0.0 4.9

5 -9 2 0.0 1.8 8-10 1 0.0 0.6 -10 0 4 0.0 11.3

5 -9 1 0.0 17.0 8-10 0 39.0 39.2 -10 0 3 0.0 6.5

5 -9 0 0.0 14.5 7-10 7 0.0 13.8 -10 0 2 0.0 1.9

-4 9 8 0.0 12.2 7-10 6 0.0 1.6 -10 0 1 0.0 3.1

4 -9 7 0.0 9.3 7-10 5 0.0 2.5 -10 0 0 0.0 11.0

4 -9 6 0.0 7.1 7-10 4 0.0 16.4 10-11 5 0.0 22.7

4 -9 5 0.0 21.4 7-10 3 0.0 24.9 10-11 4 0.0 10.9

4 -9 4 0.0 13.0 7-10 2 0.0 0.9 10-11 3 31.4 33.2

4 -9 3 0.0 16.2 7-10 1 0.0 9.3 10-11 2 31.3 31.2

4 -9 2 0.0 0.7 7-10 0 20.2 21.0 10-11 1 31.1 30.1

4 -9 1 24.6 26.1 -6 10 7 0.0 1.0 10-11 0 0.0 14.6

4 -9 0 0.0 9.6 6-10 6 0.0 18.0 9-11 6 0.0 4.9

3 -9 8 0.0 1.5 6-10 5 0.0 5.4 9-11 5 0.0 6.2

3 -9 7 0.0 8.3 6-10 4 0.0 5.3 9-11 4 0.0 19.4

3 -9 6 39.7 40.6 6-10 3 0.0 4.1 9-11 3 0.0 17.1

3 -9 5 0.0 20.5 6-10 2 0.0 7.0 9-11 2 0.0 8.4

3 -9 4 0.0 2.5 6-10 1 0.0 5.9 9-11 1 0.0 9.2

3 -9 3 0.0 0.4 6-10 0 0.0 9.1 9-11 0 0.0 21.3

3 -9 2 58.0 56.7 5-10 7 0.0 17.2 8-11 6 0.0 11.4

3 -9 1 20.5 20.8 5-10 6 0.0 13.6 8-11 5 0.0 15.3

H K L FO FC H K L FO FC H K L FO FC

8-11 4 0.0 1.7 11-12 4 0.0 17.8 2-12 2 0.0 11.0

8-11 3 0.0 13.6 11-12 3 0.0 1.7 2-12 1 0.0 22.4

8-11 2 0.0 6.2 11-12 2 29.2 28.9 2-12 0 22.0 24.6

8-11 1 0.0 21.0 11-12 1 0.0 1.2 -1 12 4 0.0 5.8

8-11 0 0.0 3.4 11-12 0 27.1 28.2 1-12 3 0.0 7.9

7-11 6 0.0 7.5 10-12 5 0.0 11.8 1-12 2 0.0 3.7

7-11 5 0.0 6.8 10-12 4 0.0 9.7 1-12 1 0.0 8.8

7-11 4 30.9 31.5 10-12 3 0.0 16.9 1-12 0 0.0 1.8

7-11 3 0.0 9.9 10-12 2 0.0 1.7 -12 0 3 0.0 2.6

7-11 2 0.0 11.8 10-12 1 0.0 17.2 -12 0 2 0.0 6.6

7-11 1 0.0 10.3 10-12 0 0.0 11.2 -12 0 1 0.0 4.9

7-11 0 38.4 37.6 9-12 5 0.0 10.8 -12 0 0 0.0 37.6

6-11 6 0.0 8.8 9-12 4 0.0 13.4 12-13 2 0.0 1.2

6-11 5 0.0 5.8 9-12 3 0.0 11.5 12-13 1 0.0 9.4

6-11 4 0.0 8.0 9-12 2 30.5 29.2 12-13 0 0.0 6.2

6-11 3 0.0 16.4 9-12 1 0.0 13.4 11-13 3 0.0 14.3

6-11 2 0.0 6.9 9-12 0 29.6 28.4 11-13 2 0.0 13.9

6-11 1 0.0 9.7 8-12 5 0.0 2.9 11-13 1 0.0 6.7

6-11 0 0.0 3.3 8-12 4 0.0 20.7 11-13 0 21.8 19.8

5-11 6 0.0 12.1 8-12 3 0.0 6.6 10-13 4 0.0 23.0

5-11 5 0.0 27.8 8-12 2 30.5 29.2 10-13 3 0.0 8.3

5-11 4 31.9 30.2 8-12 1 0.0 5.8 10-13 2 0.0 14.7

5-11 3 0.0 20.3 8-12 0 36.2 34.8 10-13 1 0.0 6.1

5-11 2 0.0 19.7 7-12 6 0.0 7.9 10-13 0 0.0 23.0

5-11 1 34.3 32.4 7-12 5 0.0 18.5 9-13 4 0.0 1.5

5-11 0 35.5 34.2 7-12 4 0.0 2.8 9-13 3 0.0 5.7

4-11 6 0.0 2.0 7-12 3 0.0 8.7 9-13 2 0.0 11.2

4-11 5 0.0 7.8 7-12 2 0.0 9.8 9-13 1 0.0 3.4

4-11 4 41.6 41.5 7-12 1 0.0 20.5 9-13 0 0.0 13.0

4-11 3 0.0 0.4 7-12 0 0.0 4.5 8-13 4 0.0 25.7

4-11 2 0.0 0.7 6-12 6 0.0 16.3 8-13 3 0.0 8.4

4-11 1 0.0 7.8 6-12 5 0.0 12.5 8-13 2 0.0 6.8

4-11 0 51.7 50.7 6-12 4 0.0 14.9 8-13 1 0.0 15.4

3-11 6 0.0 26.4 6-12 3 0.0 9.7 8-13 0 31.3 32.3

3-11 5 0.0 4.9 6-12 2 30.8 29.7 7-13 5 0.0 4.9

3-11 4 0.0 5.0 6-12 1 0.0 14.4 7-13 4 0.0 16.9

3-11 3 0.0 4.9 6-12 0 0.0 23.3 7-13 3 0.0 9.1

3-11 2 0.0 15.4 5-12 6 0.0 6.6 7-13 2 0.0 8.7

3-11 1 0.0 5.3 5-12 5 0.0 2.7 7-13 1 0.0 8.4

3-11 0 22.5 22.1 5-12 4 0.0 5.6 7-13 0 0.0 15.3

-2 11 6 0.0 1.0 5-12 3 0.0 3.8 6-13 5 0.0 15.8

2-11 5 0.0 27.7 5-12 2 0.0 2.2 6-13 4 0.0 1.8

2-11 4 0.0 19.4 5-12 1 0.0 2.8 6-13 3 0.0 16.0

2-11 3 0.0 27.1 5-12 0 0.0 3.1 6-13 2 0.0 7.7

2-11 2 0.0 9.2 4-12 5 0.0 20.9 6-13 1 0.0 18.1

2-11 1 33.1 34.0 4-12 4 0.0 10.1 6-13 0 0.0 18.0

2-11 0 0.0 14.2 4-12 3 0.0 11.0 5-13 4 0.0 8.2

-1 11 5 0.0 11.7 4-12 2 0.0 25.0 5-13 3 0.0 0.7

1-11 4 0.0 30.6 4-12 1 0.0 21.6 5-13 2 0.0 28.4

1-11 3 0.0 12.2 4-12 0 0.0 11.9 5-13 1 0.0 1.0

1-11 2 0.0 7.9 3-12 5 0.0 5.5 5-13 0 0.0 13.3

1-11 1 0.0 12.6 3-12 4 0.0 24.0 4-13 4 0.0 3.0

1-11 0 41.8 39.5 3-12 3 0.0 8.1 4-13 3 0.0 8.3

11 0 5 0.0 15.7 3-12 2 0.0 12.7 4-13 2 0.0 12.4

-11 0 4 0.0 2.9 3-12 1 0.0 8.0 4-13 1 0.0 1.9

-11 0 3 0.0 17.7 3-12 0 30.7 31.6 4-13 0 0.0 5.1

-11 0 2 0.0 0.5 -2 12 5 0.0 14.4 3-13 4 0.0 0.6

-11 0 1 0.0 19.1 2-12 4 0.0 20.8 3-13 3 0.0 15.1

-11 0 0 0.0 9.6 2-12 3 0.0 31.5 3-13 2 0.0 5.9

H K L FO FC H K L FO FC H K L FO FC

3-13 1 0.0 16.4 9-14 3 0.0 3.2 6-14 2 0.0 6.3

3-13 0 0.0 7.7 9-14 2 0.0 14.9 6-14 1 0.0 5.4

2-13 3 0.0 10.6 9-14 1 0.0 1.2 6-14 0 0.0 9.2

2-13 2 0.0 33.1 9-14 0 0.0 21.2 5-14 3 0.0 23.2

2-13 1 0.0 12.3 8-14 3 0.0 15.2 5-14 2 0.0 7.2

2-13 0 0.0 0.4 8-14 2 0.0 6.3 5-14 1 0.0 29.5

1-13 2 0.0 20.6 8-14 1 0.0 22.7 5-14 0 0.0 17.9

1-13 1 0.0 0.1 8-14 0 0.0 16.7 4-14 2 0.0 28.2

1-13 0 0.0 12.4 7-14 3 0.0 14.1 4-14 1 0.0 2.0

11-14 1 0.0 9.7 7-14 2 0.0 28.1 4-14 0 0.0 13.2

10-14 2 0.0 23.0 7-14 1 0.0 18.4 3-14 1 0.0 3.2

10-14 1 0.0 2.5 7-14 0 0.0 9.0 3-14 0 0.0 0.2

10-14 0 0.0 6.6 6-14 3 0.0 1.1 0 0 0 0.0 0.0

 

Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:

Uptake, Site Preference and

Degradation of Monoclinic Structure

Michael E. Fleet, Xioayang Liu

and Yuanming Pan

 

 

Deposited Material

 

 

Table 5. List of observed and calculated structure factors

 

 

