Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:
Uptake, Site Preference and
Degradation of Monoclinic Structure
Michael E. Fleet, Xioayang Liu
and Yuanming Pan
Deposited Material
Table 5. List of observed and calculated structure factors
(a) P63/m structure of La-chlorapatite
H K L FO FC H K L FO FC H K L FO FC
0 0 2 100.1 106.0 -3 1 0 42.1 43.3 -5 4 7 0.0 6.0
0 0 4 186.1 198.3 -3 0 10 0.0 5.3 -5 4 6 0.0 14.5
0 0 6 98.0 98.7 -3 0 9 0.0 5.4 -5 4 5 0.0 0.7
0 0 8 79.4 73.3 -3 0 8 31.8 31.3 -5 4 4 47.3 47.7
0 0 10 0.0 39.9 -3 0 7 0.0 9.0 -5 4 3 17.2 18.5
-1 0 10 0.0 11.6 -3 0 6 12.1 12.1 -5 4 2 29.2 29.8
-1 0 9 0.0 2.6 -3 0 5 0.0 10.2 -5 4 1 0.0 3.6
-1 0 8 16.1 15.7 -3 0 4 73.7 73.9 -5 4 0 64.6 65.8
-1 0 7 0.0 5.4 -3 0 3 24.9 24.8 5 -3 10 0.0 1.8
-1 0 6 19.4 20.1 -3 0 2 40.1 39.4 -5 3 9 0.0 18.4
-1 0 5 0.0 7.5 -3 0 1 27.0 26.2 -5 3 8 22.5 22.1
-1 0 4 23.3 23.3 -3 0 0 158.3 153.8 -5 3 7 17.9 19.8
-1 0 3 0.0 4.0 -4 3 10 0.0 17.3 -5 3 6 0.0 5.7
-1 0 2 0.0 0.1 -4 3 9 0.0 12.4 -5 3 5 49.3 49.8
-1 0 1 15.8 15.9 -4 3 8 0.0 13.3 -5 3 4 38.2 38.7
-1 0 0 13.7 14.1 -4 3 7 24.9 24.8 -5 3 3 17.8 18.0
-2 1 10 0.0 28.3 -4 3 6 44.0 44.8 -5 3 2 14.1 14.0
-2 1 9 0.0 7.5 -4 3 5 26.7 26.3 -5 3 1 63.8 63.8
-2 1 8 0.0 0.4 -4 3 4 0.0 5.6 -5 3 0 59.8 58.7
-2 1 7 0.0 4.7 -4 3 3 39.3 39.4 5 -2 10 0.0 16.8
-2 1 6 61.8 61.3 -4 3 2 28.9 28.9 -5 2 9 0.0 16.7
-2 1 5 11.2 12.2 -4 3 1 42.9 43.2 -5 2 8 0.0 0.2
-2 1 4 0.0 7.2 -4 3 0 92.2 87.9 -5 2 7 25.6 26.1
-2 1 3 42.7 42.2 -4 2 10 0.0 24.5 -5 2 6 31.3 30.5
2 -1 2 0.0 111.8 -4 2 9 0.0 0.1 -5 2 5 28.3 28.8
-2 1 1 12.8 12.9 -4 2 8 0.0 4.4 -5 2 4 0.0 10.4
-2 1 0 0.0 0.3 -4 2 7 0.0 2.6 -5 2 3 52.4 52.7
-2 0 10 0.0 11.0 -4 2 6 47.1 47.5 -5 2 2 39.4 39.7
-2 0 9 0.0 1.4 -4 2 5 0.0 9.4 -5 2 1 51.7 51.7
-2 0 8 0.0 8.8 -4 2 4 0.0 0.1 -5 2 0 14.9 15.4
-2 0 7 0.0 1.5 -4 2 3 9.7 9.9 5 -1 10 0.0 4.7
-2 0 6 20.2 20.0 -4 2 2 116.8 115.4 -5 1 9 0.0 0.3
-2 0 5 19.3 20.2 -4 2 1 6.9 7.6 -5 1 8 0.0 18.0
-2 0 4 0.0 6.0 -4 2 0 17.5 18.4 -5 1 7 0.0 2.5
-2 0 3 26.8 26.0 -4 1 10 0.0 11.5 -5 1 6 0.0 10.9
-2 0 2 37.9 37.6 -4 1 9 0.0 13.9 -5 1 5 0.0 2.1
-2 0 1 22.9 22.6 -4 1 8 0.0 4.3 -5 1 4 49.9 50.2
-2 0 0 4.6 4.1 -4 1 7 0.0 7.2 -5 1 3 0.0 1.3
-3 2 10 0.0 6.8 -4 1 6 14.6 15.3 -5 1 2 35.7 35.7
-3 2 9 0.0 20.6 -4 1 5 0.0 5.0 -5 1 1 0.0 2.4
-3 2 8 30.8 31.9 -4 1 4 0.0 4.8 -5 1 0 93.7 93.7
-3 2 7 34.1 34.2 -4 1 3 40.9 40.7 -5 0 9 0.0 2.2
-3 2 6 14.5 15.4 -4 1 2 38.0 37.8 -5 0 8 0.0 9.3
-3 2 5 38.1 37.7 -4 1 1 8.7 7.4 -5 0 7 0.0 3.3
-3 2 4 40.7 40.8 -4 1 0 18.9 18.6 -5 0 6 34.1 33.2
-3 2 3 64.9 65.1 4 0 10 0.0 22.3 -5 0 5 23.7 25.2
-3 2 2 50.9 49.4 -4 0 9 0.0 3.0 -5 0 4 18.8 18.4
-3 2 1 68.8 69.6 -4 0 8 0.0 6.2 -5 0 3 0.0 9.0
-3 2 0 0.0 0.7 -4 0 7 0.0 9.3 -5 0 2 53.3 53.0
-3 1 10 0.0 1.3 -4 0 6 38.7 38.1 -5 0 1 33.6 33.2
-3 1 9 30.7 33.6 -4 0 5 13.1 13.4 -5 0 0 14.3 13.7
-3 1 8 21.5 21.3 -4 0 4 13.4 14.4 -6 5 9 0.0 7.9
-3 1 7 36.7 36.3 -4 0 3 0.0 3.1 -6 5 8 0.0 17.8
-3 1 6 0.0 0.1 -4 0 2 51.8 52.3 -6 5 7 0.0 18.8
-3 1 5 58.9 58.7 -4 0 1 12.5 12.8 -6 5 6 0.0 15.0
-3 1 4 29.4 29.6 -4 0 0 27.9 28.1 -6 5 5 18.8 20.0
-3 1 3 81.9 81.6 -5 4 10 0.0 6.5 -6 5 4 12.9 12.0
-3 1 2 9.5 8.4 -5 4 9 0.0 5.2 -6 5 3 18.1 19.0
-3 1 1 97.7 98.2 -5 4 8 25.2 24.8 -6 5 2 0.0 0.7
H K L FO FC H K L FO FC H K L FO FC
-6 5 1 29.4 29.7 -7 6 5 0.0 13.6 -7 0 6 25.8 26.1
-6 5 0 0.0 5.4 -7 6 4 40.9 40.8 -7 0 5 0.0 1.1
-6 4 10 0.0 4.9 -7 6 3 15.2 14.9 -7 0 4 0.0 13.2
-6 4 9 0.0 20.9 -7 6 2 33.8 34.3 -7 0 3 21.7 21.9
-6 4 8 33.4 33.0 -7 6 1 19.1 20.1 -7 0 2 35.2 35.7
-6 4 7 0.0 18.9 -7 6 0 27.6 28.1 -7 0 1 0.0 4.7
-6 4 6 0.0 15.4 -7 5 9 0.0 6.6 -7 0 0 17.1 17.5
-6 4 5 24.3 23.6 -7 5 8 0.0 7.6 8 -7 9 0.0 8.5
-6 4 4 48.7 48.2 -7 5 7 0.0 7.4 -8 7 8 32.7 31.5
-6 4 3 46.9 47.2 -7 5 6 21.4 22.1 -8 7 7 0.0 10.7
-6 4 2 38.1 38.1 -7 5 5 0.0 8.5 -8 7 6 0.0 4.8
-6 4 1 31.9 32.6 -7 5 4 0.0 5.7 -8 7 5 0.0 2.0
-6 4 0 58.0 57.4 -7 5 3 0.0 10.6 -8 7 4 53.7 52.4
-6 3 10 0.0 14.9 -7 5 2 82.2 82.0 -8 7 3 26.3 27.3
-6 3 9 0.0 9.6 -7 5 1 0.0 11.2 -8 7 2 0.0 4.3
-6 3 8 0.0 10.4 -7 5 0 47.9 47.6 -8 7 1 0.0 10.9
-6 3 7 0.0 18.1 -7 4 9 0.0 2.1 -8 7 0 66.7 64.6
-6 3 6 28.9 28.9 -7 4 8 0.0 13.2 -8 6 9 0.0 2.2
-6 3 5 29.0 29.0 -7 4 7 0.0 2.1 -8 6 8 0.0 21.9
-6 3 4 25.4 26.4 -7 4 6 42.6 41.7 -8 6 7 0.0 3.1
-6 3 3 16.2 15.1 -7 4 5 0.0 8.0 -8 6 6 0.0 1.9
-6 3 2 49.5 49.9 -7 4 4 29.1 29.5 -8 6 5 0.0 0.6
-6 3 1 39.2 39.6 -7 4 3 0.0 3.0 -8 6 4 27.6 28.1
-6 3 0 39.0 39.1 -7 4 2 61.2 61.4 -8 6 3 0.0 4.0
-6 2 10 0.0 0.7 -7 4 1 0.0 9.6 -8 6 2 0.0 13.6
-6 2 9 0.0 7.0 -7 4 0 41.8 42.5 -8 6 1 0.0 2.2
-6 2 8 38.8 37.9 -7 3 9 0.0 14.9 -8 6 0 17.1 16.3
-6 2 7 0.0 16.4 -7 3 8 0.0 13.3 -8 5 9 0.0 2.5
-6 2 6 0.0 4.9 -7 3 7 26.7 27.0 -8 5 8 0.0 13.3
-6 2 5 16.3 16.9 -7 3 6 0.0 9.5 -8 5 7 0.0 5.2
-6 2 4 44.8 44.0 -7 3 5 21.9 22.3 -8 5 6 41.1 40.8
-6 2 3 27.1 27.5 -7 3 4 17.9 19.7 -8 5 5 0.0 7.2
-6 2 2 49.5 49.3 -7 3 3 53.7 53.8 -8 5 4 26.7 26.4
-6 2 1 30.8 30.7 -7 3 2 0.0 1.3 -8 5 3 0.0 8.0
-6 2 0 10.8 9.7 -7 3 1 41.9 42.3 -8 5 2 52.7 52.1
-6 1 9 0.0 30.5 -7 3 0 16.5 15.6 -8 5 1 0.0 10.0
-6 1 8 39.0 37.8 -7 2 9 0.0 15.6 -8 5 0 38.4 37.8
-6 1 7 33.6 33.7 -7 2 8 0.0 15.6 -8 4 9 0.0 4.5
-6 1 6 0.0 9.6 -7 2 7 20.9 21.9 -8 4 8 32.9 35.1
-6 1 5 52.8 52.9 -7 2 6 0.0 2.9 -8 4 7 0.0 12.8
-6 1 4 52.8 53.1 -7 2 5 20.6 21.3 -8 4 6 0.0 6.1
-6 1 3 58.8 59.0 -7 2 4 38.6 38.7 -8 4 5 25.0 26.0
-6 1 2 48.3 48.8 -7 2 3 38.4 37.9 -8 4 4 61.6 60.6
-6 1 1 72.6 71.9 -7 2 2 27.2 27.8 -8 4 3 0.0 8.7
-6 1 0 43.1 43.0 -7 2 1 33.1 33.8 -8 4 2 0.0 5.5
-6 0 9 0.0 9.9 -7 2 0 76.3 76.5 -8 4 1 33.0 34.1
-6 0 8 0.0 7.6 -7 1 9 0.0 1.7 -8 4 0 76.1 74.7
-6 0 7 0.0 15.2 -7 1 8 0.0 15.8 8 -3 9 0.0 3.2
-6 0 6 33.0 32.9 -7 1 7 0.0 5.1 -8 3 8 0.0 3.9
-6 0 5 0.0 7.3 -7 1 6 0.0 0.9 -8 3 7 0.0 10.7
-6 0 4 15.7 17.4 -7 1 5 0.0 7.4 -8 3 6 0.0 15.7
-6 0 3 27.8 28.0 -7 1 4 23.5 23.8 -8 3 5 0.0 3.1
-6 0 2 49.2 49.3 -7 1 3 0.0 4.9 -8 3 4 0.0 2.0
-6 0 1 14.0 13.6 -7 1 2 0.0 5.0 -8 3 3 17.2 19.6
-6 0 0 21.1 22.8 -7 1 1 0.0 9.0 -8 3 2 17.3 17.8
-7 6 9 0.0 9.7 -7 1 0 29.7 30.2 -8 3 1 0.0 10.4
-7 6 8 29.4 30.7 -7 0 9 0.0 6.3 -8 3 0 0.0 0.5
-7 6 7 0.0 5.3 -7 0 8 0.0 4.9 8 -2 9 0.0 2.4
-7 6 6 0.0 3.0 -7 0 7 0.0 8.2 -8 2 8 0.0 4.0
H K L FO FC H K L FO FC H K L FO FC
-8 2 7 0.0 4.8 -9 5 3 0.0 16.7 -10 8 5 0.0 13.2
-8 2 6 0.0 12.4 -9 5 2 0.0 2.1 -10 8 4 0.0 6.4
-8 2 5 0.0 11.5 -9 5 1 26.0 26.4 -10 8 3 16.7 16.9
-8 2 4 0.0 2.8 -9 5 0 0.0 9.1 -10 8 2 49.3 46.6
-8 2 3 0.0 6.8 -9 4 8 0.0 16.0 -10 8 1 0.0 17.9
-8 2 2 16.2 18.2 -9 4 7 0.0 8.4 -10 8 0 23.5 25.9
-8 2 1 0.0 11.6 -9 4 6 0.0 17.5 -10 8 8 0.0 4.3
-8 2 0 0.0 5.5 -9 4 5 0.0 15.1 -10 7 8 0.0 6.2
8 -1 9 0.0 5.0 -9 4 4 0.0 8.0 -10 7 7 0.0 7.5
-8 1 8 0.0 8.1 -9 4 3 0.0 14.2 -10 7 6 0.0 20.3
-8 1 7 0.0 9.2 -9 4 2 0.0 3.3 -10 7 5 0.0 13.1
-8 1 6 0.0 12.1 -9 4 1 18.4 18.3 -10 7 4 0.0 2.5
-8 1 5 0.0 12.4 -9 4 0 0.0 14.7 -10 7 3 0.0 7.2
-8 1 4 24.9 24.6 -9 3 8 0.0 6.5 -10 7 2 0.0 10.5
-8 1 3 0.0 9.6 -9 3 7 34.0 35.1 -10 7 1 0.0 14.6
-8 1 2 40.4 41.4 -9 3 6 41.6 40.8 -10 7 0 17.8 16.2
-8 1 1 14.1 14.6 -9 3 5 46.0 44.9 -10 6 8 0.0 13.5
-8 1 0 47.7 46.0 -9 3 4 0.0 7.1 -10 6 7 0.0 3.5
-8 0 8 0.0 15.5 -9 3 3 46.8 46.6 -10 6 6 0.0 0.5
-8 0 7 0.0 2.8 -9 3 2 65.8 64.9 -10 6 5 0.0 4.7
-8 0 6 50.9 48.9 -9 3 1 60.8 60.6 -10 6 4 0.0 17.3
-8 0 5 0.0 3.3 -9 3 0 0.0 5.8 -10 6 3 0.0 1.0
-8 0 4 35.3 35.4 -9 2 8 0.0 18.6 -10 6 2 0.0 3.0
-8 0 3 0.0 5.0 -9 2 7 0.0 12.4 -10 6 1 0.0 1.6
-8 0 2 52.9 52.9 -9 2 6 0.0 0.8 -10 6 0 17.1 17.8
-8 0 1 0.0 1.0 -9 2 5 0.0 15.3 -10 5 8 0.0 1.4
-8 0 0 57.4 57.1 -9 2 4 0.0 21.0 -10 5 7 0.0 17.6
-9 8 8 0.0 9.4 -9 2 3 0.0 16.7 -10 5 6 0.0 11.3
-9 8 7 0.0 5.6 -9 2 2 0.0 9.9 -10 5 5 24.1 24.1
-9 8 6 0.0 2.4 -9 2 1 17.7 19.1 -10 5 4 0.0 13.3
-9 8 5 0.0 3.0 -9 2 0 13.5 15.1 -10 5 3 25.3 25.7
-9 8 4 0.0 13.2 -9 1 8 0.0 10.5 -10 5 2 40.4 40.2
-9 8 3 0.0 0.0 -9 1 7 0.0 6.4 -10 5 1 30.1 31.0
-9 8 2 0.0 1.0 -9 1 6 0.0 24.9 -10 5 0 35.6 37.7
-9 8 1 0.0 7.3 -9 1 5 0.0 11.2 -10 4 8 0.0 8.9
-9 8 0 16.1 16.9 -9 1 4 0.0 3.6 -10 4 7 0.0 0.3
-9 7 8 0.0 20.4 -9 1 3 0.0 12.3 -10 4 6 0.0 17.9
-9 7 7 0.0 13.8 -9 1 2 0.0 3.0 -10 4 5 0.0 4.9
-9 7 6 0.0 6.0 -9 1 1 0.0 14.6 -10 4 4 0.0 5.0
-9 7 5 0.0 10.6 -9 1 0 20.3 22.2 -10 4 3 0.0 3.1
-9 7 4 27.1 25.5 -9 0 8 0.0 4.2 -10 4 2 0.0 6.4
-9 7 3 20.7 21.8 -9 0 7 0.0 17.0 -10 4 1 0.0 5.1
-9 7 2 16.0 15.8 -9 0 6 0.0 21.2 -10 4 0 0.0 10.2
-9 7 1 14.8 16.7 -9 0 5 0.0 15.5 -10 3 8 0.0 11.0
-9 7 0 25.1 25.5 -9 0 4 0.0 8.2 -10 3 7 0.0 13.8
-9 6 8 0.0 1.0 -9 0 3 28.4 28.5 -10 3 6 0.0 1.2
-9 6 7 0.0 8.8 -9 0 2 38.8 37.7 -10 3 5 0.0 2.8
-9 6 6 39.0 38.2 -9 0 1 24.3 24.0 -10 3 4 0.0 16.1
-9 6 5 20.0 20.9 -9 0 0 0.0 16.3 -10 3 3 23.6 25.3
-9 6 4 0.0 0.7 -10 9 7 0.0 10.4 -10 3 2 0.0 1.5
-9 6 3 0.0 0.3 -10 9 6 0.0 1.2 -10 3 1 0.0 9.7
-9 6 2 55.3 55.1 -10 9 5 0.0 9.3 -10 3 0 19.7 19.8
-9 6 1 19.2 21.6 -10 9 4 0.0 12.6 -10 2 8 0.0 13.5
-9 6 0 0.0 2.3 -10 9 3 19.8 20.6 -10 2 7 0.0 2.4
-9 5 8 0.0 12.7 -10 9 2 0.0 0.2 -10 2 6 0.0 6.5
-9 5 7 0.0 9.2 -10 9 1 0.0 12.3 -10 2 5 0.0 1.1
-9 5 6 0.0 7.1 -10 9 0 0.0 13.4 -10 2 4 24.8 25.8
-9 5 5 20.6 21.4 -10 8 7 0.0 9.7 -10 2 3 0.0 1.1
-9 5 4 0.0 13.6 -10 8 6 0.0 18.2 -10 2 2 0.0 17.0
H K L FO FC H K L FO FC H K L FO FC
-10 2 1 0.0 0.3 -11 5 5 0.0 6.3 -12 9 4 0.0 20.6
-10 2 0 39.1 38.2 -11 5 4 0.0 7.8 -12 9 3 0.0 8.2
-10 1 7 0.0 18.9 -11 5 3 0.0 16.9 -12 9 2 0.0 12.9