(e) P21/b structure of La-chlorapatite

H K L FO FC H K L FO FC H K L FO FC

0 0 2 199.2 210.2 0 -6 1 53.7 52.0 2 6 1 127.2 128.1

0 0 4 371.9 395.0 -4 4 0 33.9 35.2 3-10 1 126.9 127.6

0 0 6 195.2 194.3 2 4 0 34.0 35.1 -3 4 3 165.3 164.0

0 0 8 157.8 138.3 2 -8 0 36.7 38.1 2 2 3 163.7 162.9

0 -1 2 27.4 24.8 -4 6 0 38.8 39.7 1 -6 3 162.1 161.2

-1 1 2 28.4 27.0 3 2 0 36.5 37.3 -3 2 3 131.0 130.5

1 -3 4 32.2 33.3 1 -8 0 37.7 38.4 1 4 3 130.1 129.7

1 -3 2 23.9 26.8 -4 2 0 185.9 177.5 2 -6 3 127.3 127.0

1 1 2 31.6 31.2 1 6 0 184.1 175.9 -5 2 0 126.4 128.4

0 -3 4 38.0 35.5 3 -8 0 182.3 174.1 1 8 0 129.6 131.6

0 -3 2 28.4 28.3 -3 4 2 17.5 14.7 4-10 0 131.3 133.9

-2 1 4 35.9 40.4 2 2 2 19.9 16.6 -5 8 0 187.1 186.6

-2 3 2 37.1 37.1 1 -6 2 20.1 16.9 4 2 0 185.0 184.3

2 -5 4 32.7 39.9 -3 2 2 103.0 100.1 1-10 0 190.1 189.6

2 -5 2 30.2 34.4 1 4 2 101.5 98.5 -4 8 2 104.7 106.2

1 3 4 35.4 41.7 2 -6 2 101.5 98.4 4 0 2 102.1 103.6

1 3 2 35.1 37.3 -4 4 1 12.8 14.0 0 -8 2 103.8 105.2

1 -5 2 37.4 39.4 2 4 1 14.2 15.8 -3 6 3 48.0 47.5

2 1 2 44.2 43.1 2 -8 1 14.9 16.4 3 0 3 50.7 50.5

0 -5 2 35.6 37.6 -4 6 1 14.6 12.6 0 -6 3 50.8 50.1

-3 3 4 33.8 38.8 3 2 1 16.9 14.2 -5 10 0 29.1 27.3

-3 5 2 30.8 29.9 1 -8 1 19.4 16.5 5 0 0 27.9 26.1

-4 5 4 36.4 38.8 -4 2 1 85.9 87.6 0-10 0 27.7 25.8

-5 7 2 35.1 40.1 1 6 1 85.0 86.7 -5 6 2 79.5 80.4

-1 2 0 27.7 28.3 3 -8 1 85.8 87.5 3 4 2 77.6 78.5

1 0 0 27.6 28.3 -3 6 2 81.0 79.5 2-10 2 78.8 79.9

0 -2 0 27.1 27.7 3 0 2 78.8 77.2 -5 4 2 27.1 27.3

-1 2 1 32.4 32.7 0 -6 2 80.4 78.9 2 6 2 29.6 30.1

1 0 1 31.0 31.3 -4 8 0 54.1 55.7 3-10 2 27.3 27.4

0 -2 1 31.6 31.9 4 0 0 57.4 59.1 -1 2 4 46.6 46.2

-2 4 0 8.3 7.8 0 -8 0 54.8 56.3 1 0 4 47.7 47.2

2 0 0 8.5 7.9 -2 2 3 86.6 85.0 0 -2 4 45.4 45.0

0 -4 0 10.4 9.8 1 2 3 84.9 82.9 -5 10 1 68.0 67.7

-2 2 1 26.0 27.1 1 -4 3 84.4 82.7 5 0 1 67.0 66.5

1 2 1 25.4 26.3 -4 8 1 27.0 27.7 0-10 1 66.5 65.8

1 -4 1 24.3 25.2 4 0 1 25.3 26.0 -4 2 3 77.7 78.4

-2 4 1 46.1 45.4 0 -8 1 23.2 23.8 1 6 3 78.4 78.8

2 0 1 45.3 44.8 -2 4 3 55.7 54.0 3 -8 3 78.9 79.4

0 -4 1 46.1 45.5 2 0 3 52.1 50.6 -4 6 3 79.4 78.8

-3 4 0 83.8 87.0 0 -4 3 52.2 50.5 3 2 3 84.1 83.1

2 2 0 83.3 86.5 -4 4 2 231.9 230.6 1 -8 3 82.5 81.8

1 -6 0 85.3 88.5 2 4 2 232.9 231.4 -6 6 0 78.7 77.1

-3 4 1 194.3 196.9 2 -8 2 235.5 234.1 3 6 0 76.4 74.9

2 2 1 195.0 197.4 -5 6 0 29.5 29.9 3-12 0 78.8 77.8

1 -6 1 196.3 198.6 3 4 0 29.9 30.4 -5 8 2 71.3 71.7

-3 2 1 136.1 138.3 2-10 0 30.3 30.5 4 2 2 69.4 69.4

1 4 1 137.7 139.8 -5 4 0 118.0 116.5 1-10 2 72.6 72.9

2 -6 1 137.7 139.7 2 6 0 119.7 118.2 -5 2 2 58.1 59.1

-3 6 0 317.3 309.5 3-10 0 120.3 119.1 1 8 2 58.6 59.8

3 0 0 314.7 307.2 -4 2 2 57.7 56.4 4-10 2 59.0 60.3

0 -6 0 314.9 307.6 1 6 2 57.5 56.2 -6 4 0 115.7 114.9

-2 2 2 220.2 223.2 3 -8 2 58.6 57.2 2 8 0 114.8 114.3

1 2 2 220.6 223.6 -4 6 2 75.6 74.4 4-12 0 116.8 116.0

1 -4 2 221.5 224.5 3 2 2 75.8 74.6 -6 8 0 21.5 21.7

-2 4 2 76.3 75.8 1 -8 2 76.4 75.3 4 4 0 20.4 20.0

2 0 2 75.3 74.7 -5 6 1 104.3 104.4 2-12 0 21.9 21.9

0 -4 2 75.6 75.1 3 4 1 102.4 102.6 -6 6 1 79.4 81.2

-3 6 1 53.4 51.6 2-10 1 103.2 103.5 3 6 1 78.3 79.8

3 0 1 54.5 52.5 -5 4 1 128.7 129.3 3-12 1 77.5 79.0

H K L FO FC H K L FO FC H K L FO FC

-6 8 1 60.3 61.1 0-12 1 28.3 25.8 1 4 5 76.5 73.8

4 4 1 63.4 64.0 -7 8 1 84.6 85.9 2 -6 5 77.3 74.9

2-12 1 60.6 61.2 4 6 1 84.4 85.8 -7 10 2 53.3 56.3

-6 4 1 62.1 62.8 3-14 1 83.2 84.5 5 4 2 52.4 55.0

2 8 1 62.9 63.6 -7 10 0 152.5 150.9 2-14 2 57.7 61.3

4-12 1 65.9 66.6 5 4 0 150.9 149.1 -7 4 2 161.7 161.8

-6 10 0 88.2 88.5 2-14 0 154.3 152.7 2 10 2 163.4 163.8

5 2 0 83.0 83.3 -7 4 0 94.0 92.9 5-14 2 168.4 169.1

1-12 0 87.2 87.4 2 10 0 95.9 95.0 -5 8 4 99.9 100.2

-5 10 2 107.5 106.6 5-14 0 96.9 96.0 4 2 4 98.9 99.1

5 0 2 106.0 104.6 -4 8 4 25.9 27.4 1-10 4 101.3 101.6

0-10 2 107.0 106.1 4 0 4 29.0 30.9 -5 2 4 92.3 93.1

-3 4 4 59.1 58.9 0 -8 4 26.1 27.6 1 8 4 94.9 95.9

2 2 4 57.5 57.2 -7 10 1 66.2 66.1 4-10 4 96.1 97.3

1 -6 4 58.7 58.5 5 4 1 67.3 67.6 -8 8 0 148.1 146.8

-3 2 4 81.7 81.0 2-14 1 65.3 65.3 4 8 0 149.7 148.3

1 4 4 80.1 79.5 -6 6 3 30.3 29.1 4-16 0 158.6 157.6

2 -6 4 81.5 81.1 3 6 3 30.7 30.1 -8 6 0 74.5 71.9

-6 10 1 143.2 143.4 3-12 3 34.9 33.8 3 10 0 80.0 77.6

5 2 1 145.6 145.6 -2 2 5 23.0 26.6 5-16 0 75.2 72.1

1-12 1 145.7 145.9 1 2 5 23.4 26.9 -7 14 0 31.0 30.6

-6 2 1 57.8 60.1 1 -4 5 20.6 23.8 7 0 0 38.1 38.1

1 10 1 59.1 61.3 -6 4 3 97.5 96.6 0-14 0 32.4 32.2

5-12 1 59.1 61.3 2 8 3 93.6 93.2 -7 2 2 68.2 68.9

-5 6 3 101.8 102.3 4-12 3 90.5 90.1 1 12 2 67.6 68.0

3 4 3 105.6 105.6 -6 8 3 55.5 56.8 6-14 2 66.5 66.9

2-10 3 106.6 106.7 4 4 3 54.1 56.0 -5 10 4 36.9 36.4

-5 4 3 34.0 33.9 2-12 3 52.2 53.7 5 0 4 36.7 36.5

2 6 3 35.8 35.4 -2 4 5 38.8 40.9 0-10 4 37.9 37.3

3-10 3 37.2 37.0 2 0 5 37.0 39.3 -8 8 1 65.7 67.5

-6 6 2 98.5 99.6 0 -4 5 39.2 41.8 4 8 1 64.2 66.4

3 6 2 97.6 98.6 -6 12 2 101.5 101.0 4-16 1 67.1 69.1

3-12 2 100.7 102.3 6 0 2 95.9 94.9 -6 12 3 53.5 52.9

-3 6 4 148.7 147.9 0-12 2 98.7 98.3 6 0 3 55.0 54.9

3 0 4 146.4 145.6 -7 12 0 59.9 61.7 0-12 3 57.3 56.7

0 -6 4 147.5 147.0 6 2 0 59.1 60.5 -7 8 3 105.5 106.0

-6 8 2 101.4 102.0 1-14 0 59.4 61.3 4 6 3 108.2 108.2

4 4 2 98.3 98.8 -7 2 0 56.0 57.1 3-14 3 109.1 109.6

2-12 2 97.5 97.9 1 12 0 54.7 56.1 -4 2 5 54.6 53.7

-6 4 2 76.3 75.2 6-14 0 57.3 58.8 1 6 5 52.7 52.6

2 8 2 78.7 77.7 -7 6 2 119.9 120.8 3 -8 5 51.1 50.9

4-12 2 73.8 72.5 3 8 2 122.1 123.1 -6 6 4 49.5 50.2

-5 2 3 33.8 34.1 4-14 2 124.9 126.1 3 6 4 50.5 51.4

1 8 3 34.2 35.3 -5 4 4 74.5 74.1 3-12 4 54.1 55.3

4-10 3 36.0 37.0 2 6 4 78.8 78.2 -8 4 0 30.0 32.3

-6 12 0 44.6 47.9 3-10 4 75.8 75.3 2 12 0 35.1 37.9

6 0 0 38.8 40.7 -7 2 1 36.9 40.6 6-16 0 36.5 39.9

0-12 0 42.8 45.9 1 12 1 39.2 42.9 -6 4 4 98.1 96.2

-7 6 0 85.8 87.3 6-14 1 39.3 43.0 2 8 4 96.7 94.8

3 8 0 82.5 83.9 -6 10 3 118.5 118.4 4-12 4 96.8 95.2

4-14 0 82.1 83.5 5 2 3 117.2 117.7 -6 8 4 89.7 88.9

-7 8 0 30.8 29.4 1-12 3 116.5 116.5 4 4 4 89.3 88.3

4 6 0 29.8 28.5 -6 2 3 38.7 40.9 2-12 4 88.6 88.0

3-14 0 37.1 35.4 1 10 3 37.5 40.0 -7 10 3 77.0 75.4

-6 10 2 97.2 98.6 5-12 3 33.4 35.7 5 4 3 77.7 75.4

5 2 2 97.7 99.5 -3 4 5 115.7 113.7 2-14 3 75.3 73.8

1-12 2 94.5 95.9 2 2 5 117.5 115.4 -4 8 5 28.1 27.4

-6 12 1 29.1 26.4 1 -6 5 118.8 116.9 4 0 5 24.8 24.9

6 0 1 27.6 24.7 -3 2 5 73.7 71.6 0 -8 5 25.4 25.1

H K L FO FC H K L FO FC H K L FO FC

-7 14 2 73.3 74.9 4-18 1 38.5 38.1 1 6 6 86.7 88.6

7 0 2 66.5 67.8 -9 8 1 53.7 54.4 3 -8 6 86.5 88.4

0-14 2 70.9 72.7 4 10 1 51.8 52.5 -9 14 1 37.3 41.0

-8 10 2 34.0 35.2 5-18 1 51.1 51.7 7 4 1 34.9 38.8

5 6 2 35.9 36.9 -8 10 3 37.6 41.9 2-18 1 35.8 39.3

3-16 2 35.6 36.8 5 6 3 34.2 38.4 -9 4 1 31.8 36.3

-8 6 2 107.8 105.1 3-16 3 33.2 37.2 2 14 1 29.4 33.5

3 10 2 104.3 101.8 -7 14 3 37.6 38.5 7-18 1 28.6 32.9

5-16 2 105.0 102.9 7 0 3 45.2 46.2 -6 10 5 102.1 102.0

-6 2 4 24.3 22.8 0-14 3 44.6 45.8 5 2 5 106.1 105.5

1 10 4 25.5 24.0 -5 10 5 49.8 52.7 1-12 5 106.9 106.7

5-12 4 27.6 26.4 5 0 5 46.7 50.0 -6 2 5 34.2 37.6

-6 10 4 108.1 106.3 0-10 5 46.0 48.7 1 10 5 37.0 40.4

5 2 4 101.7 99.9 -8 14 2 82.2 82.9 5-12 5 38.9 42.2

1-12 4 106.9 105.2 7 2 2 76.4 76.6 -9 6 2 107.8 107.7

-1 2 6 38.8 40.0 1-16 2 82.9 83.8 3 12 2 110.5 110.6

1 0 6 37.0 38.6 -7 10 4 78.5 79.5 6-18 2 113.2 114.0

0 -2 6 40.8 42.4 5 4 4 75.7 76.3 -9 12 2 131.1 131.0

-7 2 3 30.9 30.6 2-14 4 78.5 79.7 6 6 2 130.0 129.7

1 12 3 31.3 31.7 -3 6 6 24.8 24.5 3-18 2 133.6 133.9

6-14 3 29.1 29.1 3 0 6 24.8 24.8 -8 16 2 104.8 106.8

-8 14 0 95.8 94.7 0 -6 6 23.2 22.8 8 0 2 106.3 107.9

7 2 0 92.3 90.4 -8 16 0 115.1 114.2 0-16 2 103.9 105.7

1-16 0 98.1 96.7 8 0 0 114.0 113.5 -8 2 3 51.3 54.2

-8 2 0 131.6 127.0 0-16 0 115.9 115.3 1 14 3 49.5 53.0

1 14 0 134.6 130.1 -9 12 1 123.9 124.2 7-16 3 54.8 58.3

7-16 0 136.0 131.8 6 6 1 121.3 121.2 -4 8 6 76.6 74.9

-5 4 5 100.3 99.3 3-18 1 119.5 119.7 4 0 6 76.4 74.6

2 6 5 98.2 97.9 -9 6 1 40.1 45.4 0 -8 6 77.4 75.6

3-10 5 97.6 97.2 3 12 1 38.1 43.1 -8 8 4 122.2 120.1

-5 6 5 58.8 58.6 6-18 1 36.5 41.2 4 8 4 121.4 119.2

3 4 5 55.8 56.0 -6 6 5 57.9 59.0 4-16 4 126.5 124.6

2-10 5 54.6 54.5 3 6 5 57.5 57.6 -9 16 0 36.6 37.3

-2 2 6 123.3 118.2 3-12 5 56.6 57.4 8 2 0 45.9 47.7

1 2 6 124.4 119.0 -6 8 5 29.6 31.1 1-18 0 38.5 39.7

1 -4 6 125.5 120.5 4 4 5 35.1 36.5 -9 2 0 28.8 31.3

-8 12 2 34.1 39.2 2-12 5 32.9 34.4 1 16 0 34.9 37.7

6 4 2 28.5 32.8 -6 4 5 45.6 43.9 8-18 0 31.4 34.4

2-16 2 34.1 39.0 2 8 5 47.5 45.4 -9 4 2 28.8 28.8

-8 14 1 26.8 29.2 4-12 5 52.0 50.0 2 14 2 34.7 34.9

7 2 1 27.5 30.1 -4 4 6 92.9 92.8 7-18 2 29.5 29.4

1-16 1 30.3 32.8 2 4 6 93.1 93.0 -8 6 4 52.2 51.5

-2 4 6 40.5 42.8 2 -8 6 95.3 95.0 3 10 4 56.7 56.0

2 0 6 40.2 42.5 -9 14 0 24.2 30.0 5-16 4 50.8 49.8

0 -4 6 40.7 43.1 7 4 0 28.5 34.5 -5 6 6 62.3 63.4

-6 12 4 33.2 37.2 2-18 0 28.5 35.1 3 4 6 60.9 61.8

6 0 4 28.8 31.9 -9 4 0 50.8 52.2 2-10 6 62.9 64.3

0-12 4 33.0 37.1 2 14 0 49.1 51.0 -10 10 0 69.5 72.1

-7 6 4 61.0 62.8 7-18 0 50.1 52.1 5 10 0 69.8 72.2

3 8 4 56.3 57.6 -7 12 4 44.2 44.5 5-20 0 73.4 77.0

4-14 4 57.0 58.4 6 2 4 47.9 48.3 -7 8 5 45.2 46.4

-7 8 4 34.9 38.4 1-14 4 47.8 48.2 4 6 5 42.3 44.1

4 6 4 33.3 36.7 -7 2 4 83.0 83.7 3-14 5 42.6 44.2

3-14 4 38.2 42.0 1 12 4 78.7 79.3 -10 8 0 34.9 40.7

-3 2 6 28.5 30.6 6-14 4 80.9 81.6 4 12 0 29.1 33.8

1 4 6 32.1 34.4 -4 6 6 28.2 30.0 6-20 0 37.4 43.3

2 -6 6 30.7 33.2 3 2 6 29.9 32.0 -8 4 4 51.0 52.3

-9 10 1 34.8 34.5 1 -8 6 29.3 31.2 2 12 4 58.1 59.7

5 8 1 37.1 36.4 -4 2 6 88.7 90.7 6-16 4 57.5 59.2

H K L FO FC H K L FO FC H K L FO FC

-10 10 1 60.5 64.2 0-16 4 71.6 72.9 4 10 5 41.1 42.8

5 10 1 60.8 64.4 -10 10 3 50.5 53.7 5-18 5 39.1 40.6

5-20 1 60.3 64.1 5 10 3 51.0 53.5 -9 12 5 94.6 91.9

-9 12 3 92.5 93.0 5-20 3 49.1 52.1 6 6 5 92.5 88.7

6 6 3 92.4 93.4 -10 4 2 93.8 89.5 3-18 5 88.4 85.6

3-18 3 95.9 96.4 2 16 2 98.2 94.3 -9 6 5 41.1 42.7

-7 10 5 40.4 39.5 8-20 2 102.6 98.7 3 12 5 40.7 41.2

5 4 5 41.2 40.9 -6 12 6 67.2 65.7 6-18 5 36.7 37.8

2-14 5 42.1 41.2 6 0 6 65.2 63.2 -11 6 2 38.1 36.1

-10 14 0 42.2 44.1 0-12 6 66.0 64.5 3 16 2 31.2 29.5

7 6 0 35.0 36.2 -11 10 0 60.8 63.8 8-22 2 35.1 33.7

3-20 0 42.6 44.3 5 12 0 66.4 69.7 -7 14 6 53.2 54.7

-10 6 0 41.7 38.1 6-22 0 67.0 71.0 7 0 6 47.6 48.6

3 14 0 32.1 29.1 -9 4 4 55.5 52.7 0-14 6 53.9 55.3

7-20 0 32.4 29.5 2 14 4 52.0 49.4 -8 6 6 82.9 82.2

-5 10 6 69.8 68.5 7-18 4 54.3 52.1 3 10 6 79.3 78.4

5 0 6 67.9 66.5 -7 6 6 82.2 79.8 5-16 6 81.5 80.9

0-10 6 66.5 65.1 3 8 6 86.5 84.6 -3 2 8 61.2 66.0

-9 4 3 38.4 40.8 4-14 6 86.8 84.9 1 4 8 60.8 65.9

2 14 3 40.0 42.5 -11 10 1 62.5 63.1 2 -6 8 61.2 66.0

7-18 3 44.9 47.5 5 12 1 65.3 66.0 -3 4 8 44.3 46.8

-10 10 2 80.0 80.3 6-22 1 65.8 66.3 2 2 8 41.5 42.9

5 10 2 77.1 77.3 -10 14 3 45.1 48.9 1 -6 8 42.8 44.7

5-20 2 84.0 84.8 7 6 3 48.6 52.2 -11 4 1 68.2 72.7

-8 14 4 48.8 50.5 3-20 3 50.3 54.2 2 18 1 67.6 71.5

7 2 4 46.6 47.9 -11 14 0 74.6 71.4 9-22 1 69.1 73.2

1-16 4 50.1 51.9 7 8 0 73.3 69.8 -10 18 3 61.3 61.9

-8 2 4 105.9 104.5 4-22 0 82.3 79.4 9 2 3 57.2 58.7

1 14 4 107.3 106.0 -11 8 0 100.9 96.3 1-20 3 58.4 59.7

7-16 4 108.4 107.4 4 14 0 103.3 99.5 -10 2 3 40.7 42.6

-3 4 7 74.4 71.5 7-22 0 110.2 106.3 1 18 3 40.0 42.6

2 2 7 72.9 70.8 -5 6 7 50.4 49.5 9-20 3 37.0 39.3

1 -6 7 73.3 71.0 3 4 7 52.1 50.7 -6 10 7 69.1 67.3

-3 2 7 68.6 67.3 2-10 7 51.4 50.2 5 2 7 66.3 64.8

1 4 7 67.8 66.1 -5 4 7 35.8 37.5 1-12 7 66.2 64.2

2 -6 7 65.4 64.0 2 6 7 35.7 36.5 -3 6 8 64.6 58.5

-6 6 6 56.7 55.1 3-10 7 36.5 37.9 3 0 8 63.5 58.0

3 6 6 56.7 55.6 -7 4 6 40.9 42.9 0 -6 8 63.9 58.4

3-12 6 59.4 58.3 2 10 6 42.1 44.0 -10 16 4 49.7 52.2

-9 18 1 49.0 51.3 5-14 6 44.9 47.2 8 4 4 46.4 48.1

9 0 1 47.6 49.6 -9 18 3 57.2 58.8 2-20 4 50.7 53.6

0-18 1 47.4 49.5 9 0 3 57.3 59.2 -12 14 1 48.1 43.1

-10 16 0 77.6 74.4 0-18 3 58.5 59.6 7 10 1 47.6 43.5

8 4 0 75.4 71.8 -11 6 0 45.2 45.4 5-24 1 44.6 40.0

2-20 0 80.1 77.0 3 16 0 51.4 51.7 -11 2 0 73.4 71.4

-10 4 0 44.9 47.0 8-22 0 45.5 44.9 1 20 0 80.4 79.5

2 16 0 46.5 49.0 -11 10 2 45.0 45.6 10-22 0 78.4 77.2

8-20 0 50.7 54.2 5 12 2 37.5 37.5 -7 8 7 51.8 54.0

-8 8 5 49.3 51.3 6-22 2 38.9 38.8 4 6 7 53.1 54.7

4 8 5 46.9 50.1 -10 4 3 33.0 31.9 3-14 7 54.2 55.9

4-16 5 51.7 54.1 2 16 3 33.9 33.6 -12 16 0 72.3 70.0

-9 18 2 78.9 75.9 8-20 3 35.7 34.9 8 8 0 80.3 77.8

9 0 2 73.9 70.6 -1 2 8 32.8 35.6 4-24 0 70.8 68.0

0-18 2 77.9 75.2 1 0 8 34.6 37.5 -11 20 1 58.5 61.8

-4 2 7 49.0 48.5 0 -2 8 32.3 35.3 10 2 1 59.4 62.4

1 6 7 49.4 48.9 -11 16 1 39.3 38.8 1-22 1 60.7 63.5

3 -8 7 50.5 50.1 8 6 1 42.8 42.3 -10 10 5 48.9 48.1

-8 16 4 70.2 71.6 3-22 1 42.9 42.1 5 10 5 48.9 49.1

8 0 4 69.1 70.7 -9 8 5 45.0 46.2 5-20 5 50.3 49.8

H K L FO FC H K L FO FC H K L FO FC

-12 8 1 45.2 42.3 6-18 6 79.0 78.6 8 10 0 55.4 58.0

4 16 1 45.3 42.5 -9 12 6 80.7 79.7 5-26 0 60.5 64.8

8-24 1 42.8 40.2 6 6 6 82.9 81.7 -11 10 5 49.8 51.7

-7 10 7 40.6 41.4 3-18 6 86.5 85.5 5 12 5 54.6 56.0

5 4 7 42.9 42.4 -12 16 2 57.4 64.6 6-22 5 54.1 55.4

2-14 7 39.8 40.2 8 8 2 47.5 52.8 -3 4 9 63.5 63.3

-12 12 2 51.5 55.4 4-24 2 57.0 64.3 2 2 9 63.9 64.0

6 12 2 52.1 56.0 -12 8 2 47.2 45.7 1 -6 9 63.5 63.7

6-24 2 58.2 63.9 4 16 2 57.3 55.3 -12 22 0 44.4 51.1

-11 10 4 55.9 55.4 8-24 2 54.4 53.2 11 2 0 54.3 63.8

5 12 4 64.1 63.9 -5 2 8 48.6 44.2 1-24 0 44.0 50.3

6-22 4 63.9 64.1 1 8 8 50.2 45.7 -11 2 4 55.1 54.3

-5 4 8 41.6 42.5 4-10 8 53.0 48.4 1 20 4 60.8 60.6

2 6 8 48.5 50.2 -8 16 6 100.4 96.0 10-22 4 60.9 60.8

3-10 8 45.0 46.3 8 0 6 103.3 98.6 -9 12 7 68.7 68.4

-11 4 3 58.9 57.7 0-16 6 99.6 95.5 6 6 7 66.2 67.2

2 18 3 56.8 55.7 -12 18 2 53.4 55.5 3-18 7 68.5 68.4

9-22 3 56.9 55.9 9 6 2 51.2 52.6 -7 2 8 63.2 65.5

-12 6 0 55.6 52.5 3-24 2 57.0 59.9 1 12 8 57.3 58.7

3 18 0 59.4 56.5 -11 20 3 70.3 69.5 6-14 8 60.2 62.1

9-24 0 63.8 61.5 10 2 3 66.7 65.3 -11 4 5 57.7 57.4

-11 20 2 58.1 62.0 1-22 3 65.9 65.4 2 18 5 58.2 57.0

10 2 2 51.3 53.7 -6 8 8 78.3 76.7 9-22 5 60.1 58.7

1-22 2 57.3 61.4 4 4 8 79.9 78.7 -12 24 0 70.9 77.1

-11 14 4 57.2 59.6 2-12 8 77.3 76.4 12 0 0 65.1 70.2

7 8 4 54.8 57.0 -6 4 8 68.2 68.7 0-24 0 70.3 76.5

4-22 4 61.1 64.2 2 8 8 67.3 67.2 -8 8 8 62.5 66.1

-11 8 4 79.1 80.4 4-12 8 66.3 66.8 4 8 8 61.0 64.4

4 14 4 80.3 81.7 -6 10 8 78.4 80.3 4-16 8 64.9 68.8

7-22 4 84.3 86.2 5 2 8 71.4 72.4 -14 10 1 54.0 61.4

-9 6 6 74.2 73.2 1-12 8 76.0 77.8 5 18 1 54.9 62.2

3 12 6 75.3 74.7 -13 16 0 56.4 59.6 9-28 1 55.3 62.6

 

 

 

 

 

 

 

 

 

Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:

Uptake, Site Preference and

Degradation of Monoclinic Structure

Michael E. Fleet, Xioayang Liu

and Yuanming Pan

 

 

Deposited Material

 

 

Table 5. List of observed and calculated structure factors

 

 