-10 1 6 0.0 0.7 -11 5 2 0.0 6.0 -12 9 1 0.0 8.1
-10 1 5 0.0 13.2 -11 5 1 0.0 10.1 -12 9 0 28.5 28.6
-10 1 4 0.0 17.7 -11 5 0 0.0 2.2 -12 8 6 0.0 19.3
-10 1 3 29.7 29.1 -11 4 7 0.0 7.8 -12 8 5 0.0 20.9
-10 1 2 0.0 5.0 -11 4 6 0.0 5.1 -12 8 4 0.0 10.4
-10 1 1 0.0 21.2 -11 4 5 0.0 7.7 -12 8 3 0.0 11.3
-10 1 0 0.0 14.1 -11 4 4 29.3 29.4 -12 8 2 26.4 24.4
-10 0 7 0.0 1.2 -11 4 3 0.0 10.7 -12 8 1 22.0 22.0
-10 0 6 0.0 1.5 -11 4 2 0.0 9.8 -12 8 0 0.0 12.8
-10 0 5 0.0 5.7 -11 4 1 0.0 11.4 -12 7 6 0.0 7.4
-10 0 4 0.0 11.2 -11 4 0 38.8 36.0 -12 7 5 0.0 3.1
-10 0 3 0.0 5.9 -11 3 7 0.0 13.6 -12 7 4 0.0 5.0
-10 0 2 0.0 2.6 -11 3 6 0.0 12.7 -12 7 3 0.0 3.7
-10 0 1 0.0 4.1 -11 3 5 0.0 15.4 -12 7 2 0.0 2.2
-10 0 0 0.0 10.0 -11 3 4 0.0 0.6 -12 7 1 0.0 3.2
-11 10 6 0.0 1.1 -11 3 3 0.0 13.7 -12 7 0 0.0 1.6
-11 10 5 0.0 11.2 -11 3 2 0.0 6.7 -12 6 6 0.0 14.3
-11 10 4 29.9 29.5 -11 3 1 20.9 21.2 -12 6 5 0.0 13.2
-11 10 3 0.0 12.0 -11 3 0 0.0 5.7 -12 6 4 0.0 12.7
-11 10 2 0.0 5.1 -11 2 7 0.0 7.1 -12 6 3 0.0 10.3
-11 10 1 0.0 12.3 -11 2 6 0.0 3.8 -12 6 2 26.8 28.0
-11 10 0 39.5 39.2 -11 2 5 0.0 6.1 -12 6 1 0.0 15.3
-11 9 7 0.0 19.8 -11 2 4 0.0 18.3 -12 6 0 21.4 21.8
-11 9 6 0.0 0.9 -11 2 3 0.0 16.8 -12 5 6 0.0 7.4
-11 9 5 29.1 28.0 -11 2 2 0.0 7.9 -12 5 5 0.0 19.0
-11 9 4 0.0 19.5 -11 2 1 0.0 8.8 -12 5 4 0.0 3.4
-11 9 3 29.0 27.7 -11 2 0 0.0 19.3 -12 5 3 0.0 9.5
-11 9 2 0.0 10.4 -11 1 6 0.0 18.2 -12 5 2 0.0 8.3
-11 9 1 34.4 34.9 -11 1 5 0.0 23.1 -12 5 1 23.0 21.3
-11 9 0 0.0 13.4 -11 1 4 0.0 8.7 -12 5 0 0.0 4.7
-11 8 7 0.0 2.6 -11 1 3 34.3 33.5 -12 4 6 0.0 33.3
-11 8 6 0.0 26.8 -11 1 2 27.8 29.6 -12 4 5 0.0 2.6
-11 8 5 0.0 5.2 -11 1 1 30.4 30.8 -12 4 4 0.0 20.5
-11 8 4 0.0 5.8 -11 1 0 0.0 13.0 -12 4 3 0.0 6.7
-11 8 3 0.0 5.2 11 0 6 0.0 15.6 -12 4 2 27.1 28.4
-11 8 2 16.9 15.3 -11 0 5 0.0 15.3 -12 4 1 0.0 5.5
-11 8 1 0.0 5.6 -11 0 4 0.0 2.1 -12 4 0 37.2 35.6
-11 8 0 23.3 23.8 -11 0 3 0.0 17.5 -12 3 6 0.0 8.0
-11 7 7 0.0 3.0 -11 0 2 0.0 0.7 -12 3 5 0.0 11.4
-11 7 6 0.0 4.6 -11 0 1 0.0 18.8 -12 3 4 0.0 11.5
-11 7 5 0.0 7.6 -11 0 0 0.0 11.3 -12 3 3 0.0 12.2
-11 7 4 40.9 40.2 -12 11 5 0.0 8.7 -12 3 2 27.4 27.7
-11 7 3 0.0 0.5 -12 11 4 0.0 5.1 -12 3 1 0.0 14.3
-11 7 2 0.0 3.6 -12 11 3 0.0 8.2 -12 3 0 0.0 26.8
-11 7 1 0.0 7.7 -12 11 2 0.0 3.6 -12 2 5 0.0 12.6
-11 7 0 52.4 49.9 -12 11 1 0.0 9.2 -12 2 4 0.0 9.7
-11 6 7 0.0 19.7 -12 11 0 0.0 0.7 -12 2 3 0.0 17.5
-11 6 6 0.0 11.2 -12 10 6 0.0 8.2 -12 2 2 0.0 0.8
-11 6 5 26.8 27.2 -12 10 5 0.0 14.2 -12 2 1 0.0 18.0
-11 6 4 30.8 29.6 -12 10 4 0.0 20.7 -12 2 0 0.0 10.9
-11 6 3 0.0 20.1 -12 10 3 32.8 31.4 -12 2 6 0.0 1.1
-11 6 2 19.9 20.1 -12 10 2 0.0 11.8 -12 1 5 0.0 2.0
-11 6 1 32.4 32.1 -12 10 1 0.0 22.4 -12 1 4 0.0 17.2
-11 6 0 33.1 32.5 -12 10 0 0.0 23.9 -12 1 3 0.0 2.1
-11 5 7 0.0 8.6 -12 9 6 0.0 5.6 -12 1 2 0.0 27.4
-11 5 6 0.0 9.1 -12 9 5 0.0 5.4 -12 1 1 0.0 0.8
H K L FO FC H K L FO FC H K L FO FC
-12 1 0 25.2 28.4 -13 6 0 0.0 15.3 -14 9 2 0.0 8.2
-12 0 4 0.0 22.7 -13 5 5 0.0 14.5 -14 9 1 28.5 30.2
-12 0 3 0.0 3.0 -13 5 4 0.0 23.6 -14 9 0 0.0 17.7
-12 0 2 0.0 5.5 -13 5 3 0.0 8.2 -14 8 4 0.0 13.3
-12 0 1 0.0 5.5 -13 5 2 0.0 5.7 -14 8 3 0.0 2.0
-12 0 0 35.5 36.4 -13 5 1 0.0 15.3 -14 8 2 0.0 6.6
-13 12 3 0.0 6.0 -13 5 0 28.4 30.6 -14 8 1 0.0 6.4
-13 12 2 0.0 20.7 13 -4 5 0.0 0.6 -14 8 0 0.0 7.7
-13 12 1 0.0 0.7 -13 4 4 0.0 2.1 -14 7 4 0.0 1.8
-13 12 0 0.0 13.9 -13 4 3 0.0 6.2 -14 7 3 0.0 13.6
-13 12 4 0.0 10.4 -13 4 2 0.0 10.9 -14 7 2 0.0 26.5
-13 11 4 0.0 2.1 -13 4 1 0.0 3.7 -14 7 1 0.0 18.2
-13 11 3 0.0 10.9 -13 4 0 0.0 14.5 -14 7 0 0.0 8.0
-13 11 2 0.0 31.5 -13 3 4 0.0 22.5 -14 6 3 0.0 15.2
-13 11 1 0.0 12.5 -13 3 3 0.0 8.3 -14 6 2 0.0 7.1
-13 11 0 0.0 1.6 -13 3 2 0.0 15.1 -14 6 1 0.0 22.8
-13 10 5 0.0 14.5 -13 3 1 0.0 6.2 -14 6 0 0.0 16.3
-13 10 4 0.0 0.8 -13 3 0 0.0 22.2 -14 6 4 0.0 14.1
-13 10 3 0.0 15.5 -13 3 5 0.0 4.5 -14 5 3 0.0 2.8
-13 10 2 0.0 5.6 -13 2 3 0.0 14.8 -14 5 2 0.0 15.9
-13 10 1 0.0 17.0 -13 2 2 0.0 12.4 -14 5 1 0.0 0.9
-13 10 0 0.0 8.9 -13 2 1 0.0 7.3 -14 5 0 0.0 20.5
-13 9 5 0.0 0.5 -13 2 0 0.0 18.9 -14 4 3 0.0 6.6
-13 9 4 0.0 2.3 -13 2 4 0.0 15.4 -14 4 2 0.0 22.4
-13 9 3 0.0 7.5 13 -1 3 0.0 14.0 -14 4 1 0.0 0.9
-13 9 2 0.0 11.1 -13 1 2 0.0 0.1 -14 4 0 0.0 4.8
-13 9 1 0.0 1.0 -13 1 1 0.0 9.6 -14 3 1 0.0 8.9
-13 9 0 0.0 5.0 -13 1 0 0.0 6.1 -14 3 0 0.0 4.2
-13 8 5 0.0 0.2 13 0 2 0.0 0.4 -15 10 2 0.0 3.8
-13 8 4 0.0 6.6 -13 0 1 0.0 0.1 -15 10 1 0.0 1.7
-13 8 3 0.0 0.7 -13 0 0 0.0 6.3 -15 10 0 0.0 12.3
-13 8 2 0.0 26.7 14-12 1 0.0 3.4 -15 9 2 0.0 6.2
-13 8 1 0.0 0.6 14-12 0 0.0 10.6 -15 9 1 0.0 4.6
-13 8 0 0.0 12.1 -14 12 2 0.0 4.3 -15 9 0 0.0 22.8
-13 7 5 0.0 15.5 -14 11 3 0.0 1.1 -15 8 2 0.0 8.5
-13 7 4 0.0 2.2 -14 11 2 0.0 4.2 -15 8 1 0.0 7.4
-13 7 3 0.0 15.6 -14 11 1 0.0 3.7 -15 8 0 0.0 3.4
-13 7 2 0.0 7.4 -14 11 0 0.0 0.3 -15 7 2 0.0 25.5
-13 7 1 0.0 17.7 -14 10 4 0.0 3.3 -15 7 1 0.0 0.4
-13 7 0 0.0 19.2 -14 10 3 0.0 2.7 -15 7 0 0.0 19.3
-13 6 5 0.0 5.6 -14 10 2 0.0 26.3 -15 6 2 0.0 17.2
-13 6 4 0.0 17.2 -14 10 1 0.0 1.5 -15 6 1 0.0 11.1
-13 6 3 0.0 9.7 -14 10 0 0.0 12.5 -15 6 0 0.0 19.3
-13 6 2 0.0 9.9 -14 9 4 0.0 16.2 0 0 0 0.0 0.0
-13 6 1 0.0 9.1 -14 9 3 0.0 23.9 0 0 0 0.0 0.0
Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:
Uptake, Site Preference and
Degradation of Monoclinic Structure
Michael E. Fleet, Xioayang Liu
and Yuanming Pan
Deposited Material
Table 5. List of observed and calculated structure factors
(b) P63/m structure of Nd-chlorapatite
H K L FO FC H K L FO FC H K L FO FC
0 0 2 104.1 105.3 -3 1 5 58.1 58.0 -4 0 5 13.5 13.1
0 0 4 204.3 200.3 -3 1 4 29.2 29.5 -4 0 4 14.1 15.1
0 0 6 95.2 95.2 -3 1 3 82.1 82.9 -4 0 3 0.0 3.2
0 0 8 77.8 74.5 -3 1 2 9.6 8.3 -4 0 2 54.8 54.5
0 0 10 35.5 36.5 -3 1 1 98.2 98.7 -4 0 1 12.5 12.7
-1 0 11 0.0 4.6 -3 1 0 44.9 44.9 -4 0 0 28.7 29.0
-1 0 10 0.0 10.6 -3 0 11 0.0 2.2 -5 4 9 0.0 4.9
-1 0 9 0.0 2.1 -3 0 10 0.0 2.9 -5 4 8 25.5 27.0
-1 0 8 0.0 14.2 -3 0 9 0.0 5.0 -5 4 7 0.0 6.4
-1 0 7 0.0 4.6 -3 0 8 33.1 32.9 -5 4 6 0.0 16.1
-1 0 6 18.4 19.1 -3 0 7 0.0 8.8 -5 4 5 0.0 0.7
-1 0 5 0.0 7.8 -3 0 6 0.0 9.2 -5 4 4 50.5 50.3
-1 0 4 22.3 22.5 -3 0 5 10.0 9.8 -5 4 3 17.6 18.4
-1 0 3 0.0 4.5 -3 0 4 75.1 75.2 -5 4 2 29.8 30.2
-1 0 2 0.0 0.9 -3 0 3 24.3 24.3 -5 4 1 0.0 4.1
-1 0 1 15.7 15.8 -3 0 2 41.6 40.7 -5 4 0 68.7 68.9
-1 0 0 14.1 14.0 -3 0 1 26.5 25.9 -5 4 10 0.0 7.6
-2 1 11 0.0 1.1 -3 0 0 156.5 155.1 -5 3 9 0.0 17.4
-2 1 10 0.0 28.6 -4 3 11 0.0 11.3 -5 3 8 19.8 20.8
-2 1 9 0.0 7.0 4 -3 10 0.0 16.6 -5 3 7 19.7 19.8
-2 1 8 0.0 2.1 -4 3 9 0.0 12.0 -5 3 6 0.0 6.1
-2 1 7 0.0 4.5 -4 3 8 0.0 11.4 -5 3 5 48.7 48.9
-2 1 6 64.1 62.9 -4 3 7 24.2 23.5 -5 3 4 37.3 38.5
-2 1 5 10.8 11.5 -4 3 6 42.3 44.0 -5 3 3 19.0 19.5
-2 1 4 9.6 9.4 -4 3 5 26.2 25.9 -5 3 2 13.3 13.2
-2 1 3 42.9 42.4 -4 3 4 0.0 6.5 -5 3 1 63.7 64.2
-2 1 2 113.0 113.5 -4 3 3 38.2 38.3 -5 3 0 60.2 59.6
-2 1 1 12.5 12.3 -4 3 2 31.4 30.7 -5 3 10 0.0 1.8
-2 1 0 0.0 1.4 -4 3 1 42.1 42.6 -5 2 9 0.0 16.8
-2 0 11 0.0 2.5 -4 3 0 89.8 87.8 -5 2 8 0.0 0.9
-2 0 10 0.0 10.1 -4 2 11 0.0 2.8 -5 2 7 24.7 25.2
-2 0 9 0.0 0.9 -4 2 10 0.0 25.1 -5 2 6 29.4 28.9
-2 0 8 0.0 7.8 -4 2 9 0.0 0.0 -5 2 5 29.3 29.8
-2 0 7 0.0 1.4 -4 2 8 0.0 2.1 -5 2 4 0.0 9.6
-2 0 6 19.0 18.4 -4 2 7 0.0 3.1 -5 2 3 52.4 53.4
-2 0 5 18.1 19.1 -4 2 6 49.7 49.8 -5 2 2 39.1 40.2
-2 0 4 0.0 6.5 -4 2 5 0.0 9.7 -5 2 1 52.5 52.8
-2 0 3 26.3 25.9 -4 2 4 0.0 2.0 -5 2 0 13.8 13.0
-2 0 2 37.9 37.2 -4 2 3 9.4 8.9 -5 2 10 0.0 15.7
-2 0 1 21.9 21.6 -4 2 2 117.2 117.6 -5 1 10 0.0 6.2
-2 0 0 10.2 6.6 -4 2 1 0.0 8.9 -5 1 9 0.0 0.1
-3 2 11 0.0 16.8 -4 2 0 19.6 19.7 -5 1 8 0.0 20.0
-3 2 10 0.0 6.1 -4 1 11 0.0 3.3 -5 1 7 0.0 1.7
-3 2 9 0.0 20.4 -4 1 10 0.0 10.4 -5 1 6 0.0 13.8
-3 2 8 30.8 30.0 -4 1 9 0.0 12.6 -5 1 5 0.0 1.4
-3 2 7 32.8 33.2 -4 1 8 0.0 3.8 -5 1 4 51.6 52.3
-3 2 6 0.0 13.7 -4 1 7 0.0 7.3 -5 1 3 0.0 2.4
-3 2 5 38.5 38.2 -4 1 6 14.4 14.1 -5 1 2 37.1 37.6
-3 2 4 40.2 40.3 -4 1 5 0.0 5.5 -5 1 1 0.0 1.2
-3 2 3 64.5 65.0 -4 1 4 0.0 5.2 -5 1 0 95.1 94.3
-3 2 2 49.5 48.6 -4 1 3 40.6 40.2 -5 0 9 0.0 1.7
-3 2 1 69.5 70.2 -4 1 2 38.2 38.0 -5 0 8 0.0 9.8
-3 2 0 6.0 2.6 -4 1 1 8.7 7.7 -5 0 7 0.0 3.6
-3 1 11 0.0 15.9 -4 1 0 20.6 20.1 -5 0 6 32.6 32.5
-3 1 10 0.0 1.1 -4 0 10 0.0 20.8 -5 0 5 22.7 24.0
-3 1 9 32.6 32.2 -4 0 9 0.0 3.2 -5 0 4 19.1 18.9
-3 1 8 20.8 19.9 -4 0 8 0.0 7.0 -5 0 3 0.0 9.1
-3 1 7 36.4 36.3 -4 0 7 0.0 8.7 -5 0 2 54.4 54.6
-3 1 6 0.0 1.1 -4 0 6 39.2 37.6 -5 0 1 32.5 32.2
H K L FO FC H K L FO FC H K L FO FC
-5 0 0 13.8 13.6 -6 0 6 34.0 34.8 -7 1 8 0.0 15.6
5 0 10 0.0 18.9 -6 0 5 0.0 6.6 -7 1 7 0.0 6.0
-6 5 9 0.0 7.7 -6 0 4 18.1 19.3 -7 1 6 0.0 2.0
-6 5 8 0.0 16.3 -6 0 3 25.8 26.2 -7 1 5 0.0 8.5
-6 5 7 0.0 17.8 -6 0 2 51.5 51.1 -7 1 4 24.3 25.0
-6 5 6 0.0 14.0 -6 0 1 13.0 12.9 -7 1 3 0.0 3.0
-6 5 5 18.4 20.2 -6 0 0 22.2 24.2 -7 1 2 0.0 5.1
-6 5 4 0.0 12.5 -7 6 9 0.0 9.2 -7 1 1 0.0 11.2
-6 5 3 19.0 18.9 -7 6 8 30.0 29.1 -7 1 0 31.0 33.0
-6 5 2 0.0 1.9 -7 6 7 0.0 6.1 -7 0 9 0.0 5.9
-6 5 1 29.6 30.0 -7 6 6 0.0 3.3 -7 0 8 0.0 4.7
-6 5 0 0.0 2.5 -7 6 5 0.0 13.4 -7 0 7 0.0 7.7
6 -5 10 0.0 7.3 -7 6 4 40.5 41.3 -7 0 6 26.4 24.9
-6 4 9 0.0 19.9 -7 6 3 14.5 15.9 -7 0 5 0.0 0.9
-6 4 8 30.6 31.2 -7 6 2 32.1 32.9 -7 0 4 0.0 12.1
-6 4 7 0.0 18.6 -7 6 1 20.0 20.7 -7 0 3 19.4 21.1
-6 4 6 16.4 15.9 -7 6 0 29.2 30.0 -7 0 2 36.4 36.2
-6 4 5 23.3 23.3 7 -6 10 0.0 3.1 -7 0 1 0.0 4.4
-6 4 4 48.0 47.6 -7 5 9 0.0 6.9 -7 0 0 16.7 15.4
-6 4 3 46.7 47.5 -7 5 8 0.0 5.0 -8 7 8 32.2 33.0
-6 4 2 37.0 36.7 -7 5 7 0.0 8.1 -8 7 7 0.0 10.1
-6 4 1 32.1 32.8 -7 5 6 24.6 25.3 -8 7 6 0.0 2.6
-6 4 0 59.0 58.9 -7 5 5 0.0 9.7 -8 7 5 0.0 2.1
6 -4 10 0.0 4.7 -7 5 4 0.0 7.6 -8 7 4 55.4 54.3
-6 3 9 0.0 9.5 -7 5 3 0.0 12.1 -8 7 3 25.5 26.0
-6 3 8 0.0 12.4 -7 5 2 84.8 83.8 -8 7 2 0.0 3.0
-6 3 7 0.0 17.9 -7 5 1 0.0 13.0 -8 7 1 0.0 10.6
-6 3 6 31.0 31.3 -7 5 0 46.9 47.6 -8 7 0 68.2 66.9
-6 3 5 29.3 29.5 -7 4 9 0.0 1.5 8 -7 9 0.0 7.8
-6 3 4 27.6 27.5 -7 4 8 0.0 12.5 -8 6 9 0.0 1.2
-6 3 3 16.3 15.9 -7 4 7 0.0 2.2 -8 6 8 0.0 20.6
-6 3 2 51.3 52.4 -7 4 6 40.6 39.6 -8 6 7 0.0 2.9
-6 3 1 40.8 40.8 -7 4 5 0.0 8.2 -8 6 6 0.0 1.8
-6 3 0 39.8 39.7 -7 4 4 28.5 28.0 -8 6 5 0.0 0.3
6 -3 10 0.0 16.2 -7 4 3 0.0 2.2 -8 6 4 29.1 28.3
-6 2 9 0.0 6.5 -7 4 2 60.7 60.6 -8 6 3 0.0 4.1
-6 2 8 35.6 35.7 -7 4 1 0.0 10.0 -8 6 2 0.0 12.2
-6 2 7 0.0 15.0 -7 4 0 38.9 39.7 -8 6 1 0.0 2.7
-6 2 6 0.0 4.1 -7 3 9 0.0 14.5 -8 6 0 18.6 17.8
-6 2 5 15.5 16.2 -7 3 8 0.0 12.3 -8 5 9 0.0 2.7
-6 2 4 43.7 43.8 -7 3 7 26.2 26.4 -8 5 8 0.0 12.7
-6 2 3 25.7 26.1 -7 3 6 0.0 9.3 -8 5 7 0.0 4.3
-6 2 2 47.1 47.3 -7 3 5 22.3 22.4 -8 5 6 40.3 39.4
-6 2 1 29.5 29.6 -7 3 4 18.5 20.0 -8 5 5 0.0 6.8
-6 2 0 11.5 11.8 -7 3 3 52.8 52.8 -8 5 4 25.8 25.5
-6 1 9 0.0 29.0 -7 3 2 0.0 0.4 -8 5 3 0.0 7.5
-6 1 8 36.5 36.1 -7 3 1 41.8 42.4 -8 5 2 53.3 52.6
-6 1 7 33.4 33.2 -7 3 0 16.2 16.3 -8 5 1 0.0 8.9
-6 1 6 0.0 10.3 -7 2 9 0.0 15.0 -8 5 0 36.2 35.9
-6 1 5 52.8 51.8 -7 2 8 0.0 17.6 -8 4 9 0.0 4.3
-6 1 4 52.8 52.6 -7 2 7 21.7 21.7 -8 4 8 34.2 36.7
-6 1 3 59.5 59.3 -7 2 6 0.0 5.6 -8 4 7 0.0 12.2
-6 1 2 47.4 47.9 -7 2 5 21.4 21.9 -8 4 6 0.0 4.0
-6 1 1 71.9 71.5 -7 2 4 40.0 40.2 -8 4 5 25.4 24.8
-6 1 0 44.7 44.6 -7 2 3 37.7 38.0 -8 4 4 62.4 63.1
-6 0 10 0.0 17.7 -7 2 2 29.7 29.9 -8 4 3 0.0 8.1
-6 0 9 0.0 8.7 -7 2 1 33.3 34.9 -8 4 2 0.0 5.2
-6 0 8 0.0 9.8 -7 2 0 75.7 77.5 -8 4 1 32.4 32.8
-6 0 7 0.0 14.3 -7 1 9 0.0 1.1 -8 4 0 78.8 77.2
H K L FO FC H K L FO FC H K L FO FC
-8 3 9 0.0 3.4 -9 6 5 20.1 21.1 -9 0 1 23.2 23.4
-8 3 8 0.0 2.5 -9 6 4 0.0 1.3 -9 0 0 17.9 18.8
-8 3 7 0.0 9.7 -9 6 3 0.0 2.1 -10 9 7 0.0 10.6
-8 3 6 0.0 16.1 -9 6 2 57.9 57.0 -10 9 6 0.0 1.4
-8 3 5 0.0 3.5 -9 6 1 21.5 22.7 -10 9 5 0.0 9.2
-8 3 4 0.0 1.0 -9 6 0 0.0 1.0 -10 9 4 0.0 13.6
-8 3 3 18.6 18.7 -9 5 9 0.0 9.3 -10 9 3 20.2 20.5
-8 3 2 20.2 20.5 -9 5 8 0.0 11.3 -10 9 2 0.0 0.9
-8 3 1 0.0 10.2 -9 5 7 0.0 9.0 -10 9 1 0.0 12.9
-8 3 0 0.0 0.7 -9 5 6 0.0 7.5 -10 9 0 15.8 15.3
-8 2 8 0.0 3.5 -9 5 5 20.7 21.1 10 -9 8 0.0 9.8
-8 2 7 0.0 4.0 -9 5 4 0.0 13.3 -10 8 7 0.0 9.1
-8 2 6 0.0 12.0 -9 5 3 0.0 16.9 -10 8 6 0.0 20.9
-8 2 5 0.0 11.3 -9 5 2 0.0 0.8 -10 8 5 0.0 12.6
-8 2 4 0.0 3.6 -9 5 1 25.5 26.0 -10 8 4 0.0 8.1
-8 2 3 0.0 6.5 -9 5 0 0.0 9.9 -10 8 3 16.5 16.0
-8 2 2 18.3 19.1 -9 4 8 0.0 14.3 -10 8 2 48.3 47.8
-8 2 1 0.0 11.2 -9 4 7 0.0 8.3 -10 8 1 17.6 17.1
-8 2 0 0.0 7.4 -9 4 6 0.0 17.0 -10 8 0 26.2 26.0
-8 1 8 0.0 10.4 -9 4 5 0.0 14.7 10 -8 8 0.0 1.6
-8 1 7 0.0 8.7 -9 4 4 0.0 7.5 -10 7 8 0.0 6.4
-8 1 6 0.0 15.0 -9 4 3 0.0 14.4 -10 7 7 0.0 7.7
-8 1 5 0.0 11.4 -9 4 2 0.0 0.6 -10 7 6 0.0 18.4
-8 1 4 26.3 26.7 -9 4 1 18.1 18.1 -10 7 5 0.0 13.0
-8 1 3 0.0 8.8 -9 4 0 13.3 12.8 -10 7 4 0.0 1.1
-8 1 2 42.3 42.1 -9 3 8 0.0 3.5 -10 7 3 0.0 7.7
-8 1 1 14.1 13.9 -9 3 7 34.8 33.6 -10 7 2 0.0 10.8
-8 1 0 47.7 46.6 -9 3 6 42.5 42.0 -10 7 1 0.0 15.0
-8 0 8 0.0 15.5 -9 3 5 44.3 43.5 -10 7 0 15.5 12.5
-8 0 7 0.0 2.4 -9 3 4 0.0 3.6 -10 6 9 0.0 3.2
-8 0 6 50.6 47.8 -9 3 3 45.9 45.1 -10 6 8 0.0 13.3
-8 0 5 0.0 3.0 -9 3 2 67.0 65.4 -10 6 7 0.0 3.9
-8 0 4 35.5 35.4 -9 3 1 60.0 59.4 -10 6 6 0.0 0.9
-8 0 3 0.0 4.8 -9 3 0 0.0 3.0 -10 6 5 0.0 2.9
-8 0 2 54.5 54.5 -9 2 8 0.0 17.8 -10 6 4 0.0 18.7
-8 0 1 0.0 1.0 -9 2 7 0.0 12.9 -10 6 3 0.0 2.0
-8 0 0 57.5 55.6 -9 2 6 0.0 0.5 -10 6 2 0.0 2.7
-9 8 8 0.0 7.8 -9 2 5 0.0 15.9 -10 6 1 0.0 0.2
-9 8 7 0.0 5.1 -9 2 4 0.0 22.1 -10 6 0 19.2 20.2
-9 8 6 0.0 4.0 -9 2 3 18.7 17.8 -10 5 8 0.0 3.8
-9 8 5 0.0 2.6 -9 2 2 0.0 8.8 -10 5 7 0.0 16.9
-9 8 4 0.0 11.8 -9 2 1 20.2 20.5 -10 5 6 0.0 14.0
-9 8 3 0.0 1.0 -9 2 0 17.0 17.6 -10 5 5 23.4 23.8
-9 8 2 0.0 4.7 -9 1 7 0.0 6.0 -10 5 4 0.0 14.7
-9 8 1 0.0 6.5 -9 1 6 0.0 23.9 -10 5 3 25.7 25.7
-9 8 0 16.4 16.0 -9 1 5 0.0 10.5 -10 5 2 41.4 41.9
-9 7 8 0.0 18.9 -9 1 4 0.0 4.3 -10 5 1 29.6 31.0
-9 7 7 0.0 13.6 -9 1 3 0.0 11.6 -10 5 0 36.9 37.9
-9 7 6 0.0 5.8 -9 1 2 0.0 4.7 -10 4 8 0.0 9.1
-9 7 5 0.0 10.5 -9 1 1 0.0 13.9 -10 4 7 0.0 0.0
-9 7 4 26.2 25.7 -9 1 0 19.2 19.6 -10 4 6 0.0 16.3
-9 7 3 21.0 21.3 9 -1 8 0.0 9.7 -10 4 5 0.0 4.2
-9 7 2 13.8 13.8 -9 0 8 0.0 6.6 -10 4 4 0.0 6.4
-9 7 1 15.9 16.9 -9 0 7 0.0 15.8 -10 4 3 0.0 2.7
-9 7 0 26.6 27.4 -9 0 6 0.0 22.7 -10 4 2 0.0 6.5
9 -7 9 0.0 8.1 -9 0 5 0.0 15.1 -10 4 1 0.0 4.5
-9 6 8 0.0 1.2 -9 0 4 0.0 11.3 -10 4 0 0.0 6.8
-9 6 7 0.0 9.3 -9 0 3 28.0 27.0 -10 3 7 0.0 13.8
-9 6 6 39.7 40.2 -9 0 2 38.9 38.3 -10 3 6 0.0 1.7
H K L FO FC H K L FO FC H K L FO FC
-10 3 5 0.0 4.2 -11 7 7 0.0 2.9 -11 1 1 32.2 31.1
-10 3 4 0.0 17.5 -11 7 6 0.0 1.8 -11 1 0 0.0 12.9
-10 3 3 23.4 25.4 -11 7 5 0.0 6.8 -11 0 7 0.0 8.3
-10 3 2 0.0 1.2 -11 7 4 41.9 41.7 -11 0 6 0.0 15.0
-10 3 1 0.0 11.2 -11 7 3 0.0 0.7 -11 0 5 0.0 14.0
-10 3 0 22.5 22.4 -11 7 2 0.0 1.4 -11 0 4 0.0 2.6
10 -3 8 0.0 11.0 -11 7 1 0.0 7.1 -11 0 3 0.0 16.1
-10 2 7 0.0 1.3 -11 7 0 52.6 50.9 -11 0 2 0.0 3.1
-10 2 6 0.0 9.4 -11 6 8 0.0 18.5 -11 0 1 0.0 17.3
-10 2 5 0.0 0.7 -11 6 7 0.0 18.8 -11 0 0 0.0 8.8
-10 2 4 26.6 26.7 -11 6 6 0.0 10.3 -12 11 7 0.0 3.2
-10 2 3 0.0 2.0 -11 6 5 0.0 26.9 -12 11 6 0.0 8.9
-10 2 2 0.0 19.5 -11 6 4 30.6 29.6 -12 11 5 0.0 8.1
-10 2 1 0.0 0.5 -11 6 3 0.0 20.6 -12 11 4 0.0 4.4
-10 2 0 39.7 38.7 -11 6 2 0.0 17.8 -12 11 3 0.0 8.1
10 -2 8 0.0 15.0 -11 6 1 32.9 32.2 -12 11 2 0.0 6.4
-10 1 7 0.0 18.6 -11 6 0 33.0 33.3 -12 11 1 0.0 8.7
-10 1 6 0.0 0.9 -11 5 8 0.0 6.5 -12 11 0 0.0 1.1
-10 1 5 0.0 13.6 -11 5 7 0.0 9.1 -12 10 7 0.0 15.6
-10 1 4 0.0 18.3 -11 5 6 0.0 8.9 -12 10 6 0.0 7.2
-10 1 3 29.0 28.6 -11 5 5 0.0 7.6 -12 10 5 0.0 12.8
-10 1 2 0.0 3.6 -11 5 4 0.0 8.5 -12 10 4 0.0 21.0
-10 1 1 22.9 21.9 -11 5 3 0.0 17.5 -12 10 3 31.3 28.8
-10 1 0 0.0 15.8 -11 5 2 0.0 7.2 -12 10 2 0.0 9.7
-10 0 8 0.0 10.7 -11 5 1 0.0 11.7 -12 10 1 20.7 20.5
-10 0 7 0.0 0.4 -11 5 0 0.0 3.9 -12 10 0 23.8 24.9
-10 0 6 0.0 0.7 -11 4 7 0.0 8.2 -12 9 8 0.0 14.2
-10 0 5 0.0 5.5 -11 4 6 0.0 7.7 -12 9 7 0.0 4.7
-10 0 4 0.0 12.8 -11 4 5 0.0 7.7 -12 9 6 0.0 7.7
-10 0 3 0.0 5.1 -11 4 4 30.3 30.8 -12 9 5 0.0 5.9
-10 0 2 0.0 2.0 -11 4 3 0.0 10.7 -12 9 4 0.0 22.6
-10 0 1 0.0 4.4 -11 4 2 0.0 11.6 -12 9 3 0.0 8.3
-10 0 0 0.0 13.2 -11 4 1 0.0 11.9 -12 9 2 0.0 14.1
-11 10 7 0.0 7.2 -11 4 0 37.6 36.8 -12 9 1 0.0 8.3
-11 10 6 0.0 4.0 11 -4 8 0.0 19.3 -12 9 0 31.4 30.1
-11 10 5 0.0 11.0 -11 3 7 0.0 12.7 -12 8 8 0.0 7.0
-11 10 4 27.6 30.8 -11 3 6 0.0 12.7 -12 8 7 0.0 7.4
-11 10 3 0.0 12.2 -11 3 5 0.0 14.7 -12 8 6 0.0 19.9
-11 10 2 0.0 7.6 -11 3 4 0.0 0.6 -12 8 5 0.0 19.7
-11 10 1 0.0 12.6 -11 3 3 0.0 13.1 -12 8 4 0.0 10.3
-11 10 0 41.2 39.7 -11 3 2 0.0 9.3 -12 8 3 0.0 11.3
-11 9 7 0.0 19.6 -11 3 1 0.0 20.3 -12 8 2 25.5 26.7
-11 9 6 0.0 0.6 -11 3 0 0.0 4.3 -12 8 1 0.0 20.9
-11 9 5 0.0 27.7 11 -3 8 0.0 4.3 -12 8 0 0.0 12.1
-11 9 4 0.0 20.9 -11 2 7 0.0 7.1 -12 7 8 0.0 5.8
-11 9 3 27.6 28.2 -11 2 6 0.0 2.9 -12 7 7 0.0 0.2
-11 9 2 0.0 9.6 -11 2 5 0.0 6.6 -12 7 6 0.0 8.3
-11 9 1 35.6 35.0 -11 2 4 0.0 17.8 -12 7 5 0.0 3.0
-11 9 0 0.0 16.0 -11 2 3 0.0 16.9 -12 7 4 0.0 4.7
-11 8 8 0.0 1.1 -11 2 2 0.0 5.7 -12 7 3 0.0 3.3
-11 8 7 0.0 2.6 -11 2 1 0.0 9.4 -12 7 2 0.0 5.5
-11 8 6 0.0 25.6 -11 2 0 17.5 19.8 -12 7 1 0.0 3.2
-11 8 5 0.0 5.3 11 -2 8 0.0 12.4 -12 7 0 0.0 2.4
-11 8 4 0.0 5.0 -11 1 7 0.0 19.0 -12 6 7 0.0 7.9
-11 8 3 0.0 5.1 -11 1 6 0.0 20.8 -12 6 6 0.0 16.8
-11 8 2 0.0 16.7 -11 1 5 0.0 23.0 -12 6 5 0.0 11.8
-11 8 1 0.0 5.8 -11 1 4 0.0 9.6 -12 6 4 0.0 14.6
-11 8 0 23.0 21.3 -11 1 3 32.9 33.4 -12 6 3 0.0 9.3
-11 7 8 0.0 25.6 -11 1 2 32.0 31.8 -12 6 2 28.7 29.6
H K L FO FC H K L FO FC H K L FO FC
-12 6 1 0.0 14.2 -13 11 3 0.0 11.9 -13 3 6 0.0 7.4
-12 6 0 19.8 22.3 -13 11 2 0.0 32.2 -13 3 5 0.0 5.2
-12 5 7 0.0 9.7 -13 11 1 0.0 13.4 -13 3 4 0.0 22.8
-12 5 6 0.0 7.2 -13 11 0 0.0 0.4 -13 3 3 0.0 8.9
-12 5 5 0.0 18.2 -13 10 7 0.0 9.7 -13 3 2 0.0 13.4
-12 5 4 0.0 4.6 -13 10 6 0.0 10.2 -13 3 1 0.0 7.0
-12 5 3 0.0 9.3 -13 10 5 0.0 14.3 -13 3 0 0.0 23.8
-12 5 2 0.0 9.2 -13 10 4 0.0 1.3 13 -3 7 0.0 6.5
-12 5 1 20.3 20.6 -13 10 3 0.0 15.4 -13 2 6 0.0 10.6
-12 5 0 0.0 6.6 -13 10 2 0.0 6.2 -13 2 4 0.0 16.7
-12 4 7 0.0 4.0 -13 10 1 0.0 17.1 -13 2 3 0.0 15.5
-12 4 6 34.8 32.9 -13 10 0 0.0 4.8 -13 2 2 0.0 14.2
-12 4 5 0.0 2.3 -13 9 7 0.0 0.4 -13 2 1 0.0 8.8
-12 4 4 0.0 19.9 -13 9 6 0.0 10.4 -13 2 0 0.0 19.7
-12 4 3 0.0 6.0 -13 9 5 0.0 0.3 13 -2 5 0.0 5.6
-12 4 2 31.0 31.0 -13 9 4 0.0 1.3 -13 1 6 0.0 3.7
-12 4 1 0.0 4.7 -13 9 3 0.0 6.2 -13 1 4 0.0 8.4
-12 4 0 35.7 33.7 -13 9 2 0.0 12.1 -13 1 3 0.0 12.3
-12 3 7 0.0 8.1 -13 9 1 0.0 0.0 -13 1 2 0.0 1.6
-12 3 6 0.0 9.8 -13 9 0 0.0 2.9 -13 1 1 0.0 8.5
-12 3 5 0.0 10.7 -13 8 7 0.0 0.4 -13 1 0 0.0 7.1
-12 3 4 0.0 14.9 -13 8 6 0.0 15.7 13 -1 5 0.0 4.4
-12 3 3 0.0 11.5 -13 8 5 0.0 0.3 -13 0 3 0.0 2.8