(f) P21/b structure of Dy-hydroxylapatite

H K L FO FC H K L FO FC H K L FO FC

0 0 2 281.0 284.8 2 2 1 207.2 208.8 -4 4 2 204.3 205.3

0 0 4 390.1 409.0 1 -6 1 197.1 198.7 2 4 2 196.3 197.7

0 0 6 204.0 204.9 -3 2 1 136.3 137.0 2 -8 2 209.0 210.7

0 0 8 175.5 177.5 1 4 1 131.9 132.8 -4 6 2 77.5 77.9

0 0 10 83.1 84.1 2 -6 1 141.7 142.1 3 2 2 84.1 84.2

0 0 12 121.5 115.2 -2 2 2 171.7 173.8 1 -8 2 106.5 105.6

0 -1 2 17.0 14.5 1 2 2 173.9 175.5 -4 2 2 109.7 107.1

-1 1 4 17.5 12.2 1 -4 2 174.9 176.6 1 6 2 114.1 111.2

1 1 3 19.1 23.6 -3 6 0 264.2 272.3 3 -8 2 107.7 105.8

0 -3 3 22.6 20.4 3 0 0 268.8 275.9 -5 6 0 14.5 14.1

-2 3 4 20.4 23.7 0 -6 0 280.5 288.1 3 4 0 25.8 24.6

-2 3 2 18.3 22.8 -2 4 2 120.9 117.6 2-10 0 0.8 1.5

1 3 3 17.9 2.0 2 0 2 122.2 119.3 -5 4 0 116.4 115.9

1 -5 2 20.2 22.3 0 -4 2 112.7 110.8 2 6 0 114.1 114.0

2 1 4 17.6 20.8 -3 6 1 68.2 66.2 3-10 0 102.2 104.1

2 1 2 26.8 26.3 3 0 1 51.2 50.5 -3 4 3 193.2 190.7

0 -5 2 19.1 24.9 0 -6 1 48.0 46.9 2 2 3 201.4 197.6

-3 1 2 13.6 15.2 -4 4 0 20.7 26.5 1 -6 3 200.5 196.3

-3 3 3 25.5 30.5 2 4 0 12.7 16.7 -3 2 3 134.7 132.9

-3 5 4 14.9 15.4 2 -8 0 5.2 6.5 1 4 3 137.9 134.9

-3 5 1 16.9 23.4 -3 4 2 61.6 59.2 2 -6 3 127.0 125.4

3 -7 6 27.7 24.6 2 2 2 62.7 59.7 -5 6 1 134.0 133.9

3 1 4 20.0 23.1 1 -6 2 50.2 48.0 3 4 1 130.9 130.9

4 -9 4 27.7 27.7 -3 2 2 44.7 40.3 2-10 1 111.7 112.4

2 5 1 30.5 35.8 1 4 2 42.0 38.1 -5 4 1 120.0 119.7

3 3 3 26.4 23.1 2 -6 2 38.0 34.6 2 6 1 115.6 115.6

0 -9 4 22.3 15.3 -4 6 0 69.9 73.7 3-10 1 129.9 129.3

0 -9 1 28.2 31.5 3 2 0 93.3 96.2 -5 8 0 146.4 150.9

-5 5 1 27.6 33.8 1 -8 0 92.8 94.8 4 2 0 132.2 136.0

-5 7 2 25.7 25.7 -4 2 0 184.2 178.2 1-10 0 131.6 136.4

5 1 1 27.2 35.8 1 6 0 180.8 175.1 -5 2 0 156.6 159.3

-1 2 0 35.6 37.3 3 -8 0 195.2 187.3 1 8 0 146.4 148.3

1 0 0 36.5 37.9 -4 4 1 40.9 43.2 4-10 0 148.3 152.1

0 -2 0 31.8 33.7 2 4 1 36.8 38.1 -4 8 2 157.1 158.0

-1 2 1 28.6 28.0 2 -8 1 36.1 37.7 4 0 2 153.5 153.8

1 0 1 20.3 20.5 -1 2 3 16.1 15.0 0 -8 2 150.9 152.0

0 -2 1 22.0 22.0 1 0 3 19.1 17.5 -3 6 3 44.2 44.2

-2 2 0 38.4 38.1 0 -2 3 23.9 21.1 3 0 3 50.3 49.4

1 2 0 29.2 29.8 -4 6 1 47.6 44.8 0 -6 3 39.0 38.7

1 -4 0 21.6 22.2 3 2 1 30.4 29.5 -5 8 1 28.7 28.8

-2 4 0 72.3 67.9 1 -8 1 41.2 39.1 4 2 1 32.8 32.9

2 0 0 51.7 50.3 -4 2 1 73.8 75.6 1-10 1 24.8 25.5

0 -4 0 65.9 62.5 1 6 1 72.2 74.8 -5 2 1 18.3 18.3

-2 2 1 27.4 30.1 3 -8 1 52.5 54.9 1 8 1 23.7 24.0

1 2 1 29.9 32.4 -3 6 2 40.0 36.9 4-10 1 15.1 15.6

1 -4 1 29.9 32.7 3 0 2 34.1 31.4 1 -2 4 47.7 45.4

-2 4 1 34.9 35.4 0 -6 2 24.1 22.6 -1 0 4 42.2 40.7

2 0 1 22.5 22.9 -2 2 3 81.8 77.2 0 2 4 43.7 42.0

0 -4 1 17.8 19.0 1 2 3 89.1 83.6 -5 4 2 20.2 21.2

-1 2 2 73.0 70.5 1 -4 3 85.7 80.4 2 6 2 11.1 12.1

1 0 2 64.6 62.5 -4 8 0 51.1 50.6 3-10 2 10.0 12.2

0 -2 2 63.1 61.8 4 0 0 61.1 60.4 -5 6 2 107.9 112.2

-3 2 0 28.6 28.7 0 -8 0 78.5 75.1 3 4 2 101.1 104.4

1 4 0 27.2 26.8 -2 4 3 68.4 63.8 2-10 2 105.5 110.2

2 -6 0 41.4 40.4 2 0 3 78.1 73.0 -5 10 0 14.4 14.1

-3 4 0 121.2 122.6 0 -4 3 72.1 67.9 5 0 0 37.8 37.2

2 2 0 117.8 118.6 -4 8 1 16.6 20.2 0-10 0 22.4 21.5

1 -6 0 120.8 121.7 4 0 1 18.3 21.3 -2 2 4 16.7 15.0

-3 4 1 205.1 206.6 0 -8 1 5.1 6.0 1 2 4 15.4 13.6

H K L FO FC H K L FO FC H K L FO FC

1 -4 4 10.3 10.1 1 10 1 51.9 53.2 -7 4 0 58.8 62.1

-4 6 3 69.5 68.6 5-12 1 70.2 70.9 2 10 0 64.3 67.6

3 2 3 72.7 72.9 -6 6 2 65.7 67.9 5-14 0 58.4 62.8

1 -8 3 62.0 62.0 3 6 2 63.8 64.9 2 -4 5 29.7 30.0

-4 2 3 55.5 55.6 3-12 2 64.4 66.1 -2 0 5 22.3 22.8

1 6 3 68.7 68.4 -6 8 2 47.8 47.4 0 4 5 27.3 27.9

3 -8 3 61.8 62.1 4 4 2 56.4 56.2 -6 6 3 40.1 38.5

-5 10 1 67.0 66.2 2-12 2 45.5 45.2 3 6 3 42.5 40.4

5 0 1 63.0 62.5 -6 4 2 40.2 39.7 3-12 3 29.1 27.8

0-10 1 47.1 47.1 2 8 2 37.8 38.0 -7 10 1 68.7 69.1

-2 4 4 27.7 28.1 4-12 2 63.5 62.8 5 4 1 77.4 76.9

2 0 4 23.0 22.8 -5 8 3 46.5 47.6 2-14 1 92.6 93.0

0 -4 4 23.5 23.9 4 2 3 37.0 38.9 -7 4 1 50.9 49.9

-5 8 2 38.1 39.7 1-10 3 48.1 48.7 2 10 1 63.0 61.4

4 2 2 49.6 49.7 -5 2 3 52.3 51.5 5-14 1 55.2 53.6

1-10 2 44.6 45.5 1 8 3 50.7 49.9 -6 4 3 111.7 114.0

-6 6 0 42.6 43.0 4-10 3 46.5 46.3 2 8 3 130.3 130.8

3 6 0 63.1 61.2 -4 6 4 27.0 28.0 4-12 3 106.1 107.8

3-12 0 74.0 74.4 3 2 4 33.6 34.7 -6 8 3 38.2 40.7

-6 8 0 26.8 27.0 1 -8 4 34.0 34.6 4 4 3 31.9 33.7

4 4 0 31.7 32.3 -4 2 4 16.8 19.9 2-12 3 30.0 32.3

2-12 0 44.2 46.6 1 6 4 12.0 14.4 -5 4 4 68.1 67.7

-6 4 0 153.2 155.5 3 -8 4 17.7 21.3 2 6 4 71.8 71.4

2 8 0 145.8 147.7 -6 12 0 41.0 44.5 3-10 4 77.4 77.3

4-12 0 148.7 150.6 6 0 0 29.7 31.2 -6 12 2 75.6 75.7

-6 6 1 98.9 101.6 0-12 0 33.6 36.6 6 0 2 68.8 67.7

3 6 1 97.5 100.2 1 -2 5 11.4 12.2 0-12 2 58.8 58.5

3-12 1 87.3 89.8 -1 0 5 14.4 15.0 -3 4 5 127.3 124.3

-6 8 1 27.0 29.5 0 2 5 13.8 13.8 2 2 5 128.2 125.1

4 4 1 42.3 44.8 -6 10 2 57.1 56.7 1 -6 5 123.1 119.9

2-12 1 52.4 54.6 5 2 2 62.1 62.8 3 -2 5 82.9 80.9

-6 4 1 81.6 83.7 1-12 2 77.5 77.5 -1 -4 5 82.8 81.7

2 8 1 82.8 85.3 -6 2 2 52.4 52.7 -2 6 5 90.4 88.2

4-12 1 71.6 73.7 1 10 2 44.9 45.7 -7 6 2 95.5 96.8

-3 2 4 88.9 85.7 5-12 2 66.3 66.8 3 8 2 94.3 95.8

1 4 4 81.7 79.6 -7 8 0 53.9 57.3 4-14 2 110.2 110.8

2 -6 4 93.5 90.3 4 6 0 37.8 39.7 -7 8 2 10.2 11.0

-3 4 4 69.3 68.3 3-14 0 29.1 31.1 4 6 2 26.0 27.1

2 2 4 75.8 74.0 -7 6 0 23.2 23.2 3-14 2 32.5 34.0

1 -6 4 66.1 64.9 3 8 0 19.7 19.9 -7 12 0 81.9 83.7

-5 10 2 154.0 156.1 4-14 0 0.4 1.1 6 2 0 100.0 101.4

5 0 2 154.1 156.1 -5 10 3 8.1 10.5 1-14 0 105.1 106.5

0-10 2 150.7 152.5 5 0 3 26.8 29.6 -7 2 0 81.9 83.6

-6 10 0 86.0 88.6 0-10 3 31.5 34.8 1 12 0 83.7 85.7

5 2 0 88.2 88.8 -2 2 5 19.5 22.2 6-14 0 80.5 84.0

1-12 0 105.4 106.3 1 2 5 22.6 25.1 -5 8 4 99.6 97.1

-3 6 4 155.0 153.3 1 -4 5 27.4 30.0 4 2 4 93.4 90.2

3 0 4 144.9 143.4 -7 8 1 114.0 116.4 1-10 4 93.5 90.9

0 -6 4 158.2 156.5 4 6 1 116.1 118.1 -5 2 4 127.1 126.1

-5 6 3 137.0 136.0 3-14 1 117.0 118.7 1 8 4 115.0 113.7

3 4 3 135.6 134.9 -7 6 1 22.5 22.6 4-10 4 118.7 118.2

2-10 3 127.8 126.7 3 8 1 20.6 20.9 -6 10 3 138.3 137.8

-5 4 3 45.3 44.6 4-14 1 27.2 27.1 5 2 3 132.1 131.8

2 6 3 44.7 43.6 -4 8 4 36.3 35.4 1-12 3 128.4 128.7

3-10 3 52.6 52.4 4 0 4 41.8 41.1 -6 2 3 22.3 21.4

-6 10 1 145.0 145.1 0 -8 4 38.4 37.9 1 10 3 32.0 31.2

5 2 1 147.4 146.7 -7 10 0 128.2 131.0 5-12 3 27.2 26.8

1-12 1 143.2 143.3 5 4 0 136.8 138.7 -3 6 5 23.3 27.5

-6 2 1 50.4 51.4 2-14 0 123.8 125.8 3 0 5 12.3 15.6

H K L FO FC H K L FO FC H K L FO FC

0 -6 5 15.6 18.5 1 0 6 32.2 32.0 -7 8 4 52.6 51.6

-7 12 1 45.6 46.8 0 -2 6 39.6 39.5 4 6 4 47.9 46.9

6 2 1 36.9 37.9 -7 10 3 81.0 80.5 3-14 4 31.5 32.3

1-14 1 31.3 31.8 5 4 3 71.3 71.6 -7 6 4 20.2 19.2