-12 3 2 28.5 27.7 -13 8 4 0.0 9.6 -13 0 2 0.0 2.0
-12 3 1 0.0 13.8 -13 8 3 0.0 0.6 -13 0 1 0.0 0.5
-12 3 0 29.1 28.7 -13 8 2 26.5 26.6 -13 0 0 0.0 7.2
-12 2 7 0.0 11.2 -13 8 1 0.0 0.8 13 0 4 0.0 7.3
-12 2 6 0.0 1.5 -13 8 0 0.0 14.9 13 0 5 0.0 0.1
-12 2 5 0.0 11.9 -13 7 7 0.0 10.5 -14 13 1 0.0 13.2
-12 2 4 0.0 10.3 -13 7 6 0.0 17.9 -14 13 0 0.0 8.8
-12 2 3 0.0 16.1 -13 7 5 0.0 15.4 -14 13 2 0.0 23.5
-12 2 2 0.0 2.2 -13 7 4 0.0 1.1 -14 12 3 0.0 6.7
-12 2 1 0.0 17.1 -13 7 3 0.0 15.9 -14 12 2 0.0 2.7
-12 2 0 0.0 12.2 -13 7 2 0.0 8.9 -14 12 1 0.0 3.6
-12 1 7 0.0 1.9 -13 7 1 0.0 18.1 -14 12 0 0.0 11.8
-12 1 6 0.0 26.0 -13 7 0 0.0 15.9 -14 11 5 0.0 2.7
-12 1 5 0.0 1.8 -13 6 7 0.0 9.3 -14 11 4 0.0 9.7
-12 1 4 0.0 14.9 -13 6 5 0.0 6.6 -14 11 3 0.0 0.2
-12 1 3 0.0 2.3 -13 6 4 0.0 17.8 -14 11 2 0.0 2.8
-12 1 2 27.4 27.7 -13 6 3 0.0 10.4 -14 11 1 0.0 2.3
-12 1 1 0.0 0.4 -13 6 2 0.0 8.7 -14 11 0 0.0 2.5
-12 1 0 25.2 24.9 -13 6 1 0.0 10.3 -14 10 6 0.0 13.7
-12 0 6 0.0 3.4 -13 6 0 0.0 17.3 -14 10 5 0.0 1.0
-12 0 5 0.0 5.2 13 -6 6 0.0 2.6 -14 10 4 0.0 5.5
-12 0 4 0.0 25.2 -13 5 6 0.0 4.5 -14 10 3 0.0 1.8
-12 0 3 0.0 3.2 -13 5 5 0.0 12.4 -14 10 2 0.0 27.5
-12 0 2 0.0 6.0 -13 5 4 0.0 25.0 -14 10 1 0.0 0.8
-12 0 1 0.0 5.5 -13 5 3 0.0 6.7 -14 10 0 0.0 13.4
-12 0 0 34.0 38.0 -13 5 2 0.0 7.5 -14 9 6 0.0 4.8
-13 12 6 0.0 15.7 -13 5 1 0.0 12.9 -14 9 5 0.0 24.3
-13 12 5 0.0 0.5 -13 5 0 32.4 31.8 -14 9 4 0.0 16.8
-13 12 4 0.0 9.3 -13 4 6 0.0 17.8 -14 9 3 0.0 23.4
-13 12 3 0.0 5.3 -13 4 5 0.0 0.9 -14 9 2 0.0 6.8
-13 12 2 0.0 21.8 -13 4 4 0.0 1.5 -14 9 1 29.4 29.2
-13 12 1 0.0 0.7 -13 4 3 0.0 5.7 -14 9 0 0.0 18.9
-13 12 0 0.0 11.9 -13 4 2 0.0 12.7 -14 8 4 0.0 14.4
-13 11 6 0.0 23.2 -13 4 1 0.0 3.7 -14 8 3 0.0 2.6
-13 11 5 0.0 12.4 -13 4 0 0.0 12.6 -14 8 2 0.0 5.3
-13 11 4 0.0 0.3 13 -4 7 0.0 4.2 -14 8 1 0.0 6.8
H K L FO FC H K L FO FC H K L FO FC
-14 8 0 0.0 10.0 -14 4 3 0.0 6.8 15-10 3 0.0 0.8
14 -8 5 0.0 6.8 -14 4 2 0.0 23.8 -15 10 2 0.0 2.3
-14 7 5 0.0 15.3 -14 4 1 0.0 0.3 -15 10 1 0.0 2.8
-14 7 4 0.0 3.7 -14 4 0 0.0 6.3 -15 10 0 0.0 13.5
-14 7 3 0.0 13.9 -14 3 3 0.0 9.1 -15 9 3 0.0 1.4
-14 7 2 0.0 28.2 -14 3 2 0.0 1.1 -15 9 2 0.0 8.4
-14 7 1 0.0 17.8 -14 3 1 0.0 8.9 -15 9 1 0.0 6.2
-14 7 0 0.0 9.0 -14 3 0 0.0 7.2 -15 9 0 0.0 22.7
-14 6 4 0.0 15.0 14 -3 4 0.0 8.2 -15 8 3 0.0 0.4
-14 6 3 0.0 14.3 -14 2 2 0.0 6.7 -15 8 2 0.0 9.7
-14 6 2 0.0 5.7 -14 2 1 0.0 0.7 -15 8 1 0.0 6.7
-14 6 1 0.0 21.3 -14 2 0 0.0 9.0 -15 8 0 0.0 1.6
-14 6 0 0.0 18.1 14 -2 3 0.0 1.8 -15 7 3 0.0 2.2
14 -6 5 0.0 17.0 14 -2 5 0.0 0.1 -15 7 2 0.0 26.0
14 -6 6 0.0 4.2 14 -1 1 0.0 14.2 -15 7 1 0.0 0.6
-14 5 4 0.0 20.9 14 0 1 0.0 8.2 -15 7 0 0.0 16.5
-14 5 3 0.0 1.7 14 0 0 0.0 10.0 -15 6 2 0.0 18.3
-14 5 2 0.0 13.8 -15 12 0 0.0 25.9 -15 6 1 0.0 11.4
-14 5 1 0.0 0.2 -15 12 1 0.0 4.1 -15 6 0 0.0 19.5
-14 5 0 0.0 21.7 15-11 3 0.0 3.0 -15 5 1 0.0 2.7
14 -5 5 0.0 1.6 15-11 2 0.0 10.8 -15 5 0 0.0 5.5
-14 4 5 0.0 1.8 15-11 1 0.0 5.6 0 0 0 0.0 0.0
-14 4 4 0.0 4.9 -15 11 0 0.0 6.2 0 0 0 0.0 0.0
Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:
Uptake, Site Preference and
Degradation of Monoclinic Structure
Michael E. Fleet, Xioayang Liu
and Yuanming Pan
Deposited Material
Table 5. List of observed and calculated structure factors
(c) P63/m structure of Sm-chlorapatite
H K L FO FC H K L FO FC H K L FO FC
0 0 2 102.4 102.5 -3 1 5 59.7 59.3 -4 0 6 38.6 38.2
0 0 4 211.3 204.9 -3 1 4 29.3 29.2 -4 0 5 13.4 14.3
0 0 6 98.6 98.1 -3 1 3 83.1 82.6 -4 0 4 14.7 14.7
0 0 8 80.8 79.2 -3 1 2 10.2 9.2 -4 0 3 0.0 3.0
0 0 10 40.6 42.4 -3 1 1 97.5 98.3 -4 0 2 53.4 53.7
-1 0 11 0.0 5.1 -3 1 0 43.3 44.9 -4 0 1 12.9 13.3
-1 0 10 0.0 12.1 -3 0 11 0.0 2.6 -4 0 0 26.0 26.7
-1 0 9 0.0 2.4 -3 0 10 0.0 4.3 5 -4 11 0.0 0.6
-1 0 8 15.9 16.1 -3 0 9 0.0 5.7 -5 4 10 0.0 7.8
-1 0 7 0.0 4.7 -3 0 8 35.3 34.4 -5 4 9 0.0 5.7
-1 0 6 19.1 19.3 -3 0 7 0.0 9.5 -5 4 8 26.9 28.2
-1 0 5 0.0 8.1 -3 0 6 8.7 8.6 -5 4 7 0.0 6.6
-1 0 4 23.1 23.1 -3 0 5 9.8 10.4 -5 4 6 16.8 17.8
-1 0 3 5.1 4.6 -3 0 4 78.3 78.0 -5 4 5 0.0 0.9
-1 0 2 0.0 0.5 -3 0 3 25.2 25.1 -5 4 4 52.4 52.1
-1 0 1 16.1 16.2 -3 0 2 44.4 43.4 -5 4 3 18.6 19.1
-1 0 0 15.2 15.6 -3 0 1 27.0 26.4 -5 4 2 32.4 32.8
-2 1 11 0.0 1.5 -3 0 0 153.9 156.4 -5 4 1 0.0 4.1
-2 1 10 29.0 31.0 -4 3 11 0.0 13.0 -5 4 0 67.7 69.3
-2 1 9 0.0 7.5 -4 3 10 0.0 19.0 5 -3 11 0.0 16.7
-2 1 8 0.0 1.9 -4 3 9 0.0 13.6 -5 3 10 0.0 2.0
-2 1 7 0.0 4.6 -4 3 8 12.6 13.2 -5 3 9 0.0 18.8
-2 1 6 66.7 66.0 -4 3 7 24.7 25.2 -5 3 8 22.5 22.9
-2 1 5 12.3 12.8 -4 3 6 44.8 45.3 -5 3 7 20.3 20.7
-2 1 4 11.5 11.2 -4 3 5 27.9 27.4 -5 3 6 0.0 6.7
-2 1 3 42.9 42.2 -4 3 4 0.0 5.9 -5 3 5 50.3 50.5
-2 1 2 115.1 115.7 -4 3 3 39.5 39.4 -5 3 4 38.6 39.2
-2 1 1 12.7 13.0 -4 3 2 29.7 29.5 -5 3 3 18.7 18.7
-2 1 0 3.5 2.7 -4 3 1 43.0 43.7 -5 3 2 13.3 13.3
-2 0 11 0.0 3.3 -4 3 0 88.4 85.8 -5 3 1 64.0 64.3
-2 0 10 0.0 12.1 -4 2 11 0.0 2.8 -5 3 0 60.8 60.5
-2 0 9 0.0 1.0 -4 2 10 24.7 27.3 5 -2 11 0.0 14.7
-2 0 8 0.0 8.4 -4 2 9 0.0 0.4 -5 2 10 0.0 18.6
-2 0 7 0.0 1.0 -4 2 8 0.0 2.7 -5 2 9 0.0 18.1
-2 0 6 20.0 19.9 -4 2 7 0.0 2.6 -5 2 8 0.0 1.0
-2 0 5 19.6 20.1 -4 2 6 52.2 52.1 -5 2 7 24.8 26.3
-2 0 4 0.0 5.3 -4 2 5 9.3 9.5 -5 2 6 31.8 31.0
-2 0 3 26.3 25.6 -4 2 4 0.0 3.7 -5 2 5 29.8 29.9
-2 0 2 38.8 38.5 -4 2 3 9.7 9.6 -5 2 4 11.3 11.2
-2 0 1 22.9 22.7 -4 2 2 120.3 119.0 -5 2 3 52.8 52.7
-2 0 0 6.0 5.3 -4 2 1 7.8 8.2 -5 2 2 40.7 40.8
-3 2 11 0.0 19.5 -4 2 0 20.5 21.7 -5 2 1 51.6 52.0
-3 2 10 0.0 7.2 -4 1 11 0.0 3.9 -5 2 0 14.1 14.3
-3 2 9 21.7 22.7 -4 1 10 0.0 12.3 5 -1 11 0.0 1.5
-3 2 8 32.8 33.2 -4 1 9 0.0 13.9 -5 1 10 0.0 5.4
-3 2 7 35.0 35.2 -4 1 8 0.0 4.1 -5 1 9 0.0 0.4
-3 2 6 14.0 14.5 -4 1 7 0.0 7.8 -5 1 8 19.4 21.2
-3 2 5 39.4 39.3 -4 1 6 14.6 14.9 -5 1 7 0.0 2.7
-3 2 4 41.1 40.9 -4 1 5 0.0 5.8 -5 1 6 14.6 13.9
-3 2 3 65.6 65.3 -4 1 4 0.0 4.5 -5 1 5 0.0 2.3
-3 2 2 50.6 49.4 -4 1 3 41.8 41.2 -5 1 4 54.7 55.2
-3 2 1 69.0 70.1 -4 1 2 38.9 39.0 -5 1 3 0.0 1.0
-3 2 0 0.0 2.4 -4 1 1 9.1 7.6 -5 1 2 38.5 38.9
-3 1 11 0.0 18.3 -4 1 0 20.2 19.9 -5 1 1 0.0 2.8
-3 1 10 0.0 2.1 4 0 11 0.0 8.3 -5 1 0 96.9 97.6
-3 1 9 34.5 35.0 -4 0 10 22.0 23.6 -5 0 10 21.5 21.4
-3 1 8 21.7 21.3 -4 0 9 0.0 3.7 -5 0 9 0.0 2.3
-3 1 7 37.7 38.0 -4 0 8 0.0 6.8 -5 0 8 0.0 10.2
-3 1 6 0.0 0.6 -4 0 7 0.0 9.0 -5 0 7 0.0 4.5
H K L FO FC H K L FO FC H K L FO FC
-5 0 6 34.3 33.7 -6 1 2 48.5 48.6 -7 2 9 0.0 16.7
-5 0 5 24.7 25.7 -6 1 1 72.9 71.9 -7 2 8 18.9 18.8
-5 0 4 19.1 19.4 -6 1 0 44.6 44.8 -7 2 7 22.5 23.3
-5 0 3 7.8 8.4 -6 0 10 0.0 19.0 -7 2 6 0.0 5.5
-5 0 2 54.9 54.8 -6 0 9 0.0 10.7 -7 2 5 21.6 22.1
-5 0 1 33.8 33.5 -6 0 8 0.0 10.0 -7 2 4 43.9 42.8
-5 0 0 12.6 13.1 -6 0 7 16.6 16.5 -7 2 3 38.9 38.9
-6 5 10 0.0 8.8 -6 0 6 36.8 37.0 -7 2 2 30.5 30.5
-6 5 9 0.0 8.4 -6 0 5 0.0 7.9 -7 2 1 34.4 34.6
-6 5 8 17.8 18.4 -6 0 4 19.6 20.5 -7 2 0 79.5 79.8
-6 5 7 17.2 18.8 -6 0 3 28.9 29.2 -7 1 10 0.0 1.0
-6 5 6 13.5 14.9 -6 0 2 54.1 53.4 -7 1 9 0.0 1.6
-6 5 5 19.9 20.5 -6 0 1 14.4 14.7 -7 1 8 14.9 16.6
-6 5 4 11.7 11.8 -6 0 0 23.7 24.6 -7 1 7 0.0 5.2
-6 5 3 18.6 18.7 -7 6 10 0.0 3.2 -7 1 6 0.0 1.5
-6 5 2 0.0 1.5 -7 6 9 0.0 10.1 -7 1 5 0.0 8.1
-6 5 1 29.6 29.9 -7 6 8 31.8 32.4 -7 1 4 23.9 24.2
-6 5 0 0.0 4.2 -7 6 7 0.0 6.0 -7 1 3 0.0 4.7
-6 4 10 0.0 5.1 -7 6 6 0.0 4.0 -7 1 2 0.0 4.2
-6 4 9 20.7 21.6 -7 6 5 12.6 13.7 -7 1 1 9.5 9.8
-6 4 8 34.7 34.5 -7 6 4 42.5 42.2 -7 1 0 31.3 31.6
-6 4 7 19.6 19.7 -7 6 3 13.9 15.3 -7 0 10 0.0 18.3
-6 4 6 16.4 16.8 -7 6 2 33.6 34.2 -7 0 9 0.0 7.1
-6 4 5 24.1 23.7 -7 6 1 19.8 20.1 -7 0 8 0.0 5.3
-6 4 4 49.4 48.8 -7 6 0 30.0 30.5 -7 0 7 0.0 8.2
-6 4 3 47.6 47.9 -7 5 10 0.0 16.6 -7 0 6 26.6 26.5
-6 4 2 38.0 37.9 -7 5 9 0.0 7.0 -7 0 5 0.0 1.5
-6 4 1 32.0 32.7 -7 5 8 0.0 6.2 -7 0 4 13.2 13.6
-6 4 0 59.1 59.2 -7 5 7 0.0 7.7 -7 0 3 21.9 22.1
-6 3 10 0.0 17.2 -7 5 6 25.2 25.8 -7 0 2 36.9 37.0
-6 3 9 0.0 10.1 -7 5 5 0.0 8.7 -7 0 1 0.0 5.0
-6 3 8 0.0 12.6 -7 5 4 9.4 9.2 -7 0 0 16.1 16.5
-6 3 7 18.0 19.0 -7 5 3 10.8 10.6 -8 7 10 0.0 1.2
-6 3 6 33.3 33.1 -7 5 2 86.1 85.7 -8 7 9 0.0 9.2
-6 3 5 30.8 29.8 -7 5 1 11.1 11.2 -8 7 8 35.2 35.0
-6 3 4 29.5 29.7 -7 5 0 50.1 50.6 -8 7 7 0.0 11.5
-6 3 3 16.2 15.7 -7 4 10 24.6 26.0 -8 7 6 0.0 2.2
-6 3 2 53.7 53.8 -7 4 9 0.0 1.8 -8 7 5 0.0 2.0
-6 3 1 40.0 40.4 -7 4 8 0.0 14.7 -8 7 4 57.6 56.4
-6 3 0 41.2 41.5 -7 4 7 0.0 1.7 -8 7 3 26.7 27.7
-6 2 10 0.0 1.0 -7 4 6 44.0 43.0 -8 7 2 0.0 1.9
-6 2 9 0.0 7.7 -7 4 5 0.0 8.5 -8 7 1 10.6 10.9
-6 2 8 40.5 39.6 -7 4 4 30.4 30.6 -8 7 0 69.4 67.8
-6 2 7 16.6 16.5 -7 4 3 0.0 3.4 -8 6 10 0.0 1.9
-6 2 6 0.0 4.2 -7 4 2 62.6 63.1 -8 6 9 0.0 1.3
-6 2 5 17.3 17.6 -7 4 1 9.6 9.6 -8 6 8 22.1 22.8
-6 2 4 45.3 44.7 -7 4 0 41.1 41.7 -8 6 7 0.0 3.5
-6 2 3 27.3 27.5 -7 3 10 0.0 6.2 -8 6 6 0.0 1.5
-6 2 2 49.2 49.2 -7 3 9 0.0 16.4 -8 6 5 0.0 0.4
-6 2 1 30.8 31.0 -7 3 8 14.1 14.2 -8 6 4 29.3 29.0
-6 2 0 11.9 11.6 -7 3 7 27.9 28.0 -8 6 3 0.0 4.7
-6 1 10 0.0 6.5 -7 3 6 0.0 8.6 -8 6 2 13.2 13.1
-6 1 9 30.2 32.1 -7 3 5 22.4 23.2 -8 6 1 0.0 3.1
-6 1 8 40.4 39.7 -7 3 4 20.5 20.8 -8 6 0 18.4 18.2
-6 1 7 35.3 35.4 -7 3 3 53.9 54.1 -8 5 10 0.0 23.7
-6 1 6 0.0 10.8 -7 3 2 0.0 0.9 -8 5 9 0.0 3.2
-6 1 5 54.4 53.8 -7 3 1 42.4 42.5 -8 5 8 0.0 14.5
-6 1 4 54.0 54.0 -7 3 0 17.6 18.0 -8 5 7 0.0 4.8
-6 1 3 60.3 59.6 -7 2 10 0.0 8.5 -8 5 6 43.4 42.4
H K L FO FC H K L FO FC H K L FO FC
-8 5 5 0.0 7.8 -8 0 0 57.0 57.0 -9 3 8 0.0 5.4
-8 5 4 28.1 27.8 8 0 10 27.8 30.6 -9 3 7 36.9 37.5
-8 5 3 0.0 7.4 -9 8 10 0.0 4.1 -9 3 6 45.8 45.2
-8 5 2 54.7 54.6 -9 8 9 0.0 3.7 -9 3 5 47.6 46.7
-8 5 1 8.7 9.7 -9 8 8 0.0 10.0 -9 3 4 0.0 4.5
-8 5 0 38.6 38.0 -9 8 7 0.0 5.5 -9 3 3 49.4 48.3
-8 4 10 0.0 6.2 -9 8 6 0.0 2.2 -9 3 2 71.0 68.7
-8 4 9 0.0 5.2 -9 8 5 0.0 2.6 -9 3 1 63.1 62.1
-8 4 8 39.0 38.7 -9 8 4 12.3 13.6 -9 3 0 0.0 3.7
-8 4 7 0.0 13.9 -9 8 3 0.0 0.9 -9 2 9 0.0 10.8
-8 4 6 0.0 3.6 -9 8 2 0.0 1.9 -9 2 8 17.7 19.4
-8 4 5 26.6 26.9 -9 8 1 0.0 6.4 -9 2 7 0.0 13.4
-8 4 4 66.2 65.1 -9 8 0 17.4 18.3 -9 2 6 0.0 0.8
-8 4 3 8.8 9.0 -9 7 10 0.0 0.8 -9 2 5 14.7 15.7
-8 4 2 0.0 3.0 -9 7 9 0.0 10.0 -9 2 4 20.9 21.3
-8 4 1 33.8 34.5 -9 7 8 23.3 21.4 -9 2 3 18.0 17.6
-8 4 0 79.3 78.4 -9 7 7 0.0 14.8 -9 2 2 0.0 8.7
-8 3 10 0.0 11.3 -9 7 6 0.0 6.7 -9 2 1 19.3 19.9
-8 3 9 0.0 4.0 -9 7 5 0.0 11.8 -9 2 0 15.8 16.3
-8 3 8 0.0 3.9 -9 7 4 27.4 26.4 -9 1 9 0.0 7.1
-8 3 7 0.0 10.9 -9 7 3 22.5 22.9 -9 1 8 0.0 10.7
-8 3 6 14.5 15.6 -9 7 2 16.4 15.9 -9 1 7 0.0 6.7
-8 3 5 0.0 3.6 -9 7 1 17.6 17.9 -9 1 6 26.6 26.1
-8 3 4 0.0 2.2 -9 7 0 27.7 27.5 -9 1 5 0.0 10.8
-8 3 3 19.0 19.7 -9 6 10 0.0 22.1 -9 1 4 0.0 3.4
-8 3 2 18.1 18.4 -9 6 9 0.0 4.5 -9 1 3 10.8 12.2
-8 3 1 10.4 10.6 -9 6 8 0.0 0.6 -9 1 2 0.0 4.5
-8 3 0 0.0 1.2 -9 6 7 0.0 9.2 -9 1 1 13.9 14.2
-8 2 10 0.0 8.7 -9 6 6 42.0 42.4 -9 1 0 21.6 21.6
-8 2 9 0.0 2.5 -9 6 5 21.2 21.4 9 -1 10 0.0 12.8
-8 2 8 0.0 3.8 -9 6 4 0.0 2.0 -9 0 9 0.0 12.5
-8 2 7 0.0 4.2 -9 6 3 0.0 0.3 -9 0 8 0.0 6.1
-8 2 6 12.8 12.7 -9 6 2 59.8 58.8 -9 0 7 18.7 18.4
-8 2 5 12.2 11.7 -9 6 1 20.8 21.8 -9 0 6 24.0 24.5
-8 2 4 0.0 2.7 -9 6 0 0.0 0.1 -9 0 5 15.3 16.6
-8 2 3 0.0 7.7 -9 5 10 0.0 7.0 -9 0 4 0.0 11.0
-8 2 2 18.7 19.4 -9 5 9 0.0 10.0 -9 0 3 30.3 30.0
-8 2 1 11.1 11.2 -9 5 8 0.0 13.2 -9 0 2 41.6 40.8
-8 2 0 7.2 6.7 -9 5 7 0.0 10.2 -9 0 1 25.5 25.4
-8 1 10 0.0 5.1 -9 5 6 0.0 7.1 -9 0 0 18.3 18.8
-8 1 9 0.0 5.4 -9 5 5 22.2 22.3 -10 9 9 0.0 14.1
-8 1 8 0.0 10.2 -9 5 4 13.7 14.0 -10 9 8 0.0 10.6
-8 1 7 0.0 10.0 -9 5 3 17.2 17.6 -10 9 7 0.0 11.6
-8 1 6 15.1 15.3 -9 5 2 0.0 1.3 -10 9 6 0.0 1.4
-8 1 5 13.1 13.0 -9 5 1 26.7 27.0 -10 9 5 0.0 9.8
-8 1 4 28.3 28.3 -9 5 0 9.6 10.6 -10 9 4 12.5 13.0
-8 1 3 10.0 10.4 -9 4 10 0.0 11.6 -10 9 3 21.7 21.7
-8 1 2 44.1 44.7 -9 4 9 0.0 9.0 -10 9 2 0.0 0.9
-8 1 1 15.6 15.4 -9 4 8 16.9 16.5 -10 9 1 13.2 13.1
-8 1 0 51.0 49.2 -9 4 7 0.0 8.9 -10 9 0 15.2 14.7
-8 0 9 0.0 0.3 -9 4 6 17.0 18.2 -10 8 9 0.0 8.1
-8 0 8 0.0 16.7 -9 4 5 14.8 15.1 -10 8 8 0.0 2.9
-8 0 7 0.0 2.6 -9 4 4 0.0 7.4 -10 8 7 0.0 10.7
-8 0 6 52.4 50.8 -9 4 3 14.0 14.4 -10 8 6 20.6 21.2
-8 0 5 0.0 3.1 -9 4 2 0.0 2.0 -10 8 5 0.0 14.2
-8 0 4 37.2 36.7 -9 4 1 18.3 18.3 -10 8 4 0.0 9.4
-8 0 3 0.0 4.8 -9 4 0 12.7 14.3 -10 8 3 17.6 17.8
-8 0 2 55.7 54.9 -9 3 10 0.0 24.0 -10 8 2 51.2 49.6
-8 0 1 0.0 0.9 -9 3 9 0.0 23.6 -10 8 1 19.2 18.7
H K L FO FC H K L FO FC H K L FO FC
-10 8 0 28.0 28.7 -10 2 3 0.0 0.8 -11 7 3 0.0 0.5
-10 7 9 0.0 7.1 -10 2 2 18.4 19.4 -11 7 2 0.0 1.0
-10 7 8 0.0 6.6 -10 2 1 0.0 0.7 -11 7 1 0.0 7.7
-10 7 7 0.0 8.4 -10 2 0 41.6 41.1 -11 7 0 54.3 52.5
-10 7 6 21.3 21.0 -10 1 9 0.0 12.6 -11 6 9 0.0 11.3
-10 7 5 13.7 13.4 -10 1 8 0.0 13.7 -11 6 8 21.9 21.4
-10 7 4 0.0 2.9 -10 1 7 19.9 20.0 -11 6 7 21.1 21.0
-10 7 3 0.0 7.9 -10 1 6 0.0 0.7 -11 6 6 0.0 12.4
-10 7 2 11.2 11.8 -10 1 5 0.0 14.0 -11 6 5 29.8 29.3
-10 7 1 14.6 15.0 -10 1 4 18.8 18.5 -11 6 4 32.5 31.2
-10 7 0 15.6 15.7 -10 1 3 31.1 30.0 -11 6 3 21.3 21.8
-10 6 10 0.0 0.0 -10 1 2 0.0 4.2 -11 6 2 20.0 20.2
-10 6 9 0.0 4.6 -10 1 1 22.4 22.0 -11 6 1 35.3 34.3
-10 6 8 0.0 14.6 -10 1 0 15.6 15.4 -11 6 0 36.5 34.8
-10 6 7 0.0 3.2 -10 0 9 0.0 1.1 -11 5 9 0.0 9.9
-10 6 6 0.0 1.2 -10 0 8 0.0 11.8 -11 5 8 0.0 7.0
-10 6 5 0.0 5.0 -10 0 7 0.0 1.1 -11 5 7 0.0 9.5
-10 6 4 17.7 18.4 -10 0 6 0.0 1.1 -11 5 6 0.0 9.4
-10 6 3 0.0 0.7 -10 0 5 0.0 5.4 -11 5 5 0.0 6.4
-10 6 2 0.0 2.8 -10 0 4 0.0 12.0 -11 5 4 0.0 8.1
-10 6 1 0.0 1.8 -10 0 3 0.0 6.2 -11 5 3 15.7 17.5
-10 6 0 18.5 20.0 -10 0 2 0.0 2.3 -11 5 2 0.0 7.2
-10 5 10 0.0 11.5 -10 0 1 0.0 3.9 -11 5 1 0.0 10.3
-10 5 9 0.0 14.3 -10 0 0 11.5 11.5 -11 5 0 0.0 3.2
-10 5 8 0.0 3.5 -11 10 8 0.0 17.7 -11 4 9 0.0 4.4
-10 5 7 19.1 18.3 -11 10 7 0.0 7.5 -11 4 8 0.0 20.8
-10 5 6 0.0 14.0 -11 10 6 0.0 3.5 -11 4 7 0.0 8.6
-10 5 5 24.6 24.8 -11 10 5 0.0 11.9 -11 4 6 0.0 7.6
-10 5 4 15.8 16.3 -11 10 4 33.2 32.7 -11 4 5 0.0 8.1
-10 5 3 25.8 26.1 -11 10 3 0.0 12.5 -11 4 4 33.2 32.8
-10 5 2 44.0 43.2 -11 10 2 0.0 7.7 -11 4 3 12.5 11.3
-10 5 1 31.4 31.4 -11 10 1 0.0 12.9 -11 4 2 0.0 12.3
-10 5 0 39.7 40.3 -11 10 0 43.2 41.7 -11 4 1 0.0 12.0
-10 4 9 0.0 4.0 -11 9 9 0.0 14.8 -11 4 0 39.7 38.9
-10 4 8 0.0 9.5 -11 9 8 0.0 15.7 -11 3 9 0.0 5.0
-10 4 7 0.0 0.7 -11 9 7 0.0 20.9 -11 3 8 0.0 6.1
-10 4 6 18.1 18.3 -11 9 6 0.0 0.8 -11 3 7 0.0 14.4
-10 4 5 0.0 5.1 -11 9 5 30.0 29.8 -11 3 6 0.0 12.5
-10 4 4 0.0 5.3 -11 9 4 20.7 20.6 -11 3 5 0.0 16.3
-10 4 3 0.0 3.6 -11 9 3 29.0 28.7 -11 3 4 0.0 1.3
-10 4 2 0.0 7.4 -11 9 2 0.0 9.9 -11 3 3 0.0 14.2
-10 4 1 0.0 5.5 -11 9 1 36.6 36.1 -11 3 2 0.0 6.9
-10 4 0 0.0 9.1 -11 9 0 15.8 15.3 -11 3 1 22.1 21.8
-10 3 9 0.0 9.7 -11 8 9 0.0 4.4 -11 3 0 0.0 4.0
-10 3 8 0.0 11.9 -11 8 8 0.0 1.1 -11 2 8 0.0 14.7
-10 3 7 0.0 14.3 -11 8 7 0.0 3.2 -11 2 7 0.0 7.8
-10 3 6 0.0 2.0 -11 8 6 26.7 27.8 -11 2 6 0.0 4.6
-10 3 5 0.0 3.1 -11 8 5 0.0 5.4 -11 2 5 0.0 6.4
-10 3 4 17.4 17.5 -11 8 4 0.0 5.7 -11 2 4 18.7 19.5
-10 3 3 25.2 25.7 -11 8 3 0.0 5.8 -11 2 3 16.8 17.4
-10 3 2 0.0 1.7 -11 8 2 16.6 16.5 -11 2 2 0.0 7.9
-10 3 1 0.0 10.0 -11 8 1 0.0 6.0 -11 2 1 0.0 9.1
-10 3 0 22.6 22.4 -11 8 0 23.3 23.0 -11 2 0 21.1 21.4
10 -2 9 0.0 0.1 -11 7 9 0.0 0.1 -11 1 8 0.0 5.1
-10 2 8 0.0 16.1 -11 7 8 0.0 27.7 -11 1 7 19.2 20.8
-10 2 7 0.0 2.5 -11 7 7 0.0 3.3 -11 1 6 0.0 21.4
-10 2 6 0.0 9.2 -11 7 6 0.0 2.3 -11 1 5 25.0 24.9
-10 2 5 0.0 1.3 -11 7 5 0.0 7.7 -11 1 4 0.0 11.0
-10 2 4 28.8 29.2 -11 7 4 44.7 43.7 -11 1 3 36.2 35.6
H K L FO FC H K L FO FC H K L FO FC
-11 1 2 34.0 33.0 -12 6 8 0.0 5.4 -12 0 3 0.0 3.4
-11 1 1 33.1 32.6 -12 6 7 0.0 8.9 -12 0 2 0.0 7.2
-11 1 0 13.9 14.8 -12 6 6 0.0 17.1 -12 0 1 0.0 6.0
-11 0 8 0.0 9.1 -12 6 5 0.0 13.4 -12 0 0 38.7 39.4
-11 0 7 0.0 10.3 -12 6 4 0.0 15.6 -13 12 6 0.0 17.5
-11 0 6 0.0 15.9 -12 6 3 0.0 10.5 -13 12 5 0.0 1.3
-11 0 5 0.0 16.2 -12 6 2 31.2 31.0 -13 12 4 0.0 11.3
-11 0 4 0.0 2.9 -12 6 1 13.9 15.5 -13 12 3 0.0 5.8
-11 0 3 18.2 18.4 -12 6 0 24.2 24.3 -13 12 2 22.2 23.0
-11 0 2 0.0 1.0 -12 5 9 0.0 6.7 -13 12 1 0.0 0.2
-11 0 1 18.5 19.6 -12 5 8 0.0 2.3 -13 12 0 0.0 14.3
-11 0 0 0.0 9.9 -12 5 7 0.0 11.2 -13 11 7 0.0 8.0
-12 11 7 0.0 4.0 -12 5 6 0.0 8.0 -13 11 6 0.0 25.6
-12 11 6 0.0 8.4 -12 5 5 18.9 19.5 -13 11 5 0.0 13.1
-12 11 5 0.0 9.4 -12 5 4 0.0 3.4 -13 11 4 0.0 0.6
-12 11 4 0.0 5.5 -12 5 3 0.0 9.9 -13 11 3 0.0 12.0
-12 11 3 0.0 8.8 -12 5 2 0.0 9.7 -13 11 2 34.9 35.0
-12 11 2 0.0 4.5 -12 5 1 21.8 21.7 -13 11 1 0.0 13.6
-12 11 1 0.0 9.9 -12 5 0 0.0 5.5 -13 11 0 0.0 0.5
-12 11 0 0.0 1.8 -12 4 9 0.0 1.0 -13 10 7 0.0 10.4
12-11 8 0.0 5.5 -12 4 8 0.0 8.3 -13 10 6 0.0 12.0
-12 10 7 0.0 18.6 -12 4 7 0.0 4.9 -13 10 5 0.0 15.0
-12 10 6 0.0 8.9 -12 4 6 35.2 35.7 -13 10 4 0.0 0.4
-12 10 5 0.0 15.4 -12 4 5 0.0 3.0 -13 10 3 0.0 16.1
-12 10 4 21.6 22.1 -12 4 4 21.9 22.1 -13 10 2 0.0 6.2
-12 10 3 33.1 32.6 -12 4 3 0.0 6.9 -13 10 1 15.9 17.4
-12 10 2 0.0 11.6 -12 4 2 31.4 31.3 -13 10 0 0.0 7.8
-12 10 1 23.9 23.3 -12 4 1 0.0 5.7 -13 9 7 0.0 0.5
-12 10 0 25.1 25.9 -12 4 0 37.7 36.7 -13 9 6 0.0 11.7
12-10 8 0.0 15.1 -12 3 8 0.0 3.6 -13 9 5 0.0 0.8
-12 9 8 0.0 15.5 -12 3 7 0.0 9.2 -13 9 4 0.0 2.8
-12 9 7 0.0 5.7 -12 3 6 0.0 10.5 -13 9 3 0.0 8.2
-12 9 6 0.0 7.2 -12 3 5 0.0 11.9 -13 9 2 0.0 12.8
-12 9 5 0.0 6.4 -12 3 4 0.0 14.4 -13 9 1 0.0 1.5
-12 9 4 24.4 24.6 -12 3 3 0.0 12.7 -13 9 0 0.0 4.9
-12 9 3 0.0 9.1 -12 3 2 31.8 30.4 -13 8 7 0.0 0.8
-12 9 2 0.0 14.3 -12 3 1 13.8 14.8 -13 8 6 0.0 17.6
-12 9 1 0.0 9.0 -12 3 0 29.6 29.4 -13 8 5 0.0 0.0
-12 9 0 33.9 32.5 -12 2 8 0.0 7.3 -13 8 4 0.0 8.9
-12 8 8 0.0 7.6 -12 2 7 0.0 13.2 -13 8 3 0.0 0.6
-12 8 7 0.0 9.0 -12 2 6 0.0 1.8 -13 8 2 29.2 29.5
-12 8 6 0.0 20.6 -12 2 5 0.0 12.8 -13 8 1 0.0 0.8
-12 8 5 22.8 22.3 -12 2 4 0.0 9.6 -13 8 0 0.0 14.1
-12 8 4 0.0 10.8 -12 2 3 17.9 18.0 13 -8 8 0.0 3.9
-12 8 3 0.0 12.4 -12 2 2 0.0 2.4 -13 7 8 0.0 7.2
-12 8 2 26.3 26.2 -12 2 1 17.7 18.3 -13 7 7 0.0 11.7
-12 8 1 22.7 23.2 -12 2 0 0.0 11.3 -13 7 6 0.0 20.3
-12 8 0 0.0 12.4 -12 1 7 0.0 1.5 -13 7 5 0.0 16.6
-12 7 9 0.0 1.3 -12 1 6 28.3 29.6 -13 7 4 0.0 2.6
-12 7 8 0.0 7.7 -12 1 5 0.0 2.0 -13 7 3 16.6 16.9
-12 7 7 0.0 0.6 -12 1 4 0.0 18.5 -13 7 2 0.0 9.1
-12 7 6 0.0 7.7 -12 1 3 0.0 2.1 -13 7 1 19.3 18.9
-12 7 5 0.0 2.6 -12 1 2 31.0 30.3 -13 7 0 18.9 19.2
-12 7 4 0.0 5.3 -12 1 1 0.0 0.6 -13 6 8 0.0 14.7
-12 7 3 0.0 4.2 -12 1 0 28.4 29.2 -13 6 7 0.0 9.4
-12 7 2 0.0 3.1 -12 0 7 0.0 2.6 -13 6 6 0.0 2.8
-12 7 1 0.0 2.7 -12 0 6 0.0 4.1 -13 6 5 0.0 5.7
-12 7 0 0.0 2.5 -12 0 5 0.0 5.8 -13 6 4 17.6 18.3
-12 6 9 0.0 6.1 -12 0 4 23.8 25.9 -13 6 3 0.0 9.7
H K L FO FC H K L FO FC H K L FO FC
-13 6 2 0.0 9.6 -14 12 4 0.0 11.1 -14 5 0 22.7 22.5
-13 6 1 0.0 9.1 -14 12 3 0.0 6.5 -14 4 7 0.0 1.6
-13 6 0 17.2 17.0 -14 12 2 0.0 3.5 -14 4 6 0.0 18.7
-13 5 8 0.0 16.3 -14 12 1 0.0 3.2 -14 4 5 0.0 3.5