-7 2 1 40.8 41.2 2-14 3 93.1 91.9 3 8 4 20.8 20.1

1 12 1 46.7 47.0 -7 4 3 59.8 59.0 4-14 4 11.4 11.4

6-14 1 50.6 50.8 2 10 3 64.4 63.8 -5 10 5 45.0 45.4

-7 10 2 57.0 60.3 5-14 3 39.0 39.4 5 0 5 46.3 46.8

5 4 2 44.4 46.7 -8 4 0 49.2 50.0 0-10 5 37.1 38.8

2-14 2 70.2 73.8 2 12 0 40.5 40.9 -9 8 0 25.9 29.4

-7 4 2 158.0 159.5 6-16 0 52.7 55.8 4 10 0 30.5 34.6

2 10 2 143.0 144.7 -6 10 4 110.4 111.0 5-18 0 14.5 18.9

5-14 2 150.9 153.6 5 2 4 106.2 106.0 -7 10 4 62.7 64.2

-4 4 5 39.7 39.3 1-12 4 113.3 113.0 5 4 4 71.6 72.3

2 4 5 33.4 33.2 -6 2 4 20.3 20.3 2-14 4 48.8 50.1

2 -8 5 33.7 33.9 1 10 4 9.4 9.5 -7 14 3 56.2 56.5

-5 10 4 50.7 50.1 5-12 4 16.8 17.5 7 0 3 34.8 36.9

5 0 4 52.3 52.0 -2 2 6 155.2 151.3 0-14 3 37.5 38.3

0-10 4 47.4 46.6 1 2 6 148.4 144.8 -8 10 3 20.5 21.7

-8 8 0 155.6 157.8 1 -4 6 146.9 143.8 5 6 3 26.7 27.7

4 8 0 133.8 134.8 -8 8 2 49.7 48.2 3-16 3 29.2 30.0

4-16 0 133.9 137.3 4 8 2 43.7 43.6 -6 6 5 79.9 77.3

-4 6 5 31.8 33.5 4-16 2 51.7 49.7 3 6 5 73.5 72.4

3 2 5 17.2 20.3 -5 6 5 79.5 78.3 3-12 5 76.7 75.2

1 -8 5 14.6 17.9 3 4 5 81.8 80.3 -9 10 1 56.2 55.9

-4 2 5 49.1 48.5 2-10 5 72.6 71.9 5 8 1 56.1 55.7

1 6 5 52.8 51.8 -5 4 5 90.8 90.3 4-18 1 68.8 68.2

3 -8 5 41.4 40.5 2 6 5 93.0 92.3 -9 8 1 65.1 66.2

-7 2 2 51.4 52.4 3-10 5 106.7 105.2 4 10 1 56.5 57.4

1 12 2 46.2 47.3 -2 4 6 17.0 17.9 5-18 1 44.6 45.4

6-14 2 59.6 59.7 2 0 6 20.5 22.5 -4 4 6 113.4 111.3

-8 10 0 35.2 37.8 0 -4 6 16.8 18.8 2 4 6 121.8 119.3

5 6 0 54.9 57.9 -7 14 2 69.1 70.5 2 -8 6 127.8 125.1

3-16 0 32.8 35.4 7 0 2 80.5 80.9 -8 14 2 76.0 78.8

-8 6 0 68.8 68.0 0-14 2 85.4 85.5 7 2 2 82.1 82.1

3 10 0 59.1 58.8 -8 10 2 109.7 111.2 1-16 2 80.1 81.3

5-16 0 86.5 84.9 5 6 2 121.0 121.9 -8 2 2 52.1 51.8

-8 8 1 66.1 68.0 3-16 2 111.0 112.6 1 14 2 39.7 40.2

4 8 1 54.2 56.3 -8 6 2 126.8 126.6 7-16 2 48.5 47.2

4-16 1 65.7 67.4 3 10 2 134.2 132.9 -9 6 0 33.6 36.4

-6 6 4 52.8 51.9 5-16 2 126.8 126.6 3 12 0 32.3 35.0

3 6 4 49.2 48.5 -7 2 3 44.9 45.8 6-18 0 9.8 9.5

3-12 4 71.4 70.1 1 12 3 38.7 39.2 -6 8 5 10.2 12.5

-7 8 3 128.4 129.5 6-14 3 38.1 38.6 4 4 5 21.9 26.6

4 6 3 132.0 133.6 -8 14 0 47.4 47.8 2-12 5 28.2 33.1

3-14 3 123.3 125.0 7 2 0 37.5 35.8 -6 4 5 59.7 59.7

-8 10 1 19.0 22.2 1-16 0 44.0 42.8 2 8 5 63.9 64.4

5 6 1 10.5 12.5 -8 2 0 152.0 153.1 4-12 5 48.5 48.7

3-16 1 21.0 25.3 1 14 0 151.1 151.9 -4 2 6 98.8 96.9

-6 4 4 106.2 106.2 7-16 0 134.2 137.1 1 6 6 102.7 100.5

2 8 4 106.6 106.4 -3 2 6 19.3 19.9 3 -8 6 101.4 99.3

4-12 4 113.3 113.2 1 4 6 21.5 21.4 -8 16 0 116.2 114.2

-6 8 4 79.9 80.5 2 -6 6 21.4 21.4 8 0 0 116.2 114.5

4 4 4 88.1 88.3 -8 12 2 80.9 84.3 0-16 0 108.0 106.7

2-12 4 88.9 89.5 6 4 2 66.3 69.1 -9 12 1 98.7 96.9

-4 8 5 20.2 20.5 2-16 2 53.8 57.2 6 6 1 109.5 107.7

4 0 5 24.5 24.3 -6 12 4 46.6 45.5 3-18 1 108.8 106.3

0 -8 5 22.6 22.5 6 0 4 37.0 35.8 -9 6 1 54.5 55.6

-1 2 6 42.5 41.7 0-12 4 50.8 48.4 3 12 1 62.7 63.6

H K L FO FC H K L FO FC H K L FO FC

6-18 1 62.0 62.3 4 2 6 50.6 48.3 -6 6 6 84.1 81.9

-8 12 3 22.5 22.7 1-10 6 47.8 46.9 3 6 6 72.7 70.1

6 4 3 27.8 27.5 -5 2 6 25.4 25.2 3-12 6 73.1 71.6

2-16 3 26.1 25.2 1 8 6 25.7 25.4 -7 12 5 41.7 43.3

-7 12 4 72.9 73.0 4-10 6 20.1 20.8 6 2 5 28.9 30.2

6 2 4 68.1 67.6 -7 6 5 20.7 19.6 1-14 5 21.8 22.8

1-14 4 82.3 82.1 3 8 5 18.5 18.2 -7 2 5 21.8 23.1

-7 2 4 98.8 98.0 4-14 5 21.6 20.6 1 12 5 28.9 31.0

1 12 4 104.8 103.6 -7 8 5 71.6 72.7 6-14 5 28.7 30.8

6-14 4 90.0 89.7 4 6 5 70.6 71.2 -6 4 6 49.8 51.2

-6 10 5 113.8 110.6 3-14 5 79.8 80.6 2 8 6 40.9 41.8

5 2 5 112.1 110.0 -9 16 0 28.1 25.5 4-12 6 58.3 58.8

1-12 5 113.8 111.1 8 2 0 18.8 20.1 -9 2 2 74.9 73.5

-6 2 5 39.7 39.8 1-18 0 12.9 14.8 1 16 2 68.1 67.0

1 10 5 46.0 46.6 -9 10 3 48.6 49.3 8-18 2 87.7 86.6

5-12 5 53.2 53.4 5 8 3 51.2 51.2 -10 14 0 80.5 80.1

-4 8 6 78.7 75.9 4-18 3 40.1 40.5 7 6 0 81.1 79.8

4 0 6 84.7 81.7 -9 8 3 47.2 47.7 3-20 0 72.4 71.7

0 -8 6 88.8 85.8 4 10 3 45.1 46.1 -10 6 0 12.1 12.6

-9 10 2 43.4 47.6 5-18 3 39.6 40.0 3 14 0 14.9 15.8

5 8 2 33.4 35.3 -7 10 5 53.3 52.2 7-20 0 29.5 31.5

4-18 2 14.2 15.2 5 4 5 53.8 52.0 -8 14 4 32.1 33.2

-9 8 2 35.0 35.9 2-14 5 63.5 62.7 7 2 4 24.9 25.0

4 10 2 24.5 25.2 -7 4 5 39.0 38.1 1-16 4 33.7 34.3

5-18 2 49.9 51.4 2 10 5 47.2 46.6 -8 2 4 133.2 133.0

-9 14 0 71.5 72.7 5-14 5 45.8 45.3 1 14 4 124.6 124.5

7 4 0 70.4 71.6 -9 16 1 22.8 22.3 7-16 4 126.4 127.5

2-18 0 74.1 75.4 8 2 1 18.5 18.3 -9 14 3 44.1 43.2

-9 4 0 47.2 47.7 1-18 1 33.4 32.3 7 4 3 45.2 44.6

2 14 0 55.1 55.9 -8 4 4 69.9 68.0 2-18 3 42.4 41.1

7-18 0 58.6 59.9 2 12 4 68.2 66.3 -9 4 3 30.1 31.7

-9 14 1 62.1 62.3 6-16 4 84.4 82.8 2 14 3 9.9 11.0

7 4 1 54.5 54.5 -10 10 0 70.4 76.0 7-18 3 29.3 31.7

2-18 1 54.3 53.9 5 10 0 74.5 78.5 -10 14 1 56.5 57.7

-9 12 2 96.0 98.4 5-20 0 55.9 60.1 7 6 1 47.3 48.1

6 6 2 99.7 101.1 -5 10 6 66.1 65.2 3-20 1 65.0 66.7

3-18 2 86.8 89.6 5 0 6 80.4 80.0 -10 6 1 43.3 45.2

-9 6 2 96.9 99.1 0-10 6 71.6 70.6 3 14 1 42.7 44.8

3 12 2 106.4 108.0 -9 12 3 67.3 67.5 7-20 1 29.7 30.6

6-18 2 111.2 114.5 6 6 3 69.3 68.1 -10 10 2 62.6 62.3

-5 6 6 47.9 49.3 3-18 3 71.5 71.0 5 10 2 56.7 55.4

3 4 6 36.5 37.1 -9 6 3 17.4 16.7 5-20 2 74.1 73.9

2-10 6 44.0 45.2 3 12 3 24.4 22.9 -4 4 7 20.3 22.8

-8 16 2 144.9 144.4 6-18 3 20.5 20.2 2 4 7 21.1 24.7

8 0 2 140.2 139.5 -3 4 7 93.5 94.6 2 -8 7 11.1 12.2

0-16 2 153.1 152.9 2 2 7 92.3 92.6 -9 18 0 57.6 59.7

-8 2 3 33.0 35.1 1 -6 7 87.7 88.1 9 0 0 53.0 53.1

1 14 3 48.3 49.0 -3 2 7 77.1 76.5 0-18 0 50.3 50.6

7-16 3 15.4 18.2 1 4 7 74.7 73.2 -6 10 6 15.7 16.1

-8 8 4 139.2 139.3 2 -6 7 67.0 66.1 5 2 6 23.2 25.4

4 8 4 135.2 134.1 -10 8 0 65.8 68.0 1-12 6 36.0 40.3

4-16 4 134.8 135.2 4 12 0 62.9 64.7 -6 2 6 31.4 30.8

-8 10 4 36.2 39.1 6-20 0 48.9 51.1 1 10 6 21.7 21.6

5 6 4 47.8 51.3 -10 10 1 41.8 42.2 5-12 6 31.5 30.9

3-16 4 24.2 25.8 5 10 1 60.4 60.0 -4 2 7 44.6 43.8

-8 6 4 49.7 48.8 5-20 1 61.5 61.2 1 6 7 38.5 38.1

3 10 4 53.7 53.5 -10 8 1 58.6 57.9 3 -8 7 42.4 42.6

5-16 4 60.7 59.5 4 12 1 58.9 58.0 -9 18 1 48.5 48.7

-5 8 6 45.4 44.1 6-20 1 57.2 56.0 9 0 1 40.4 41.3

H K L FO FC H K L FO FC H K L FO FC

0-18 1 43.4 43.5 1 8 7 23.4 22.0 -10 4 3 32.6 35.5

-8 8 5 57.8 58.1 4-10 7 19.0 17.6 2 16 3 23.6 26.5

4 8 5 49.0 49.0 -1 2 8 22.6 22.4 8-20 3 51.1 54.6

4-16 5 46.7 47.0 1 0 8 24.4 24.1 -6 8 7 18.6 19.1

-9 8 4 19.7 20.3 0 -2 8 28.3 26.8 4 4 7 24.0 23.4

4 10 4 24.2 24.3 -10 18 0 28.3 31.8 2-12 7 17.9 17.7

5-18 4 9.4 9.8 9 2 0 39.5 42.2 -6 4 7 58.3 58.2

-10 16 0 61.8 62.8 1-20 0 43.0 47.3 2 8 7 58.7 57.6

8 4 0 68.2 68.6 -11 10 0 62.5 64.9 4-12 7 46.0 45.5

2-20 0 68.8 70.5 5 12 0 47.6 48.7 -3 2 8 61.7 60.0

-10 4 0 25.6 28.1 6-22 0 89.0 92.4 1 4 8 59.7 58.8

2 16 0 19.1 21.7 -10 2 0 55.1 55.3 2 -6 8 62.6 60.9

8-20 0 28.3 31.7 1 18 0 74.0 73.3 -3 4 8 50.8 51.1

-10 16 1 39.5 39.8 9-20 0 47.1 48.4 2 2 8 47.0 47.4

8 4 1 35.6 36.2 -10 14 3 84.0 83.6 1 -6 8 41.1 40.9

2-20 1 19.0 20.2 7 6 3 68.9 68.7 -11 6 0 27.9 29.7

-10 4 1 41.3 41.2 3-20 3 76.7 75.5 3 16 0 39.3 40.7

2 16 1 28.0 28.8 -10 6 3 25.1 26.3 8-22 0 45.0 45.0

8-20 1 40.1 39.9 3 14 3 15.6 15.0 -10 10 4 34.0 36.7

-8 16 4 89.1 86.5 7-20 3 18.1 18.6 5 10 4 33.1 34.2

8 0 4 86.3 84.8 -10 18 1 41.2 38.0 5-20 4 24.6 27.3

0-16 4 87.1 85.6 9 2 1 48.3 44.9 -9 12 5 79.3 77.0

-6 12 6 80.3 78.1 1-20 1 47.3 44.4 6 6 5 85.0 83.9

6 0 6 80.4 77.5 -11 12 1 57.1 56.3 3-18 5 89.7 87.4

0-12 6 79.6 76.6 6 10 1 55.6 55.0 -9 6 5 51.7 50.8

-9 18 2 52.4 55.8 5-22 1 64.9 64.6 3 12 5 55.4 55.4

9 0 2 39.1 40.0 -11 10 1 73.9 76.6 6-18 5 64.2 62.7

0-18 2 35.6 37.2 5 12 1 65.5 67.8 -11 16 1 36.2 35.4

-7 6 6 50.3 48.8 6-22 1 60.6 63.2 8 6 1 23.7 24.6

3 8 6 46.4 44.3 -11 14 0 61.8 63.3 3-22 1 41.8 41.7

4-14 6 49.7 48.4 7 8 0 49.8 48.6 -10 12 4 20.3 21.0

-10 10 3 46.7 46.6 4-22 0 64.6 66.1 6 8 4 18.2 17.5

5 10 3 45.8 45.4 -11 8 0 94.2 94.7 4-20 4 33.7 33.0

5-20 3 47.6 47.4 4 14 0 90.4 89.5 -10 8 4 47.2 48.6

-5 6 7 66.4 68.3 7-22 0 90.9 93.5 4 12 4 57.5 59.1

3 4 7 65.2 66.7 -7 12 6 20.1 20.3 6-20 4 33.0 33.7

2-10 7 58.8 59.9 6 2 6 31.4 33.4 -3 6 8 85.3 79.9

-5 4 7 51.2 52.4 1-14 6 21.1 22.1 3 0 8 84.5 79.0

2 6 7 44.5 45.1 -7 2 6 21.2 22.8 0 -6 8 91.6 85.6

3-10 7 53.1 54.4 1 12 6 15.5 15.7 -8 10 6 56.6 55.5

-10 8 3 48.0 46.9 6-14 6 25.6 28.7 5 6 6 73.9 72.1

4 12 3 46.6 46.2 -9 18 3 48.9 49.4 3-16 6 71.9 71.0

6-20 3 36.8 35.8 9 0 3 48.3 47.5 -8 6 6 85.5 84.9

-9 14 4 58.2 59.1 0-18 3 41.4 41.0 3 10 6 80.8 79.3

7 4 4 72.2 73.2 -11 14 1 36.0 37.6 5-16 6 89.1 89.0

2-18 4 61.2 62.3 7 8 1 46.8 48.7 -7 14 6 28.1 29.4

-9 4 4 41.4 38.8 4-22 1 41.8 43.2 7 0 6 28.1 28.1

2 14 4 47.8 45.6 -6 6 7 46.4 47.4 0-14 6 35.9 37.0

7-18 4 48.0 46.5 3 6 7 47.2 47.1 -6 10 7 91.2 91.9

-7 4 6 75.6 71.7 3-12 7 44.7 45.6 5 2 7 86.3 86.4

2 10 6 72.1 68.7 -9 8 5 52.6 52.5 1-12 7 72.6 72.1

5-14 6 76.8 73.8 4 10 5 46.2 45.8 -6 2 7 30.8 30.5

-10 16 2 32.3 35.2 5-18 5 40.0 40.2 1 10 7 38.6 37.8

8 4 2 18.3 19.2 -9 10 5 45.2 44.2 5-12 7 39.5 39.4

2-20 2 24.1 26.2 5 8 5 46.4 46.6 -10 20 0 44.5 46.9

-10 4 2 84.9 85.3 4-18 5 56.9 57.0 10 0 0 42.7 45.5

2 16 2 85.7 86.2 -10 16 3 47.2 48.2 0-20 0 35.9 37.3

8-20 2 78.6 80.8 8 4 3 43.7 44.9 -10 20 1 19.0 20.7

-5 2 7 20.1 19.6 2-20 3 19.0 20.9 10 0 1 33.3 36.1

H K L FO FC H K L FO FC H K L FO FC

0-20 1 20.2 23.0 1 14 6 22.9 22.2 -11 2 1 28.0 29.2

-10 14 4 67.3 66.1 7-16 6 12.7 9.8 1 20 1 19.6 20.0

7 6 4 57.6 55.6 -7 10 7 50.9 49.5 10-22 1 43.3 46.3

3-20 4 47.2 46.5 5 4 7 51.4 51.2 -12 8 1 42.0 40.9

-10 6 4 17.4 18.5 2-14 7 56.1 54.4 4 16 1 46.2 44.8

3 14 4 19.2 20.5 -7 4 7 38.8 39.7 8-24 1 29.8 29.2

7-20 4 30.7 33.7 2 10 7 45.0 47.5 -10 18 4 36.8 37.7

-9 14 5 50.3 50.6 5-14 7 25.6 25.3 9 2 4 45.4 44.3

7 4 5 44.8 44.4 -12 12 0 22.4 23.1 1-20 4 62.0 60.8

2-18 5 48.2 48.6 6 12 0 27.2 26.4 -11 10 4 56.5 56.0

-8 12 6 31.0 30.5 6-24 0 22.6 25.2 5 12 4 44.6 44.2

6 4 6 27.0 26.2 -11 18 2 35.1 35.4 6-22 4 76.7 76.6

2-16 6 29.7 29.1 9 4 2 35.6 34.4 -11 12 4 32.5 34.3

-11 16 2 44.1 43.9 2-22 2 21.4 21.4 6 10 4 28.7 30.5

8 6 2 55.4 54.5 -11 4 2 36.2 34.8 5-22 4 23.4 26.1

3-22 2 60.1 60.1 2 18 2 33.2 31.4 -10 2 4 33.8 36.1

-11 6 2 30.0 30.6 9-22 2 33.9 30.2 1 18 4 49.7 53.7

3 16 2 55.0 57.3 -5 4 8 35.1 35.3 9-20 4 33.5 35.7

8-22 2 40.0 42.6 2 6 8 36.7 38.3 -9 12 6 90.7 90.0

-4 2 8 18.1 16.9 3-10 8 45.3 47.9 6 6 6 86.7 84.8

1 6 8 21.9 19.4 -12 14 0 62.0 64.1 3-18 6 84.4 84.3

3 -8 8 16.0 15.4 7 10 0 52.6 53.4 -9 6 6 106.9 104.7

-11 4 0 63.7 62.3 5-24 0 40.0 43.2 3 12 6 106.8 102.8

2 18 0 47.5 46.1 -10 10 5 30.9 32.7 6-18 6 94.6 92.6

9-22 0 79.0 81.9 5 10 5 47.6 50.0 -12 12 2 47.9 52.6

-9 18 4 33.5 34.7 5-20 5 46.4 48.8 6 12 2 47.7 51.1

9 0 4 40.8 40.7 -12 14 1 36.5 38.0 6-24 2 54.8 61.2

0-18 4 41.2 41.5 7 10 1 41.7 43.5 -10 14 5 33.6 37.0

-10 18 3 53.6 51.8 5-24 1 45.2 46.3 7 6 5 29.3 31.7

9 2 3 58.3 55.3 -12 10 1 29.0 28.2 3-20 5 45.3 52.0

1-20 3 60.4 57.7 5 14 1 24.0 23.5 -10 6 5 38.6 41.9

-11 12 3 66.2 64.5 7-24 1 33.3 32.3 3 14 5 36.7 39.4

6 10 3 61.0 59.6 -5 2 8 82.4 76.8 7-20 5 27.9 28.9

5-22 3 73.5 70.8 1 8 8 71.5 66.8 -8 16 6 109.8 107.8

-11 10 3 42.0 43.8 4-10 8 82.2 77.3 8 0 6 111.3 108.8

5 12 3 41.2 42.7 -5 8 8 50.9 50.1 0-16 6 117.0 113.8

6-22 3 43.1 45.6 4 2 8 40.4 38.8 -12 10 2 44.5 49.2

-10 2 3 23.5 26.1 1-10 8 45.7 44.2 5 14 2 51.0 55.6

1 18 3 20.7 22.1 -11 2 0 78.2 76.5 7-24 2 27.9 31.0

9-20 3 32.0 35.2 1 20 0 96.8 94.9 -5 10 8 41.9 40.4

-11 4 1 92.5 92.3 10-22 0 82.5 83.4 5 0 8 37.9 35.8

2 18 1 96.3 96.3 -10 8 5 43.7 44.0 0-10 8 30.6 29.2

9-22 1 77.2 77.2 4 12 5 41.2 40.9 -11 14 4 55.8 57.1

-11 14 3 32.6 33.8 6-20 5 47.2 47.8 7 8 4 54.2 54.3

7 8 3 40.6 42.3 -9 10 6 48.1 48.2 4-22 4 55.7 57.3

4-22 3 36.2 37.5 5 8 6 37.2 37.6 -11 8 4 82.1 80.2

-7 8 7 74.1 72.0 4-18 6 16.8 17.7 4 14 4 89.3 86.8

4 6 7 74.1 72.3 -7 12 7 23.0 25.2 7-22 4 88.3 86.9

3-14 7 76.0 73.9 6 2 7 23.2 25.6 -11 18 3 24.4 25.4

-4 8 8 21.9 22.8 1-14 7 12.7 14.1 9 4 3 35.4 37.8

4 0 8 22.0 22.9 -12 16 0 48.1 48.3 2-22 3 39.0 40.4

0 -8 8 23.0 24.6 8 8 0 53.6 54.2 -11 4 3 86.1 85.4

-10 16 4 50.1 52.6 4-24 0 49.1 48.0 2 18 3 82.4 80.4

8 4 4 51.8 51.9 -12 8 0 37.2 34.1 9-22 3 70.4 69.0

2-20 4 48.9 50.0 4 16 0 32.9 29.9 -9 18 5 32.3 31.6

-8 14 6 59.5 58.0 8-24 0 58.2 53.6 9 0 5 29.5 29.9

7 2 6 65.0 62.0 -11 20 1 105.5 100.4 0-18 5 32.6 32.0

1-16 6 62.0 59.9 10 2 1 103.9 98.8 -11 20 2 66.7 69.6

-8 2 6 24.9 24.6 1-22 1 91.1 87.3 10 2 2 75.7 75.9

H K L FO FC H K L FO FC H K L FO FC

1-22 2 95.9 98.1 1 20 3 31.1 31.4 -13 10 0 44.8 47.7

-6 6 8 30.9 28.9 10-22 3 60.3 59.6 5 16 0 44.6 46.1

3 6 8 33.5 30.7 -12 20 0 38.9 43.3 8-26 0 46.4 48.8

3-12 8 39.9 35.7 10 4 0 27.8 31.8 -10 14 6 27.8 22.8

-12 18 0 72.3 73.4 2-24 0 45.0 51.7 7 6 6 28.1 25.0

9 6 0 71.5 69.9 -12 4 0 50.4 49.9 3-20 6 26.9 23.1

3-24 0 67.9 67.8 2 20 0 54.7 55.2 -12 6 3 36.2 36.5

-12 6 0 25.3 25.0 10-24 0 56.6 58.3 3 18 3 21.1 21.4

3 18 0 31.3 29.7 -12 20 1 30.5 30.4 9-24 3 34.1 34.0

9-24 0 31.6 32.9 10 4 1 33.1 33.5 -9 10 7 37.9 38.1

-12 16 2 83.9 83.1 2-24 1 38.3 37.9 5 8 7 36.5 35.4

8 8 2 81.4 79.6 -11 4 4 70.1 67.0 4-18 7 34.0 33.1

4-24 2 66.9 66.4 2 18 4 62.0 59.4 -9 8 7 29.9 32.3

-12 8 2 84.1 83.5 9-22 4 80.0 77.1 4 10 7 22.7 23.7

4 16 2 79.8 78.5 -10 10 6 31.5 31.1 5-18 7 22.1 23.1

8-24 2 99.5 97.4 5 10 6 23.6 21.2 -9 18 6 34.6 33.5