-13 5 7 0.0 6.8 -14 12 0 0.0 11.8 -14 4 4 0.0 5.1
-13 5 6 0.0 4.4 14-11 7 0.0 0.2 -14 4 3 0.0 6.3
-13 5 5 0.0 15.0 -14 11 6 0.0 6.4 -14 4 2 23.7 24.8
-13 5 4 25.8 26.8 -14 11 5 0.0 4.2 -14 4 1 0.0 1.4
-13 5 3 0.0 8.2 -14 11 4 0.0 9.6 -14 4 0 0.0 6.8
-13 5 2 0.0 7.6 -14 11 3 0.0 1.4 -14 3 6 0.0 1.8
-13 5 1 14.6 15.3 -14 11 2 0.0 3.8 -14 3 5 0.0 8.7
-13 5 0 34.1 33.5 -14 11 1 0.0 4.0 -14 3 4 0.0 8.0
-13 4 8 0.0 2.1 -14 11 0 0.0 1.0 -14 3 3 0.0 10.0
-13 4 7 0.0 4.5 -14 10 6 0.0 14.4 -14 3 2 0.0 2.4
-13 4 6 0.0 19.1 -14 10 5 0.0 1.2 -14 3 1 0.0 9.8
-13 4 5 0.0 0.3 -14 10 4 0.0 4.8 -14 3 0 0.0 6.0
-13 4 4 0.0 2.0 -14 10 3 0.0 2.3 -14 2 5 0.0 0.1
-13 4 3 0.0 5.9 -14 10 2 28.8 29.8 -14 2 4 0.0 12.9
-13 4 2 0.0 12.2 -14 10 1 0.0 1.1 -14 2 3 0.0 2.0
-13 4 1 0.0 3.3 -14 10 0 0.0 13.8 -14 2 2 0.0 8.9
-13 4 0 0.0 13.9 -14 9 7 0.0 19.6 -14 2 1 0.0 0.7
-13 3 7 0.0 6.7 -14 9 6 0.0 6.2 -14 2 0 0.0 9.0
-13 3 6 0.0 8.9 -14 9 5 0.0 27.5 -14 1 5 0.0 11.9
-13 3 5 0.0 4.7 -14 9 4 0.0 17.7 -14 1 4 0.0 8.0
-13 3 4 23.8 24.4 -14 9 3 24.0 25.3 -14 1 3 0.0 17.6
-13 3 3 0.0 8.3 -14 9 2 0.0 8.2 -14 1 2 0.0 16.9
-13 3 2 17.1 15.6 -14 9 1 32.0 31.8 -14 1 1 0.0 14.6
-13 3 1 0.0 6.1 -14 9 0 18.3 19.8 -14 1 0 0.0 8.9
-13 3 0 25.2 24.6 -14 8 7 0.0 1.4 -14 0 4 0.0 11.4
-13 2 7 0.0 7.9 -14 8 6 0.0 1.7 -14 0 3 0.0 8.6
-13 2 6 0.0 10.6 -14 8 5 0.0 6.4 -14 0 2 0.0 7.1
-13 2 5 0.0 5.2 -14 8 4 0.0 14.7 -14 0 1 0.0 10.4
-13 2 4 0.0 18.3 -14 8 3 0.0 1.8 -14 0 0 0.0 9.3
-13 2 3 0.0 15.9 -14 8 2 0.0 6.5 15-14 2 0.0 4.1
-13 2 2 0.0 14.6 -14 8 1 0.0 6.1 -15 14 1 0.0 11.7
-13 2 1 0.0 8.2 -14 8 0 0.0 9.6 -15 14 0 0.0 1.7
-13 2 0 21.9 21.4 -14 7 7 0.0 10.5 15-14 3 0.0 11.5
-13 1 6 0.0 3.5 -14 7 6 0.0 17.9 15-14 4 0.0 8.2
-13 1 5 0.0 5.7 -14 7 5 0.0 17.2 15-13 5 0.0 0.5
-13 1 4 0.0 8.5 -14 7 4 0.0 3.1 -15 13 4 0.0 8.1
-13 1 3 0.0 14.9 -14 7 3 0.0 14.5 15-13 3 0.0 4.7
-13 1 2 0.0 0.8 -14 7 2 29.2 30.1 15-13 2 0.0 1.3
-13 1 1 0.0 10.4 -14 7 1 19.5 19.2 -15 13 1 0.0 2.7
-13 1 0 0.0 7.2 -14 7 0 0.0 9.1 -15 13 0 0.0 7.7
-13 0 6 0.0 1.8 -14 6 7 0.0 15.6 -15 12 5 0.0 4.7
-13 0 5 0.0 1.0 -14 6 6 0.0 5.2 -15 12 4 0.0 23.3
-13 0 4 0.0 7.7 -14 6 5 0.0 20.0 -15 12 3 0.0 2.2
-13 0 3 0.0 2.5 -14 6 4 0.0 15.5 -15 12 2 0.0 0.5
-13 0 2 0.0 0.4 -14 6 3 0.0 16.3 -15 12 1 0.0 3.5
-13 0 1 0.0 0.6 -14 6 2 0.0 7.3 -15 12 0 29.1 29.0
-13 0 0 0.0 7.2 -14 6 1 23.9 24.1 15-11 6 0.0 13.0
-14 13 5 0.0 11.5 -14 6 0 17.2 18.3 -15 11 5 0.0 6.1
14-13 4 0.0 4.4 -14 5 7 0.0 0.2 -15 11 4 0.0 1.9
-14 13 3 0.0 17.3 -14 5 6 0.0 8.9 -15 11 3 0.0 2.8
-14 13 2 23.4 25.8 -14 5 5 0.0 0.4 -15 11 2 0.0 10.5
-14 13 1 0.0 14.4 -14 5 4 0.0 22.2 -15 11 1 0.0 5.9
-14 13 0 0.0 9.2 -14 5 3 0.0 3.1 -15 11 0 0.0 7.4
14-12 6 0.0 1.3 -14 5 2 0.0 16.1 15-10 6 0.0 2.7
-14 12 5 0.0 2.2 -14 5 1 0.0 1.2 -15 10 5 0.0 2.0
H K L FO FC H K L FO FC H K L FO FC
-15 10 4 0.0 12.1 -15 2 2 0.0 1.3 -16 8 0 0.0 19.8
-15 10 3 0.0 0.3 -15 2 1 0.0 15.4 -16 7 4 0.0 2.9
-15 10 2 0.0 3.6 -15 2 0 0.0 1.8 -16 7 3 0.0 12.2
-15 10 1 0.0 1.9 -15 1 3 0.0 1.3 -16 7 2 0.0 3.3
-15 10 0 0.0 14.0 -15 1 2 0.0 9.3 -16 7 1 0.0 11.9
-15 9 6 0.0 3.8 -15 1 1 0.0 3.1 -16 7 0 0.0 2.1
-15 9 5 0.0 5.6 -15 1 0 0.0 1.2 -16 6 4 0.0 14.4
-15 9 4 0.0 21.3 -15 0 3 0.0 6.1 -16 6 3 0.0 6.4
-15 9 3 0.0 0.1 -15 0 2 0.0 3.0 -16 6 2 0.0 9.6
-15 9 2 0.0 7.0 -15 0 1 0.0 5.4 -16 6 1 0.0 6.3
-15 9 1 0.0 5.6 15 0 0 0.0 22.5 -16 6 0 0.0 8.7
-15 9 0 24.5 26.5 16-15 1 0.0 2.2 -16 5 4 0.0 17.9
-15 8 6 0.0 9.7 16-15 2 0.0 12.1 -16 5 3 0.0 6.1
-15 8 5 0.0 8.5 -16 14 1 0.0 8.3 -16 5 2 0.0 3.8
-15 8 4 0.0 1.0 -16 14 0 0.0 7.9 -16 5 1 0.0 3.3
-15 8 3 0.0 0.6 16-14 2 0.0 12.5 -16 5 0 0.0 19.9
-15 8 2 0.0 9.7 16-14 3 0.0 5.9 -16 4 3 0.0 1.5
-15 8 1 0.0 7.8 16-13 4 0.0 0.6 -16 4 2 0.0 14.6
-15 8 0 0.0 2.9 -16 13 2 0.0 7.5 -16 4 1 0.0 0.7
-15 7 6 0.0 21.1 -16 13 1 0.0 0.5 -16 4 0 0.0 10.3
-15 7 5 0.0 0.1 -16 13 0 0.0 0.7 -16 3 3 0.0 7.8
-15 7 4 0.0 16.4 16-13 3 0.0 2.3 -16 3 2 0.0 0.9
-15 7 3 0.0 2.7 16-12 5 0.0 1.6 -16 3 1 0.0 5.3
-15 7 2 25.7 27.4 16-12 4 0.0 15.3 -16 3 0 0.0 4.9
-15 7 1 0.0 0.4 -16 12 3 0.0 2.3 -16 2 3 0.0 11.2
-15 7 0 19.0 19.2 -16 12 2 0.0 22.3 -16 2 2 0.0 15.9
-15 6 6 0.0 7.9 -16 12 1 0.0 1.8 -16 2 1 0.0 9.8
-15 6 5 0.0 10.2 -16 12 0 0.0 20.0 -16 2 0 0.0 5.9
-15 6 4 0.0 12.7 16-11 5 0.0 1.0 -16 1 2 0.0 5.6
-15 6 3 0.0 9.3 -16 11 4 0.0 14.2 -16 1 1 0.0 3.9
-15 6 2 19.2 19.7 -16 11 3 0.0 5.9 -16 1 0 0.0 2.4
-15 6 1 0.0 12.4 -16 11 2 0.0 8.0 17-14 1 0.0 1.2
-15 6 0 20.9 21.5 -16 11 1 0.0 1.0 17-12 3 0.0 0.1
-15 5 5 0.0 1.2 -16 11 0 0.0 15.6 17-11 3 0.0 9.7
-15 5 4 0.0 6.3 16-10 5 0.0 3.0 17-11 2 0.0 7.7
-15 5 3 0.0 6.5 -16 10 4 0.0 7.3 17-10 4 0.0 0.7
-15 5 2 0.0 0.7 -16 10 3 0.0 3.1 17-10 3 0.0 15.8
-15 5 1 0.0 2.4 -16 10 2 0.0 2.4 17-10 2 0.0 22.1
-15 5 0 0.0 4.2 -16 10 1 0.0 2.5 17 -9 3 0.0 4.9
-15 4 5 0.0 4.6 -16 10 0 0.0 4.5 -17 9 2 0.0 3.8
-15 4 4 0.0 19.3 16 -9 6 0.0 15.2 -17 9 1 0.0 4.6
-15 4 3 0.0 3.8 16 -9 5 0.0 0.6 -17 9 0 0.0 1.5
-15 4 2 0.0 30.0 -16 9 4 0.0 5.9 -17 8 2 0.0 0.4
-15 4 1 0.0 4.0 -16 9 3 0.0 0.1 -17 8 1 0.0 2.7
-15 4 0 18.7 22.5 -16 9 2 0.0 10.8 -17 8 0 0.0 6.6
-15 3 4 0.0 10.5 -16 9 1 0.0 0.9 -17 7 2 0.0 19.8
-15 3 3 0.0 1.0 -16 9 0 0.0 12.9 -17 7 1 0.0 16.2
-15 3 2 0.0 17.7 -16 8 4 0.0 17.9 -17 5 1 0.0 1.6
-15 3 1 0.0 0.9 -16 8 3 0.0 11.9 -17 4 2 0.0 9.8
-15 3 0 19.1 20.4 -16 8 2 0.0 5.5 -17 4 1 0.0 3.3
-15 2 3 0.0 14.9 -16 8 1 0.0 11.0 -17 3 1 0.0 15.4
Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:
Uptake, Site Preference and
Degradation of Monoclinic Structure
Michael E. Fleet, Xioayang Liu
and Yuanming Pan
Deposited Material
Table 5. List of observed and calculated structure factors
(d) P63/m structure of Dy-chlorapatite
H K L FO FC H K L FO FC H K L FO FC
0 0 2 98.9 100.8 1 -3 0 0.0 2.4 4 -5 3 0.0 0.7
0 0 4 206.7 202.6 -3 0 10 0.0 3.8 4 -5 2 37.9 38.2
0 0 6 95.9 95.2 -3 0 9 0.0 5.5 4 -5 1 0.0 3.1
0 0 8 82.0 76.5 -3 0 8 33.1 33.9 4 -5 0 96.9 97.6
0 0 10 37.0 39.3 -3 0 7 0.0 9.2 3 -5 9 0.0 16.6
-1 0 10 0.0 11.5 -3 0 6 0.0 7.9 3 -5 8 0.0 1.6
-1 0 9 0.0 2.5 -3 0 5 0.0 10.2 3 -5 7 23.7 25.2
-1 0 8 0.0 15.5 -3 0 4 77.9 77.2 3 -5 6 30.7 30.7
-1 0 7 0.0 5.1 -3 0 3 25.1 25.1 3 -5 5 28.0 28.3
-1 0 6 19.4 19.1 -3 0 2 44.9 44.2 3 -5 4 0.0 11.4
-1 0 5 0.0 7.9 -3 0 1 26.9 26.4 3 -5 3 51.4 51.3
-1 0 4 23.6 23.4 -3 0 0 155.7 155.4 3 -5 2 41.1 41.4
-1 0 3 0.0 4.2 3 -4 9 0.0 13.9 3 -5 1 50.2 50.6
-1 0 2 0.0 0.5 3 -4 8 0.0 3.7 3 -5 0 15.3 14.7
-1 0 1 16.2 16.3 3 -4 7 0.0 7.6 2 -5 9 0.0 18.1
-1 0 0 15.9 16.2 3 -4 6 0.0 14.6 2 -5 8 0.0 21.8
1 -2 10 0.0 30.4 3 -4 5 0.0 5.6 2 -5 7 0.0 19.6
1 -2 9 0.0 6.9 3 -4 4 0.0 4.5 2 -5 6 0.0 6.5
1 -2 8 0.0 2.7 3 -4 3 41.3 40.9 2 -5 5 49.1 49.8
1 -2 7 0.0 4.2 3 -4 2 39.5 39.4 2 -5 4 38.7 39.1
1 -2 6 66.5 65.3 3 -4 1 9.6 7.7 2 -5 3 17.2 17.8
1 -2 5 0.0 13.2 3 -4 0 19.6 19.6 2 -5 2 12.8 13.2
1 -2 4 11.8 11.8 2 -4 10 0.0 26.5 2 -5 1 63.6 63.6
1 -2 3 42.2 41.6 2 -4 9 0.0 0.1 2 -5 0 61.3 60.7
1 -2 2 113.8 114.9 2 -4 8 0.0 1.7 1 -5 9 0.0 5.6
1 -2 1 13.0 13.4 2 -4 7 0.0 2.6 1 -5 8 25.6 27.8
1 -2 0 0.0 3.8 2 -4 6 51.3 51.0 1 -5 7 0.0 6.2
-2 0 10 0.0 11.5 2 -4 5 0.0 9.7 1 -5 6 16.3 18.1
-2 0 9 0.0 1.3 2 -4 4 0.0 3.9 1 -5 5 0.0 0.7
-2 0 8 0.0 7.8 2 -4 3 9.4 9.6 1 -5 4 51.5 51.1
-2 0 7 0.0 1.1 2 -4 2 119.5 118.4 1 -5 3 17.7 18.8
-2 0 6 20.2 19.7 2 -4 1 0.0 8.0 1 -5 2 32.8 33.1
-2 0 5 19.4 20.6 2 -4 0 21.9 22.2 1 -5 1 0.0 3.7
-2 0 4 0.0 5.4 1 -4 9 0.0 13.0 1 -5 0 67.6 68.1
-2 0 3 26.1 25.4 1 -4 8 0.0 13.7 -5 0 9 0.0 2.0
-2 0 2 39.5 39.0 1 -4 7 24.1 24.9 -5 0 8 0.0 10.3
-2 0 1 23.4 23.2 1 -4 6 43.1 43.8 -5 0 7 0.0 3.7
-2 0 0 6.3 5.2 1 -4 5 27.3 26.8 -5 0 6 34.4 33.0
2 -3 10 0.0 1.4 1 -4 4 0.0 4.9 -5 0 5 24.4 25.5
2 -3 9 0.0 33.8 1 -4 3 39.6 39.2 -5 0 4 18.8 18.8
2 -3 8 0.0 20.7 1 -4 2 29.3 29.0 -5 0 3 0.0 8.8
2 -3 7 35.5 36.5 1 -4 1 43.1 43.2 -5 0 2 54.7 54.4
2 -3 6 0.0 0.7 1 -4 0 88.9 85.1 -5 0 1 33.5 33.2
2 -3 5 58.7 58.3 -4 0 9 0.0 3.7 -5 0 0 12.3 12.8
2 -3 4 29.3 29.4 -4 0 8 0.0 6.4 5 -6 9 0.0 30.6
2 -3 3 81.2 81.3 -4 0 7 0.0 9.3 5 -6 8 38.2 37.8
2 -3 2 9.9 9.5 -4 0 6 36.2 37.0 5 -6 7 32.7 33.6
2 -3 1 96.5 97.4 -4 0 5 12.5 14.1 5 -6 6 0.0 9.8
2 -3 0 43.2 44.7 -4 0 4 14.1 13.8 5 -6 5 52.7 52.3
1 -3 10 0.0 7.2 -4 0 3 0.0 3.4 5 -6 4 53.0 52.9
1 -3 9 0.0 21.3 -4 0 2 52.5 52.8 5 -6 3 58.7 57.9
1 -3 8 30.5 31.8 -4 0 1 13.1 13.1 5 -6 2 46.6 47.5
1 -3 7 34.7 34.4 -4 0 0 25.2 25.5 5 -6 1 71.0 70.4
1 -3 6 0.0 14.9 4 -5 9 0.0 0.5 5 -6 0 43.2 43.6
1 -3 5 38.7 38.2 4 -5 8 0.0 20.9 4 -6 9 0.0 7.1
1 -3 4 40.6 40.6 4 -5 7 0.0 3.0 4 -6 8 37.7 38.2
1 -3 3 64.6 64.8 4 -5 6 0.0 13.9 4 -6 7 0.0 16.1
1 -3 2 50.3 48.8 4 -5 5 0.0 2.5 4 -6 6 0.0 4.5
1 -3 1 68.4 69.5 4 -5 4 54.3 54.6 4 -6 5 17.5 16.9
H K L FO FC H K L FO FC H K L FO FC
4 -6 4 44.1 44.0 5 -7 4 42.2 42.0 7 -8 2 42.1 43.4
4 -6 3 26.9 27.2 5 -7 3 38.0 37.9 7 -8 1 15.8 15.2
4 -6 2 48.3 48.6 5 -7 2 30.2 30.0 7 -8 0 49.1 48.7
4 -6 1 30.7 30.5 5 -7 1 33.4 33.9 6 -8 8 0.0 3.6
4 -6 0 0.0 11.3 5 -7 0 78.6 79.1 6 -8 7 0.0 4.1
3 -6 9 0.0 9.5 -4 7 9 0.0 15.3 6 -8 6 0.0 11.7
3 -6 8 0.0 12.7 4 -7 8 0.0 13.6 6 -8 5 0.0 11.2
3 -6 7 0.0 18.3 4 -7 7 25.7 26.9 6 -8 4 0.0 3.4
3 -6 6 32.7 32.8 4 -7 6 0.0 8.1 6 -8 3 0.0 7.9
3 -6 5 28.1 29.2 4 -7 5 20.6 21.9 6 -8 2 18.3 18.4
3 -6 4 28.4 29.4 4 -7 4 21.2 20.8 6 -8 1 0.0 10.8
3 -6 3 15.5 15.0 4 -7 3 51.7 53.1 6 -8 0 0.0 7.5
3 -6 2 52.7 53.4 4 -7 2 0.0 1.2 5 -8 8 0.0 4.1