-6 8 8 70.1 67.5 5-20 6 40.6 42.0 9 0 6 37.1 35.8

4 4 8 74.7 71.6 -6 12 8 22.9 21.9 0-18 6 37.5 36.6

2-12 8 79.6 76.0 6 0 8 25.7 24.7 -9 12 7 55.4 54.3

-6 4 8 68.3 66.7 0-12 8 40.8 36.4 6 6 7 66.6 64.9

2 8 8 72.2 70.9 -10 18 5 30.9 32.3 3-18 7 69.8 68.7

4-12 8 76.6 75.0 9 2 5 29.5 30.1 -9 6 7 27.8 29.4

-12 6 1 43.9 40.5 1-20 5 27.2 27.7 3 12 7 33.8 34.2

3 18 1 29.6 26.9 -11 12 5 48.4 48.1 6-18 7 31.1 31.5

9-24 1 41.3 38.9 6 10 5 44.3 43.6 -11 16 5 34.6 31.4

-10 16 5 26.0 26.5 5-22 5 46.5 45.8 8 6 5 22.1 22.1

8 4 5 21.4 22.7 -11 10 5 71.1 70.8 3-22 5 33.5 31.4

2-20 5 17.3 18.8 5 12 5 65.7 66.0 -13 12 2 50.3 50.4

-10 4 5 34.5 33.2 6-22 5 52.0 51.6 6 14 2 42.3 41.0

2 16 5 20.8 21.1 -10 12 6 31.0 30.6 7-26 2 55.4 57.0

8-20 5 31.7 30.1 6 8 6 20.6 19.4 -5 6 9 48.6 49.3

-3 4 9 78.2 78.6 4-20 6 30.8 30.7 3 4 9 53.0 53.8

2 2 9 81.2 81.5 -4 2 9 23.9 22.6 2-10 9 52.2 54.2

1 -6 9 81.3 81.8 1 6 9 32.3 31.9 -5 4 9 38.0 37.9

-3 2 9 52.7 52.2 3 -8 9 25.4 24.7 2 6 9 40.1 39.4

1 4 9 59.5 59.1 -7 8 8 33.4 35.4 3-10 9 42.2 42.4

2 -6 9 51.0 50.2 4 6 8 26.9 28.5 -7 12 8 50.5 50.7

-6 10 8 84.5 81.2 3-14 8 13.6 15.3 6 2 8 45.2 43.0

5 2 8 85.6 81.8 -13 12 0 57.5 52.8 1-14 8 52.8 52.4

1-12 8 83.5 79.3 6 14 0 46.5 44.0 -7 2 8 72.5 71.0

-6 2 8 24.3 21.7 7-26 0 32.1 29.5 1 12 8 72.9 72.0

1 10 8 25.3 22.3 -13 14 0 48.2 49.2 6-14 8 68.0 67.1

5-12 8 27.3 23.9 7 12 0 62.1 62.8 -13 18 0 73.1 71.1

-10 20 4 38.9 43.1 6-26 0 45.9 47.1 9 8 0 58.6 59.8

10 0 4 26.5 28.2 -11 14 5 30.3 32.8 4-26 0 43.2 43.0

0-20 4 28.2 30.5 7 8 5 36.2 37.9 -11 2 4 73.5 71.5

-12 6 2 39.8 44.7 4-22 5 27.3 28.5 1 20 4 83.0 80.4

3 18 2 41.1 46.3 -13 14 1 50.4 47.5 10-22 4 76.4 76.5

9-24 2 46.8 53.9 7 12 1 54.6 51.9 -12 16 4 38.5 37.8

-9 16 6 51.6 51.3 6-26 1 64.6 61.1 8 8 4 38.7 38.6

8 2 6 36.3 37.8 -13 12 1 36.3 38.1 4-24 4 41.6 42.0

1-18 6 27.4 29.4 6 14 1 34.1 35.4 -12 8 4 38.2 36.1

-9 2 6 43.3 43.6 7-26 1 17.1 17.0 4 16 4 37.6 36.0

1 16 6 28.4 26.4 -7 10 8 31.8 30.8 8-24 4 44.6 40.8

8-18 6 43.4 44.2 5 4 8 38.1 35.9 -10 4 6 59.0 57.0

-11 20 3 118.3 112.5 2-14 8 21.7 20.6 2 16 6 64.4 62.3

10 2 3 115.0 109.5 -13 16 0 68.3 72.5 8-20 6 61.4 62.1

1-22 3 96.7 91.2 8 10 0 68.3 70.6 -9 14 7 37.2 38.8

-11 2 3 33.9 33.3 5-26 0 66.5 69.9 7 4 7 35.6 37.0

H K L FO FC H K L FO FC H K L FO FC

2-18 7 41.1 42.9 7 10 5 39.5 40.4 -13 14 4 46.0 47.6

-8 8 8 99.3 94.5 5-24 5 46.5 47.1 7 12 4 56.9 58.1

4 8 8 94.9 90.4 -12 10 5 32.7 26.8 6-26 4 37.2 38.7

4-16 8 102.0 98.1 5 14 5 24.7 21.0 -9 18 7 30.7 29.9

-11 4 5 75.0 76.6 7-24 5 30.0 24.7 9 0 7 29.9 27.9

2 18 5 81.4 84.3 -6 10 9 73.9 72.7 0-18 7 36.6 36.2

9-22 5 60.3 62.1 5 2 9 73.3 73.3 -7 8 9 49.4 48.8

-13 18 2 77.3 76.7 1-12 9 71.9 71.5 4 6 9 53.4 52.7

9 8 2 64.8 62.4 -10 8 7 38.7 37.6 3-14 9 51.3 50.1

4-26 2 67.4 66.6 4 12 7 41.0 40.5 -14 18 0 41.3 46.6

-12 22 2 50.7 51.2 6-20 7 44.4 44.1 9 10 0 40.0 43.2

11 2 2 36.0 35.7 -12 24 1 33.7 33.7 5-28 0 30.5 32.4

1-24 2 38.1 38.3 12 0 1 30.3 30.1 -14 10 0 31.8 34.1

-13 8 2 46.1 46.9 0-24 1 29.1 28.9 5 18 0 23.7 24.3

4 18 2 27.6 27.6 -11 20 5 83.0 82.5 9-28 0 57.2 63.8

9-26 2 33.9 34.6 10 2 5 78.6 76.8 -13 16 4 68.1 68.3

-12 2 2 31.1 28.6 1-22 5 65.3 64.7 8 10 4 60.2 58.0

1 22 2 33.6 31.6 -11 2 5 21.2 23.2 5-26 4 70.4 70.3

11-24 2 41.3 39.4 1 20 5 20.1 21.7 -13 10 4 44.9 47.6

-8 6 8 26.1 26.2 10-22 5 32.6 35.9 5 16 4 39.6 40.3

3 10 8 31.4 32.8 -12 20 4 33.1 33.1 8-26 4 45.3 50.1

5-16 8 33.5 33.4 10 4 4 25.8 24.9 -13 6 3 54.5 54.6

-12 18 4 45.1 46.5 2-24 4 32.2 32.3 3 20 3 49.0 48.9

9 6 4 47.3 47.1 -12 4 4 46.4 43.8 10-26 3 49.5 52.0

3-24 4 50.7 52.2 2 20 4 49.8 47.5 -12 6 5 37.8 36.6

-13 14 3 40.1 40.4 10-24 4 42.7 42.2 3 18 5 27.7 25.8

7 12 3 39.0 38.6 -8 2 8 94.2 88.7 9-24 5 27.4 26.3

6-26 3 50.6 50.9 1 14 8 88.5 83.9 -14 10 1 64.2 62.1

-13 12 3 30.3 27.3 7-16 8 96.4 93.6 5 18 1 73.1 70.7

6 14 3 32.9 30.9 -12 8 5 37.1 35.9 9-28 1 63.2 61.4

7-26 3 31.8 29.9 4 16 5 42.6 41.0 -4 4 10 70.8 68.9

-13 6 1 50.6 53.3 8-24 5 33.4 33.5 2 4 10 71.3 68.7

3 20 1 55.8 59.5 -11 16 6 28.7 30.6 2 -8 10 79.8 77.2

10-26 1 39.7 40.7 8 6 6 31.2 31.4 -14 14 2 64.5 65.5

-6 6 9 28.9 27.3 3-22 6 36.9 38.8 7 14 2 58.2 57.1

3 6 9 26.9 26.8 -11 6 6 45.1 44.8 7-28 2 53.6 56.4

3-12 9 29.1 29.0 3 16 6 60.6 58.7 -13 4 2 40.7 40.7

-1 2 10 25.8 21.2 8-22 6 54.7 54.6 2 22 2 49.7 49.5

1 0 10 23.6 19.5 -10 14 7 53.9 50.7 11-26 2 48.6 52.5

0 -2 10 25.3 22.0 7 6 7 46.7 44.2 -7 4 9 31.2 33.5

-6 4 9 51.6 50.7 3-20 7 61.8 58.2 2 10 9 36.3 37.8

2 8 9 63.6 64.2 -10 6 7 27.3 25.8 5-14 9 26.4 27.5

4-12 9 45.0 45.0 3 14 7 25.4 25.1 -7 10 9 38.2 41.6

-8 4 8 54.6 54.1 7-20 7 27.7 28.0 5 4 9 31.4 32.9

2 12 8 50.4 50.4 -14 16 0 51.5 53.2 2-14 9 41.6 45.2

6-16 8 62.0 62.5 8 12 0 57.5 59.4 -10 4 7 24.7 22.5

-2 2 10 80.2 78.7 6-28 0 80.3 81.2 2 16 7 14.2 12.2

1 2 10 77.6 75.9 -13 22 1 36.6 35.7 8-20 7 34.9 31.1

1 -4 10 80.8 79.4 11 4 1 35.8 35.1 -4 2 10 40.7 38.4

-11 14 6 22.5 23.4 2-26 1 27.5 26.0 1 6 10 39.4 37.5

7 8 6 30.5 31.0 -14 14 1 46.5 48.3 3 -8 10 37.2 35.3

4-22 6 23.5 24.2 7 14 1 26.9 28.9 -8 16 8 54.6 54.4

-10 10 7 29.7 30.1 7-28 1 39.1 41.3 8 0 8 45.4 44.3

5 10 7 37.1 39.5 -13 4 1 33.7 33.1 0-16 8 49.7 49.4

5-20 7 31.3 31.5 2 22 1 35.9 36.1 -13 18 4 43.5 46.1

-12 24 0 83.7 85.4 11-26 1 50.0 50.4 9 8 4 31.1 33.5

12 0 0 85.6 86.4 -14 16 1 26.5 26.6 4-26 4 18.8 18.9

0-24 0 92.4 92.8 8 12 1 23.8 23.4 -4 8 10 47.2 48.3

-12 14 5 33.5 34.1 6-28 1 27.3 27.0 4 0 10 50.9 52.9

H K L FO FC H K L FO FC H K L FO FC

0 -8 10 44.6 45.8 4 16 6 45.8 43.3 -14 18 4 40.1 41.7

-9 14 8 48.9 48.0 8-24 6 77.1 77.3 9 10 4 39.8 41.2

7 4 8 54.4 52.9 -13 2 2 91.0 88.9 5-28 4 32.1 33.8

2-18 8 50.7 49.5 1 24 2 79.8 78.4 -14 10 4 25.2 27.1

-9 4 8 29.8 27.5 12-26 2 65.8 64.7 5 18 4 22.9 23.7

2 14 8 39.9 38.1 -14 10 3 52.3 50.7 9-28 4 42.6 47.7

7-18 8 33.7 31.1 5 18 3 64.7 63.2 -13 6 5 43.0 43.3

-13 2 0 51.3 53.2 9-28 3 63.5 64.6 3 20 5 48.2 48.6

1 24 0 29.9 30.0 -5 10 10 46.5 44.1 10-26 5 37.5 35.9

12-26 0 49.1 51.4 5 0 10 52.0 50.4 -15 16 2 73.9 72.3

-12 12 6 49.1 50.3 0-10 10 50.5 49.6 8 14 2 86.8 82.7

6 12 6 45.2 43.7 -10 8 8 33.8 37.0 7-30 2 62.0 60.2

6-24 6 49.9 50.8 4 12 8 37.3 41.0 -15 20 0 40.0 42.0

-5 6 10 28.2 25.4 6-20 8 23.0 24.4 10 10 0 22.8 20.4

3 4 10 28.3 25.5 -10 12 8 27.1 26.5 5-30 0 38.6 41.3

2-10 10 33.5 30.5 6 8 8 27.1 25.1 -15 10 0 38.0 40.5

-14 14 3 34.6 35.6 4-20 8 32.0 30.0 5 20 0 35.2 39.2

7 14 3 25.7 25.8 -12 24 4 58.6 59.7 10-30 0 34.1 35.5

7-28 3 33.5 33.1 12 0 4 61.7 60.7 -6 12 10 45.6 44.0

-13 22 3 52.8 54.4 0-24 4 66.5 65.9 6 0 10 50.8 49.3