3 -6 1 39.5 39.9 4 -7 1 41.6 41.5 5 -8 7 0.0 11.2
3 -6 0 41.0 41.4 4 -7 0 19.3 18.4 5 -8 6 0.0 14.2
2 -6 9 0.0 20.8 -3 7 9 0.0 2.2 5 -8 5 0.0 3.6
2 -6 8 31.3 32.8 3 -7 8 0.0 14.0 5 -8 4 0.0 3.3
2 -6 7 0.0 18.7 3 -7 7 0.0 1.4 5 -8 3 18.8 19.8
2 -6 6 0.0 16.0 3 -7 6 42.8 41.7 5 -8 2 16.2 17.2
2 -6 5 22.7 22.7 3 -7 5 0.0 8.0 5 -8 1 0.0 11.0
2 -6 4 48.4 47.9 3 -7 4 29.5 29.7 5 -8 0 0.0 2.6
2 -6 3 45.7 46.2 3 -7 3 0.0 3.7 4 -8 8 0.0 37.4
2 -6 2 36.4 36.8 3 -7 2 62.2 62.4 4 -8 7 0.0 13.2
2 -6 1 31.0 31.4 3 -7 1 0.0 9.0 4 -8 6 0.0 2.9
2 -6 0 58.6 58.3 3 -7 0 39.9 41.5 4 -8 5 24.4 26.3
1 -6 9 0.0 7.6 -2 7 9 0.0 6.2 4 -8 4 63.3 63.4
1 -6 8 0.0 17.6 2 -7 8 0.0 5.5 4 -8 3 0.0 8.8
1 -6 7 0.0 18.3 2 -7 7 0.0 6.8 4 -8 2 0.0 2.7
1 -6 6 0.0 14.6 2 -7 6 22.9 24.7 4 -8 1 33.3 34.0
1 -6 5 19.6 19.6 2 -7 5 0.0 7.8 4 -8 0 78.7 76.8
1 -6 4 12.5 11.6 2 -7 4 0.0 9.2 3 -8 8 0.0 14.0
1 -6 3 18.2 18.1 2 -7 3 0.0 9.5 3 -8 7 0.0 4.8
1 -6 2 0.0 1.7 2 -7 2 84.2 84.4 3 -8 6 42.2 40.9
1 -6 1 28.3 29.1 2 -7 1 0.0 10.1 3 -8 5 0.0 7.3
1 -6 0 0.0 4.3 2 -7 0 49.7 50.6 3 -8 4 26.3 26.4
6 0 9 0.0 10.8 1 -7 8 31.5 31.0 3 -8 3 0.0 7.5
-6 0 8 0.0 10.0 1 -7 7 0.0 5.5 3 -8 2 53.0 53.0
-6 0 7 0.0 16.5 -1 7 6 0.0 3.7 3 -8 1 0.0 9.6
6 0 6 35.7 36.3 1 -7 5 0.0 13.6 3 -8 0 37.7 36.8
-6 0 5 0.0 8.1 1 -7 4 40.7 41.3 2 -8 8 0.0 21.5
-6 0 4 18.9 20.3 1 -7 3 0.0 15.6 2 -8 7 0.0 3.6
-6 0 3 29.2 29.5 1 -7 2 32.6 33.7 2 -8 6 0.0 1.8
-6 0 2 53.5 52.4 1 -7 1 19.4 20.5 2 -8 5 0.0 0.2
-6 0 1 14.2 15.0 1 -7 0 29.6 30.0 2 -8 4 27.3 28.0
-6 0 0 23.7 25.0 -7 0 8 0.0 5.1 2 -8 3 0.0 4.6
6 -7 8 0.0 15.3 -7 0 7 0.0 8.2 2 -8 2 0.0 12.0
6 -7 7 0.0 4.8 7 0 6 26.0 25.4 2 -8 1 0.0 3.0
6 -7 6 0.0 1.1 -7 0 5 0.0 1.4 2 -8 0 18.1 17.1
6 -7 5 0.0 7.6 -7 0 4 0.0 12.9 1 -8 8 0.0 33.5
6 -7 4 23.2 23.5 -7 0 3 21.6 22.0 1 -8 7 0.0 10.8
6 -7 3 0.0 4.9 -7 0 2 36.0 36.3 -1 8 6 0.0 1.3
6 -7 2 0.0 3.5 -7 0 1 0.0 4.8 1 -8 5 0.0 1.5
6 -7 1 0.0 9.2 -7 0 0 15.9 15.9 1 -8 4 55.0 54.1
6 -7 0 30.8 30.9 7 -8 8 0.0 10.2 1 -8 3 25.9 26.9
-5 7 9 0.0 15.7 7 -8 7 0.0 9.9 1 -8 2 0.0 0.8
5 -7 8 0.0 18.3 7 -8 6 0.0 14.6 1 -8 1 0.0 10.5
5 -7 7 0.0 22.2 7 -8 5 0.0 13.0 1 -8 0 67.2 65.2
5 -7 6 0.0 5.6 7 -8 4 28.5 28.0 -8 0 8 0.0 15.4
5 -7 5 20.0 21.3 7 -8 3 0.0 10.6 -8 0 7 0.0 2.7
H K L FO FC H K L FO FC H K L FO FC
8 0 6 50.3 48.5 3 -9 0 0.0 0.5 5-10 5 0.0 23.7
-8 0 5 0.0 3.4 2 -9 8 0.0 20.3 5-10 4 0.0 15.7
-8 0 4 35.6 34.8 2 -9 7 0.0 14.2 5-10 3 24.3 25.3
-8 0 3 0.0 4.8 2 -9 6 0.0 6.8 5-10 2 42.9 42.3
-8 0 2 53.1 52.8 2 -9 5 0.0 11.4 5-10 1 31.1 30.5
-8 0 1 0.0 1.1 2 -9 4 26.2 25.8 5-10 0 39.3 39.2
-8 0 0 56.5 55.3 2 -9 3 0.0 22.8 4-10 7 0.0 3.0
8 -9 7 0.0 6.3 2 -9 2 15.2 15.4 4-10 6 0.0 0.5
8 -9 6 24.6 25.7 2 -9 1 0.0 17.6 4-10 5 0.0 5.6
8 -9 5 0.0 10.8 2 -9 0 26.2 27.1 4-10 4 0.0 17.0
8 -9 4 0.0 2.8 1 -9 7 0.0 5.4 4-10 3 0.0 0.2
8 -9 3 0.0 11.9 -1 9 6 0.0 1.6 4-10 2 0.0 1.7
8 -9 2 0.0 4.9 1 -9 5 0.0 2.6 4-10 1 0.0 2.7
8 -9 1 0.0 14.1 1 -9 4 0.0 13.9 4-10 0 0.0 18.3
8 -9 0 21.4 22.0 1 -9 3 0.0 0.6 3-10 7 0.0 8.0
-7 9 8 0.0 18.2 1 -9 2 0.0 1.1 3-10 6 0.0 20.2
7 -9 7 0.0 12.6 1 -9 1 0.0 6.7 3-10 5 0.0 13.1
7 -9 6 0.0 1.2 1 -9 0 15.7 18.4 3-10 4 0.0 2.5
7 -9 5 0.0 14.9 9 0 7 0.0 17.5 3-10 3 0.0 7.8
7 -9 4 0.0 20.1 9 0 6 0.0 23.2 3-10 2 0.0 11.0
7 -9 3 0.0 16.6 9 0 5 0.0 15.6 3-10 1 0.0 14.7
7 -9 2 0.0 8.0 -9 0 4 0.0 10.7 3-10 0 0.0 15.1
7 -9 1 17.1 18.9 -9 0 3 30.4 28.7 2-10 7 0.0 10.4
7 -9 0 0.0 15.0 -9 0 2 40.7 39.2 -2 10 6 0.0 20.3
-6 9 8 0.0 4.7 -9 0 1 24.7 24.2 2-10 5 0.0 14.1
6 -9 7 33.7 35.6 -9 0 0 0.0 18.7 2-10 4 0.0 9.2
6 -9 6 44.8 43.4 9-10 6 0.0 1.1 2-10 3 0.0 17.6
6 -9 5 45.6 44.8 9-10 5 0.0 13.1 2-10 2 49.2 48.1
6 -9 4 0.0 4.4 9-10 4 0.0 17.1 2-10 1 20.4 18.6
6 -9 3 46.3 46.5 9-10 3 30.2 28.9 2-10 0 26.3 28.3
6 -9 2 68.6 67.1 9-10 2 0.0 3.1 -1 10 6 0.0 1.4
6 -9 1 60.8 60.3 9-10 1 22.2 21.1 -1 10 5 0.0 9.3
6 -9 0 0.0 3.3 9-10 0 0.0 14.1 1-10 4 0.0 12.3
-5 9 8 0.0 15.9 8-10 7 0.0 2.7 1-10 3 20.4 21.1
5 -9 7 0.0 8.0 8-10 6 0.0 9.1 1-10 2 0.0 1.0
5 -9 6 0.0 17.7 8-10 5 0.0 1.3 1-10 1 0.0 12.5
5 -9 5 0.0 14.1 8-10 4 27.8 27.8 1-10 0 0.0 13.9
5 -9 4 0.0 7.2 8-10 3 0.0 1.1 10 0 6 0.0 1.2
5 -9 3 0.0 13.2 8-10 2 0.0 19.3 10 0 5 0.0 4.9
5 -9 2 0.0 1.8 8-10 1 0.0 0.6 -10 0 4 0.0 11.3
5 -9 1 0.0 17.0 8-10 0 39.0 39.2 -10 0 3 0.0 6.5
5 -9 0 0.0 14.5 7-10 7 0.0 13.8 -10 0 2 0.0 1.9
-4 9 8 0.0 12.2 7-10 6 0.0 1.6 -10 0 1 0.0 3.1
4 -9 7 0.0 9.3 7-10 5 0.0 2.5 -10 0 0 0.0 11.0
4 -9 6 0.0 7.1 7-10 4 0.0 16.4 10-11 5 0.0 22.7
4 -9 5 0.0 21.4 7-10 3 0.0 24.9 10-11 4 0.0 10.9
4 -9 4 0.0 13.0 7-10 2 0.0 0.9 10-11 3 31.4 33.2
4 -9 3 0.0 16.2 7-10 1 0.0 9.3 10-11 2 31.3 31.2
4 -9 2 0.0 0.7 7-10 0 20.2 21.0 10-11 1 31.1 30.1
4 -9 1 24.6 26.1 -6 10 7 0.0 1.0 10-11 0 0.0 14.6
4 -9 0 0.0 9.6 6-10 6 0.0 18.0 9-11 6 0.0 4.9
3 -9 8 0.0 1.5 6-10 5 0.0 5.4 9-11 5 0.0 6.2
3 -9 7 0.0 8.3 6-10 4 0.0 5.3 9-11 4 0.0 19.4
3 -9 6 39.7 40.6 6-10 3 0.0 4.1 9-11 3 0.0 17.1
3 -9 5 0.0 20.5 6-10 2 0.0 7.0 9-11 2 0.0 8.4
3 -9 4 0.0 2.5 6-10 1 0.0 5.9 9-11 1 0.0 9.2
3 -9 3 0.0 0.4 6-10 0 0.0 9.1 9-11 0 0.0 21.3
3 -9 2 58.0 56.7 5-10 7 0.0 17.2 8-11 6 0.0 11.4
3 -9 1 20.5 20.8 5-10 6 0.0 13.6 8-11 5 0.0 15.3
H K L FO FC H K L FO FC H K L FO FC
8-11 4 0.0 1.7 11-12 4 0.0 17.8 2-12 2 0.0 11.0
8-11 3 0.0 13.6 11-12 3 0.0 1.7 2-12 1 0.0 22.4
8-11 2 0.0 6.2 11-12 2 29.2 28.9 2-12 0 22.0 24.6
8-11 1 0.0 21.0 11-12 1 0.0 1.2 -1 12 4 0.0 5.8
8-11 0 0.0 3.4 11-12 0 27.1 28.2 1-12 3 0.0 7.9
7-11 6 0.0 7.5 10-12 5 0.0 11.8 1-12 2 0.0 3.7
7-11 5 0.0 6.8 10-12 4 0.0 9.7 1-12 1 0.0 8.8
7-11 4 30.9 31.5 10-12 3 0.0 16.9 1-12 0 0.0 1.8
7-11 3 0.0 9.9 10-12 2 0.0 1.7 -12 0 3 0.0 2.6
7-11 2 0.0 11.8 10-12 1 0.0 17.2 -12 0 2 0.0 6.6
7-11 1 0.0 10.3 10-12 0 0.0 11.2 -12 0 1 0.0 4.9
7-11 0 38.4 37.6 9-12 5 0.0 10.8 -12 0 0 0.0 37.6
6-11 6 0.0 8.8 9-12 4 0.0 13.4 12-13 2 0.0 1.2
6-11 5 0.0 5.8 9-12 3 0.0 11.5 12-13 1 0.0 9.4
6-11 4 0.0 8.0 9-12 2 30.5 29.2 12-13 0 0.0 6.2
6-11 3 0.0 16.4 9-12 1 0.0 13.4 11-13 3 0.0 14.3
6-11 2 0.0 6.9 9-12 0 29.6 28.4 11-13 2 0.0 13.9
6-11 1 0.0 9.7 8-12 5 0.0 2.9 11-13 1 0.0 6.7
6-11 0 0.0 3.3 8-12 4 0.0 20.7 11-13 0 21.8 19.8
5-11 6 0.0 12.1 8-12 3 0.0 6.6 10-13 4 0.0 23.0
5-11 5 0.0 27.8 8-12 2 30.5 29.2 10-13 3 0.0 8.3
5-11 4 31.9 30.2 8-12 1 0.0 5.8 10-13 2 0.0 14.7
5-11 3 0.0 20.3 8-12 0 36.2 34.8 10-13 1 0.0 6.1
5-11 2 0.0 19.7 7-12 6 0.0 7.9 10-13 0 0.0 23.0
5-11 1 34.3 32.4 7-12 5 0.0 18.5 9-13 4 0.0 1.5
5-11 0 35.5 34.2 7-12 4 0.0 2.8 9-13 3 0.0 5.7
4-11 6 0.0 2.0 7-12 3 0.0 8.7 9-13 2 0.0 11.2
4-11 5 0.0 7.8 7-12 2 0.0 9.8 9-13 1 0.0 3.4
4-11 4 41.6 41.5 7-12 1 0.0 20.5 9-13 0 0.0 13.0
4-11 3 0.0 0.4 7-12 0 0.0 4.5 8-13 4 0.0 25.7
4-11 2 0.0 0.7 6-12 6 0.0 16.3 8-13 3 0.0 8.4
4-11 1 0.0 7.8 6-12 5 0.0 12.5 8-13 2 0.0 6.8
4-11 0 51.7 50.7 6-12 4 0.0 14.9 8-13 1 0.0 15.4
3-11 6 0.0 26.4 6-12 3 0.0 9.7 8-13 0 31.3 32.3
3-11 5 0.0 4.9 6-12 2 30.8 29.7 7-13 5 0.0 4.9
3-11 4 0.0 5.0 6-12 1 0.0 14.4 7-13 4 0.0 16.9
3-11 3 0.0 4.9 6-12 0 0.0 23.3 7-13 3 0.0 9.1
3-11 2 0.0 15.4 5-12 6 0.0 6.6 7-13 2 0.0 8.7
3-11 1 0.0 5.3 5-12 5 0.0 2.7 7-13 1 0.0 8.4
3-11 0 22.5 22.1 5-12 4 0.0 5.6 7-13 0 0.0 15.3
-2 11 6 0.0 1.0 5-12 3 0.0 3.8 6-13 5 0.0 15.8
2-11 5 0.0 27.7 5-12 2 0.0 2.2 6-13 4 0.0 1.8
2-11 4 0.0 19.4 5-12 1 0.0 2.8 6-13 3 0.0 16.0
2-11 3 0.0 27.1 5-12 0 0.0 3.1 6-13 2 0.0 7.7
2-11 2 0.0 9.2 4-12 5 0.0 20.9 6-13 1 0.0 18.1
2-11 1 33.1 34.0 4-12 4 0.0 10.1 6-13 0 0.0 18.0
2-11 0 0.0 14.2 4-12 3 0.0 11.0 5-13 4 0.0 8.2
-1 11 5 0.0 11.7 4-12 2 0.0 25.0 5-13 3 0.0 0.7
1-11 4 0.0 30.6 4-12 1 0.0 21.6 5-13 2 0.0 28.4
1-11 3 0.0 12.2 4-12 0 0.0 11.9 5-13 1 0.0 1.0
1-11 2 0.0 7.9 3-12 5 0.0 5.5 5-13 0 0.0 13.3
1-11 1 0.0 12.6 3-12 4 0.0 24.0 4-13 4 0.0 3.0
1-11 0 41.8 39.5 3-12 3 0.0 8.1 4-13 3 0.0 8.3
11 0 5 0.0 15.7 3-12 2 0.0 12.7 4-13 2 0.0 12.4
-11 0 4 0.0 2.9 3-12 1 0.0 8.0 4-13 1 0.0 1.9
-11 0 3 0.0 17.7 3-12 0 30.7 31.6 4-13 0 0.0 5.1
-11 0 2 0.0 0.5 -2 12 5 0.0 14.4 3-13 4 0.0 0.6
-11 0 1 0.0 19.1 2-12 4 0.0 20.8 3-13 3 0.0 15.1
-11 0 0 0.0 9.6 2-12 3 0.0 31.5 3-13 2 0.0 5.9
H K L FO FC H K L FO FC H K L FO FC
3-13 1 0.0 16.4 9-14 3 0.0 3.2 6-14 2 0.0 6.3
3-13 0 0.0 7.7 9-14 2 0.0 14.9 6-14 1 0.0 5.4
2-13 3 0.0 10.6 9-14 1 0.0 1.2 6-14 0 0.0 9.2
2-13 2 0.0 33.1 9-14 0 0.0 21.2 5-14 3 0.0 23.2
2-13 1 0.0 12.3 8-14 3 0.0 15.2 5-14 2 0.0 7.2
2-13 0 0.0 0.4 8-14 2 0.0 6.3 5-14 1 0.0 29.5
1-13 2 0.0 20.6 8-14 1 0.0 22.7 5-14 0 0.0 17.9
1-13 1 0.0 0.1 8-14 0 0.0 16.7 4-14 2 0.0 28.2
1-13 0 0.0 12.4 7-14 3 0.0 14.1 4-14 1 0.0 2.0
11-14 1 0.0 9.7 7-14 2 0.0 28.1 4-14 0 0.0 13.2
10-14 2 0.0 23.0 7-14 1 0.0 18.4 3-14 1 0.0 3.2
10-14 1 0.0 2.5 7-14 0 0.0 9.0 3-14 0 0.0 0.2
10-14 0 0.0 6.6 6-14 3 0.0 1.1 0 0 0 0.0 0.0
Rare Earth Elements in Chlorapatite [Ca10(PO4)6(Cl)2]:
Uptake, Site Preference and
Degradation of Monoclinic Structure
Michael E. Fleet, Xioayang Liu
and Yuanming Pan
Deposited Material
Table 5. List of observed and calculated structure factors
(e) P21/b structure of La-chlorapatite
H K L FO FC H K L FO FC H K L FO FC
0 0 2 199.2 210.2 0 -6 1 53.7 52.0 2 6 1 127.2 128.1
0 0 4 371.9 395.0 -4 4 0 33.9 35.2 3-10 1 126.9 127.6
0 0 6 195.2 194.3 2 4 0 34.0 35.1 -3 4 3 165.3 164.0
0 0 8 157.8 138.3 2 -8 0 36.7 38.1 2 2 3 163.7 162.9
0 -1 2 27.4 24.8 -4 6 0 38.8 39.7 1 -6 3 162.1 161.2
-1 1 2 28.4 27.0 3 2 0 36.5 37.3 -3 2 3 131.0 130.5