11 4 3 47.9 48.9 -6 6 10 50.3 48.5 0-12 10 46.7 45.6

2-26 3 34.1 34.5 3 6 10 52.9 50.5 -15 18 2 33.1 34.8

-13 4 3 32.8 35.5 3-12 10 40.0 38.6 9 12 2 26.3 25.9

2 22 3 37.7 40.2 -12 6 6 38.9 40.7 6-30 2 40.0 41.0

11-26 3 50.0 51.9 3 18 6 33.9 34.4 -15 12 2 29.1 33.3

-10 18 7 36.6 35.8 9-24 6 36.6 38.4 6 18 2 28.1 31.3

9 2 7 43.2 42.4 -6 4 10 21.8 23.2 9-30 2 37.6 44.1

1-20 7 37.4 37.5 2 8 10 18.4 18.3 -3 2 11 41.2 43.5

-11 12 7 44.0 43.0 4-12 10 29.0 29.9 1 4 11 39.1 39.5

6 10 7 45.9 44.6 -14 20 3 35.4 36.8 2 -6 11 41.2 43.9

5-22 7 48.2 47.2 10 8 3 52.0 53.1 -3 4 11 47.3 48.7

-11 10 7 43.3 46.7 4-28 3 40.3 41.6 2 2 11 46.8 46.8

5 12 7 39.7 41.5 -10 6 8 21.4 22.8 1 -6 11 47.1 47.6

6-22 7 38.6 41.6 3 14 8 25.5 26.2 -7 6 10 32.8 30.8

-13 20 4 47.4 47.3 7-20 8 31.6 32.3 3 8 10 30.4 28.3

10 6 4 37.5 35.1 -15 16 0 26.6 26.4 4-14 10 34.4 31.4

3-26 4 40.4 39.3 8 14 0 39.8 39.0 -13 12 6 55.2 53.7

-5 8 10 29.8 27.9 7-30 0 44.7 44.5 6 14 6 45.3 43.6

4 2 10 28.0 25.8 -13 22 4 31.6 30.6 7-26 6 53.3 51.5

1-10 10 29.3 27.8 11 4 4 27.7 24.5 13 -2 4 54.0 53.4

-11 20 6 72.6 72.2 2-26 4 38.7 34.6 -1-24 4 31.4 29.9

10 2 6 72.3 69.1 -14 16 4 44.2 47.1 -12 26 4 39.5 37.3

1-22 6 87.3 85.0 8 12 4 40.0 41.0 -7 10 10 33.0 31.4

-14 20 2 52.7 53.6 6-28 4 60.4 64.7 5 4 10 25.9 24.2

10 8 2 56.4 57.0 -14 12 4 31.6 34.1 2-14 10 41.1 37.5

4-28 2 72.6 76.2 6 16 4 32.3 35.2 -7 4 10 51.7 53.7

-14 8 2 44.1 43.1 8-28 4 31.0 34.6 2 10 10 47.5 49.0

4 20 2 46.3 45.1 -15 18 0 28.5 31.0 5-14 10 52.9 55.3

10-28 2 35.4 37.8 9 12 0 27.4 27.3 -11 20 7 75.1 71.8

-11 14 7 24.5 25.2 6-30 0 19.0 21.7 10 2 7 72.7 71.5

7 8 7 35.2 38.3 -6 2 10 14.8 10.9 1-22 7 62.5 60.7

4-22 7 27.3 29.3 1 10 10 19.7 15.4 -10 18 8 24.8 26.5

-13 14 5 40.0 38.6 5-12 10 22.8 17.5 9 2 8 30.0 31.9

7 12 5 43.1 41.6 -11 4 7 58.6 61.6 1-20 8 43.1 47.2

6-26 5 52.1 50.2 2 18 7 62.6 65.6 -11 10 8 39.5 40.7

-12 16 6 65.6 67.9 9-22 7 46.0 47.6 5 12 8 31.1 31.0

8 8 6 65.4 67.5 -15 12 1 49.1 49.3 6-22 8 45.9 46.0

4-24 6 53.6 54.4 6 18 1 45.3 44.7 -14 14 5 40.7 41.6

-12 8 6 52.4 50.8 9-30 1 49.9 50.4 7 14 5 24.3 26.9

H K L FO FC H K L FO FC H K L FO FC

7-28 5 37.0 39.3 9 14 0 45.5 46.8 -15 12 5 48.4 47.1

-13 4 5 27.0 30.2 7-32 0 32.4 28.7 6 18 5 46.8 44.5

2 22 5 26.8 30.6 -14 4 4 26.4 26.5 9-30 5 43.0 41.3

11-26 5 41.0 47.8 2 24 4 29.4 30.0 -2 4 12 20.7 18.1

-11 14 8 41.2 40.5 12-28 4 34.4 34.7 2 0 12 20.4 17.6

7 8 8 42.0 41.0 -14 26 3 45.7 43.1 0 -4 12 27.0 23.0

4-22 8 39.1 38.1 13 2 3 50.6 50.4 -14 20 6 50.0 54.5

-11 8 8 55.5 50.7 1-28 3 52.6 51.4 10 8 6 49.2 51.0

4 14 8 64.6 60.7 14 -2 3 27.6 23.7 4-28 6 51.7 54.0

7-22 8 69.4 65.9 -1-26 3 37.5 33.4 -7 8 11 33.9 32.8

-13 18 6 75.1 69.9 -13 28 3 42.4 33.6 4 6 11 28.8 26.5

9 8 6 65.2 61.3 -13 14 7 34.6 33.4 3-14 11 35.7 35.6

4-26 6 68.7 65.5 7 12 7 36.7 36.4 -13 2 6 53.9 56.1

-12 22 6 38.5 35.6 6-26 7 51.7 51.9 1 24 6 47.5 50.9

11 2 6 29.4 27.9 -6 6 11 37.8 38.4 12-26 6 49.4 55.3

1-24 6 27.2 25.2 3 6 11 33.2 32.7 -13 6 7 34.1 37.0

-14 26 1 40.1 40.6 3-12 11 35.3 36.3 3 20 7 34.7 38.1

13 2 1 38.6 37.4 -8 14 10 35.4 34.7 10-26 7 29.9 32.5

1-28 1 44.9 46.1 7 2 10 35.8 34.6 -16 24 0 41.9 40.0

-14 24 3 37.7 37.0 1-16 10 30.6 28.8 12 8 0 33.4 34.0

12 4 3 34.7 34.3 -14 14 6 44.3 46.3 4-32 0 32.3 29.7

2-28 3 34.9 35.8 7 14 6 46.3 47.6 -16 8 0 56.3 53.3

-14 10 5 59.0 55.2 7-28 6 33.5 34.4 4 24 0 52.8 51.1

5 18 5 68.5 64.4 -13 4 6 43.0 42.3 12-32 0 67.1 63.5

9-28 5 53.4 49.3 2 22 6 58.9 57.5 -7 10 11 30.6 29.7

-15 22 2 53.4 53.0 11-26 6 50.5 51.1 5 4 11 25.5 25.9

11 8 2 49.3 47.9 -6 4 11 22.4 24.7 2-14 11 29.8 27.9

4-30 2 41.2 41.1 2 8 11 22.4 22.2 -3 4 12 38.4 34.9

-14 26 2 31.4 38.0 4-12 11 17.1 17.6 2 2 12 32.9 30.1

13 2 2 31.9 35.3 -16 18 2 57.6 57.0 1 -6 12 36.6 34.6

1-28 2 52.4 59.7 9 14 2 58.1 56.2 -3 2 12 25.9 22.4

-15 24 0 44.0 47.6 7-32 2 65.7 67.2 1 4 12 22.2 19.8

12 6 0 50.9 52.3 -15 4 0 38.2 38.6 2 -6 12 26.0 23.1

3-30 0 53.9 55.6 2 26 0 34.8 35.5 -3 6 12 59.7 52.7

-5 4 11 37.9 36.7 13-30 0 31.1 32.5 3 0 12 61.6 55.5

2 6 11 37.8 37.2 -11 2 8 47.3 43.7 0 -6 12 61.5 54.7

3-10 11 44.3 44.4 1 20 8 55.7 51.7 -15 24 4 32.0 35.7

-5 6 11 36.7 38.5 10-22 8 52.3 50.9 12 6 4 34.4 35.6

3 4 11 36.8 38.4 -16 22 0 37.1 35.4 3-30 4 42.6 46.3

2-10 11 32.9 33.2 11 10 0 29.9 24.7 -16 24 2 53.7 57.9

-8 10 10 34.4 35.5 5-32 0 36.9 33.2 12 8 2 47.4 50.4

5 6 10 44.8 45.9 -16 10 0 51.7 48.8 4-32 2 64.0 69.8

3-16 10 39.8 41.6 5 22 0 54.4 51.3 -16 8 2 72.9 73.1

-8 6 10 43.8 45.3 11-32 0 56.9 58.2 4 24 2 69.9 69.5

3 10 10 45.7 47.8 -6 2 11 21.8 20.9 12-32 2 71.9 73.0

5-16 10 44.9 46.7 1 10 11 30.3 28.9 -16 16 4 49.0 52.0

-7 14 10 24.0 24.2 5-12 11 32.8 34.0 8 16 4 48.2 49.0

7 0 10 25.5 24.2 -6 10 11 52.2 52.8 8-32 4 50.7 55.0

0-14 10 22.6 20.6 5 2 11 47.5 47.3 -8 8 11 29.3 24.3

-16 16 0 43.5 48.4 1-12 11 46.4 46.1 4 8 11 19.6 17.6

8 16 0 50.1 55.1 -9 12 10 48.8 52.6 4-16 11 22.8 19.9

8-32 0 47.1 53.0 6 6 10 49.5 51.6 13-16 8 44.7 44.0

-10 14 9 39.0 39.8 3-18 10 44.3 47.3 -8-10 8 41.9 40.9

7 6 9 34.0 33.6 -9 6 10 60.4 60.6 -5 26 8 51.6 52.9

3-20 9 41.1 40.7 3 12 10 67.6 67.3 -13 10 8 33.7 36.3

-11 4 8 52.5 52.0 6-18 10 55.2 55.2 5 16 8 31.6 32.5

2 18 8 42.9 43.1 -8 16 10 68.7 64.7 8-26 8 29.9 33.3

9-22 8 55.7 54.3 8 0 10 71.8 68.6 15-16 6 41.8 42.8

-16 18 0 40.0 40.4 0-16 10 78.4 75.0 -8-14 6 50.2 50.5

H K L FO FC H K L FO FC H K L FO FC

-7 30 6 43.0 44.8 10 2 9 60.0 59.9 -6 10 12 33.8 33.6

-14 10 7 41.3 42.8 1-22 9 46.5 46.2 5 2 12 36.8 37.7

5 18 7 46.2 47.1 -6 4 12 43.8 42.9 1-12 12 37.3 38.2

9-28 7 37.9 38.1 2 8 12 41.3 39.5 -12 24 8 36.1 40.8

-17 14 1 46.6 51.8 4-12 12 46.1 44.4 12 0 8 36.8 38.8

7 20 1 41.0 44.2 -6 8 12 23.5 24.0 0-24 8 40.7 43.1

10-34 1 40.6 43.6 4 4 12 24.9 24.3 -7 10 12 31.2 25.1

-5 4 12 25.7 25.3 2-12 12 29.9 30.7 5 4 12 35.6 27.4

2 6 12 26.8 26.9 -16 8 4 44.2 47.7 2-14 12 28.3 24.9

3-10 12 24.8 24.0 4 24 4 38.2 40.5 -3 4 13 37.3 39.6

-5 8 12 25.8 26.0 12-32 4 48.9 51.5 2 2 13 37.5 39.5

4 2 12 23.5 23.0 -9 10 11 21.1 16.7 1 -6 13 38.2 40.3

1-10 12 27.0 26.1 5 8 11 22.1 17.7 -3 2 13 24.0 30.4

-5 2 12 39.3 36.2 4-18 11 27.5 24.7 1 4 13 25.4 32.4

1 8 12 41.6 39.7 -17 14 3 39.4 42.8 2 -6 13 19.9 23.4

4-10 12 46.6 45.3 7 20 3 41.0 45.1 -7 12 12 28.1 26.0

-16 10 4 46.9 52.7 10-34 3 44.1 47.4 6 2 12 34.4 33.8

5 22 4 47.2 51.9 -9 6 11 30.8 26.8 1-14 12 33.8 32.5

11-32 4 42.0 49.1 3 12 11 36.8 32.3 -7 2 12 27.3 30.7

-10 4 10 41.2 44.5 6-18 11 37.2 32.8 1 12 12 26.4 29.1

2 16 10 38.2 39.9 -9 12 11 33.2 34.3 6-14 12 27.0 32.3

8-20 10 36.4 38.4 6 6 11 39.4 42.3 0 0 0 0.0 0.0

-11 20 9 64.3 66.7 3-18 11 39.5 42.6 0 0 0 0.0 0.0