1 -3 4 32.2 33.3 1 -8 0 37.7 38.4 1 4 3 130.1 129.7
1 -3 2 23.9 26.8 -4 2 0 185.9 177.5 2 -6 3 127.3 127.0
1 1 2 31.6 31.2 1 6 0 184.1 175.9 -5 2 0 126.4 128.4
0 -3 4 38.0 35.5 3 -8 0 182.3 174.1 1 8 0 129.6 131.6
0 -3 2 28.4 28.3 -3 4 2 17.5 14.7 4-10 0 131.3 133.9
-2 1 4 35.9 40.4 2 2 2 19.9 16.6 -5 8 0 187.1 186.6
-2 3 2 37.1 37.1 1 -6 2 20.1 16.9 4 2 0 185.0 184.3
2 -5 4 32.7 39.9 -3 2 2 103.0 100.1 1-10 0 190.1 189.6
2 -5 2 30.2 34.4 1 4 2 101.5 98.5 -4 8 2 104.7 106.2
1 3 4 35.4 41.7 2 -6 2 101.5 98.4 4 0 2 102.1 103.6
1 3 2 35.1 37.3 -4 4 1 12.8 14.0 0 -8 2 103.8 105.2
1 -5 2 37.4 39.4 2 4 1 14.2 15.8 -3 6 3 48.0 47.5
2 1 2 44.2 43.1 2 -8 1 14.9 16.4 3 0 3 50.7 50.5
0 -5 2 35.6 37.6 -4 6 1 14.6 12.6 0 -6 3 50.8 50.1
-3 3 4 33.8 38.8 3 2 1 16.9 14.2 -5 10 0 29.1 27.3
-3 5 2 30.8 29.9 1 -8 1 19.4 16.5 5 0 0 27.9 26.1
-4 5 4 36.4 38.8 -4 2 1 85.9 87.6 0-10 0 27.7 25.8
-5 7 2 35.1 40.1 1 6 1 85.0 86.7 -5 6 2 79.5 80.4
-1 2 0 27.7 28.3 3 -8 1 85.8 87.5 3 4 2 77.6 78.5
1 0 0 27.6 28.3 -3 6 2 81.0 79.5 2-10 2 78.8 79.9
0 -2 0 27.1 27.7 3 0 2 78.8 77.2 -5 4 2 27.1 27.3
-1 2 1 32.4 32.7 0 -6 2 80.4 78.9 2 6 2 29.6 30.1
1 0 1 31.0 31.3 -4 8 0 54.1 55.7 3-10 2 27.3 27.4
0 -2 1 31.6 31.9 4 0 0 57.4 59.1 -1 2 4 46.6 46.2
-2 4 0 8.3 7.8 0 -8 0 54.8 56.3 1 0 4 47.7 47.2
2 0 0 8.5 7.9 -2 2 3 86.6 85.0 0 -2 4 45.4 45.0
0 -4 0 10.4 9.8 1 2 3 84.9 82.9 -5 10 1 68.0 67.7
-2 2 1 26.0 27.1 1 -4 3 84.4 82.7 5 0 1 67.0 66.5
1 2 1 25.4 26.3 -4 8 1 27.0 27.7 0-10 1 66.5 65.8
1 -4 1 24.3 25.2 4 0 1 25.3 26.0 -4 2 3 77.7 78.4
-2 4 1 46.1 45.4 0 -8 1 23.2 23.8 1 6 3 78.4 78.8
2 0 1 45.3 44.8 -2 4 3 55.7 54.0 3 -8 3 78.9 79.4
0 -4 1 46.1 45.5 2 0 3 52.1 50.6 -4 6 3 79.4 78.8
-3 4 0 83.8 87.0 0 -4 3 52.2 50.5 3 2 3 84.1 83.1
2 2 0 83.3 86.5 -4 4 2 231.9 230.6 1 -8 3 82.5 81.8
1 -6 0 85.3 88.5 2 4 2 232.9 231.4 -6 6 0 78.7 77.1
-3 4 1 194.3 196.9 2 -8 2 235.5 234.1 3 6 0 76.4 74.9
2 2 1 195.0 197.4 -5 6 0 29.5 29.9 3-12 0 78.8 77.8
1 -6 1 196.3 198.6 3 4 0 29.9 30.4 -5 8 2 71.3 71.7
-3 2 1 136.1 138.3 2-10 0 30.3 30.5 4 2 2 69.4 69.4
1 4 1 137.7 139.8 -5 4 0 118.0 116.5 1-10 2 72.6 72.9
2 -6 1 137.7 139.7 2 6 0 119.7 118.2 -5 2 2 58.1 59.1
-3 6 0 317.3 309.5 3-10 0 120.3 119.1 1 8 2 58.6 59.8
3 0 0 314.7 307.2 -4 2 2 57.7 56.4 4-10 2 59.0 60.3
0 -6 0 314.9 307.6 1 6 2 57.5 56.2 -6 4 0 115.7 114.9
-2 2 2 220.2 223.2 3 -8 2 58.6 57.2 2 8 0 114.8 114.3
1 2 2 220.6 223.6 -4 6 2 75.6 74.4 4-12 0 116.8 116.0
1 -4 2 221.5 224.5 3 2 2 75.8 74.6 -6 8 0 21.5 21.7
-2 4 2 76.3 75.8 1 -8 2 76.4 75.3 4 4 0 20.4 20.0
2 0 2 75.3 74.7 -5 6 1 104.3 104.4 2-12 0 21.9 21.9
0 -4 2 75.6 75.1 3 4 1 102.4 102.6 -6 6 1 79.4 81.2
-3 6 1 53.4 51.6 2-10 1 103.2 103.5 3 6 1 78.3 79.8
3 0 1 54.5 52.5 -5 4 1 128.7 129.3 3-12 1 77.5 79.0
H K L FO FC H K L FO FC H K L FO FC
-6 8 1 60.3 61.1 0-12 1 28.3 25.8 1 4 5 76.5 73.8
4 4 1 63.4 64.0 -7 8 1 84.6 85.9 2 -6 5 77.3 74.9
2-12 1 60.6 61.2 4 6 1 84.4 85.8 -7 10 2 53.3 56.3
-6 4 1 62.1 62.8 3-14 1 83.2 84.5 5 4 2 52.4 55.0
2 8 1 62.9 63.6 -7 10 0 152.5 150.9 2-14 2 57.7 61.3
4-12 1 65.9 66.6 5 4 0 150.9 149.1 -7 4 2 161.7 161.8
-6 10 0 88.2 88.5 2-14 0 154.3 152.7 2 10 2 163.4 163.8
5 2 0 83.0 83.3 -7 4 0 94.0 92.9 5-14 2 168.4 169.1
1-12 0 87.2 87.4 2 10 0 95.9 95.0 -5 8 4 99.9 100.2
-5 10 2 107.5 106.6 5-14 0 96.9 96.0 4 2 4 98.9 99.1
5 0 2 106.0 104.6 -4 8 4 25.9 27.4 1-10 4 101.3 101.6
0-10 2 107.0 106.1 4 0 4 29.0 30.9 -5 2 4 92.3 93.1
-3 4 4 59.1 58.9 0 -8 4 26.1 27.6 1 8 4 94.9 95.9
2 2 4 57.5 57.2 -7 10 1 66.2 66.1 4-10 4 96.1 97.3
1 -6 4 58.7 58.5 5 4 1 67.3 67.6 -8 8 0 148.1 146.8
-3 2 4 81.7 81.0 2-14 1 65.3 65.3 4 8 0 149.7 148.3
1 4 4 80.1 79.5 -6 6 3 30.3 29.1 4-16 0 158.6 157.6
2 -6 4 81.5 81.1 3 6 3 30.7 30.1 -8 6 0 74.5 71.9
-6 10 1 143.2 143.4 3-12 3 34.9 33.8 3 10 0 80.0 77.6
5 2 1 145.6 145.6 -2 2 5 23.0 26.6 5-16 0 75.2 72.1
1-12 1 145.7 145.9 1 2 5 23.4 26.9 -7 14 0 31.0 30.6
-6 2 1 57.8 60.1 1 -4 5 20.6 23.8 7 0 0 38.1 38.1
1 10 1 59.1 61.3 -6 4 3 97.5 96.6 0-14 0 32.4 32.2
5-12 1 59.1 61.3 2 8 3 93.6 93.2 -7 2 2 68.2 68.9
-5 6 3 101.8 102.3 4-12 3 90.5 90.1 1 12 2 67.6 68.0
3 4 3 105.6 105.6 -6 8 3 55.5 56.8 6-14 2 66.5 66.9
2-10 3 106.6 106.7 4 4 3 54.1 56.0 -5 10 4 36.9 36.4
-5 4 3 34.0 33.9 2-12 3 52.2 53.7 5 0 4 36.7 36.5
2 6 3 35.8 35.4 -2 4 5 38.8 40.9 0-10 4 37.9 37.3
3-10 3 37.2 37.0 2 0 5 37.0 39.3 -8 8 1 65.7 67.5
-6 6 2 98.5 99.6 0 -4 5 39.2 41.8 4 8 1 64.2 66.4
3 6 2 97.6 98.6 -6 12 2 101.5 101.0 4-16 1 67.1 69.1
3-12 2 100.7 102.3 6 0 2 95.9 94.9 -6 12 3 53.5 52.9
-3 6 4 148.7 147.9 0-12 2 98.7 98.3 6 0 3 55.0 54.9
3 0 4 146.4 145.6 -7 12 0 59.9 61.7 0-12 3 57.3 56.7
0 -6 4 147.5 147.0 6 2 0 59.1 60.5 -7 8 3 105.5 106.0
-6 8 2 101.4 102.0 1-14 0 59.4 61.3 4 6 3 108.2 108.2
4 4 2 98.3 98.8 -7 2 0 56.0 57.1 3-14 3 109.1 109.6
2-12 2 97.5 97.9 1 12 0 54.7 56.1 -4 2 5 54.6 53.7
-6 4 2 76.3 75.2 6-14 0 57.3 58.8 1 6 5 52.7 52.6
2 8 2 78.7 77.7 -7 6 2 119.9 120.8 3 -8 5 51.1 50.9
4-12 2 73.8 72.5 3 8 2 122.1 123.1 -6 6 4 49.5 50.2
-5 2 3 33.8 34.1 4-14 2 124.9 126.1 3 6 4 50.5 51.4
1 8 3 34.2 35.3 -5 4 4 74.5 74.1 3-12 4 54.1 55.3
4-10 3 36.0 37.0 2 6 4 78.8 78.2 -8 4 0 30.0 32.3
-6 12 0 44.6 47.9 3-10 4 75.8 75.3 2 12 0 35.1 37.9
6 0 0 38.8 40.7 -7 2 1 36.9 40.6 6-16 0 36.5 39.9
0-12 0 42.8 45.9 1 12 1 39.2 42.9 -6 4 4 98.1 96.2
-7 6 0 85.8 87.3 6-14 1 39.3 43.0 2 8 4 96.7 94.8
3 8 0 82.5 83.9 -6 10 3 118.5 118.4 4-12 4 96.8 95.2
4-14 0 82.1 83.5 5 2 3 117.2 117.7 -6 8 4 89.7 88.9
-7 8 0 30.8 29.4 1-12 3 116.5 116.5 4 4 4 89.3 88.3
4 6 0 29.8 28.5 -6 2 3 38.7 40.9 2-12 4 88.6 88.0
3-14 0 37.1 35.4 1 10 3 37.5 40.0 -7 10 3 77.0 75.4
-6 10 2 97.2 98.6 5-12 3 33.4 35.7 5 4 3 77.7 75.4
5 2 2 97.7 99.5 -3 4 5 115.7 113.7 2-14 3 75.3 73.8
1-12 2 94.5 95.9 2 2 5 117.5 115.4 -4 8 5 28.1 27.4
-6 12 1 29.1 26.4 1 -6 5 118.8 116.9 4 0 5 24.8 24.9
6 0 1 27.6 24.7 -3 2 5 73.7 71.6 0 -8 5 25.4 25.1
H K L FO FC H K L FO FC H K L FO FC
-7 14 2 73.3 74.9 4-18 1 38.5 38.1 1 6 6 86.7 88.6
7 0 2 66.5 67.8 -9 8 1 53.7 54.4 3 -8 6 86.5 88.4
0-14 2 70.9 72.7 4 10 1 51.8 52.5 -9 14 1 37.3 41.0
-8 10 2 34.0 35.2 5-18 1 51.1 51.7 7 4 1 34.9 38.8
5 6 2 35.9 36.9 -8 10 3 37.6 41.9 2-18 1 35.8 39.3
3-16 2 35.6 36.8 5 6 3 34.2 38.4 -9 4 1 31.8 36.3
-8 6 2 107.8 105.1 3-16 3 33.2 37.2 2 14 1 29.4 33.5
3 10 2 104.3 101.8 -7 14 3 37.6 38.5 7-18 1 28.6 32.9
5-16 2 105.0 102.9 7 0 3 45.2 46.2 -6 10 5 102.1 102.0
-6 2 4 24.3 22.8 0-14 3 44.6 45.8 5 2 5 106.1 105.5
1 10 4 25.5 24.0 -5 10 5 49.8 52.7 1-12 5 106.9 106.7
5-12 4 27.6 26.4 5 0 5 46.7 50.0 -6 2 5 34.2 37.6
-6 10 4 108.1 106.3 0-10 5 46.0 48.7 1 10 5 37.0 40.4
5 2 4 101.7 99.9 -8 14 2 82.2 82.9 5-12 5 38.9 42.2
1-12 4 106.9 105.2 7 2 2 76.4 76.6 -9 6 2 107.8 107.7
-1 2 6 38.8 40.0 1-16 2 82.9 83.8 3 12 2 110.5 110.6
1 0 6 37.0 38.6 -7 10 4 78.5 79.5 6-18 2 113.2 114.0
0 -2 6 40.8 42.4 5 4 4 75.7 76.3 -9 12 2 131.1 131.0
-7 2 3 30.9 30.6 2-14 4 78.5 79.7 6 6 2 130.0 129.7
1 12 3 31.3 31.7 -3 6 6 24.8 24.5 3-18 2 133.6 133.9
6-14 3 29.1 29.1 3 0 6 24.8 24.8 -8 16 2 104.8 106.8
-8 14 0 95.8 94.7 0 -6 6 23.2 22.8 8 0 2 106.3 107.9
7 2 0 92.3 90.4 -8 16 0 115.1 114.2 0-16 2 103.9 105.7
1-16 0 98.1 96.7 8 0 0 114.0 113.5 -8 2 3 51.3 54.2
-8 2 0 131.6 127.0 0-16 0 115.9 115.3 1 14 3 49.5 53.0
1 14 0 134.6 130.1 -9 12 1 123.9 124.2 7-16 3 54.8 58.3
7-16 0 136.0 131.8 6 6 1 121.3 121.2 -4 8 6 76.6 74.9
-5 4 5 100.3 99.3 3-18 1 119.5 119.7 4 0 6 76.4 74.6
2 6 5 98.2 97.9 -9 6 1 40.1 45.4 0 -8 6 77.4 75.6
3-10 5 97.6 97.2 3 12 1 38.1 43.1 -8 8 4 122.2 120.1
-5 6 5 58.8 58.6 6-18 1 36.5 41.2 4 8 4 121.4 119.2
3 4 5 55.8 56.0 -6 6 5 57.9 59.0 4-16 4 126.5 124.6
2-10 5 54.6 54.5 3 6 5 57.5 57.6 -9 16 0 36.6 37.3
-2 2 6 123.3 118.2 3-12 5 56.6 57.4 8 2 0 45.9 47.7
1 2 6 124.4 119.0 -6 8 5 29.6 31.1 1-18 0 38.5 39.7
1 -4 6 125.5 120.5 4 4 5 35.1 36.5 -9 2 0 28.8 31.3
-8 12 2 34.1 39.2 2-12 5 32.9 34.4 1 16 0 34.9 37.7
6 4 2 28.5 32.8 -6 4 5 45.6 43.9 8-18 0 31.4 34.4
2-16 2 34.1 39.0 2 8 5 47.5 45.4 -9 4 2 28.8 28.8
-8 14 1 26.8 29.2 4-12 5 52.0 50.0 2 14 2 34.7 34.9
7 2 1 27.5 30.1 -4 4 6 92.9 92.8 7-18 2 29.5 29.4
1-16 1 30.3 32.8 2 4 6 93.1 93.0 -8 6 4 52.2 51.5
-2 4 6 40.5 42.8 2 -8 6 95.3 95.0 3 10 4 56.7 56.0
2 0 6 40.2 42.5 -9 14 0 24.2 30.0 5-16 4 50.8 49.8
0 -4 6 40.7 43.1 7 4 0 28.5 34.5 -5 6 6 62.3 63.4
-6 12 4 33.2 37.2 2-18 0 28.5 35.1 3 4 6 60.9 61.8
6 0 4 28.8 31.9 -9 4 0 50.8 52.2 2-10 6 62.9 64.3
0-12 4 33.0 37.1 2 14 0 49.1 51.0 -10 10 0 69.5 72.1
-7 6 4 61.0 62.8 7-18 0 50.1 52.1 5 10 0 69.8 72.2
3 8 4 56.3 57.6 -7 12 4 44.2 44.5 5-20 0 73.4 77.0
4-14 4 57.0 58.4 6 2 4 47.9 48.3 -7 8 5 45.2 46.4
-7 8 4 34.9 38.4 1-14 4 47.8 48.2 4 6 5 42.3 44.1
4 6 4 33.3 36.7 -7 2 4 83.0 83.7 3-14 5 42.6 44.2
3-14 4 38.2 42.0 1 12 4 78.7 79.3 -10 8 0 34.9 40.7
-3 2 6 28.5 30.6 6-14 4 80.9 81.6 4 12 0 29.1 33.8
1 4 6 32.1 34.4 -4 6 6 28.2 30.0 6-20 0 37.4 43.3
2 -6 6 30.7 33.2 3 2 6 29.9 32.0 -8 4 4 51.0 52.3
-9 10 1 34.8 34.5 1 -8 6 29.3 31.2 2 12 4 58.1 59.7
5 8 1 37.1 36.4 -4 2 6 88.7 90.7 6-16 4 57.5 59.2
H K L FO FC H K L FO FC H K L FO FC
-10 10 1 60.5 64.2 0-16 4 71.6 72.9 4 10 5 41.1 42.8
5 10 1 60.8 64.4 -10 10 3 50.5 53.7 5-18 5 39.1 40.6
5-20 1 60.3 64.1 5 10 3 51.0 53.5 -9 12 5 94.6 91.9
-9 12 3 92.5 93.0 5-20 3 49.1 52.1 6 6 5 92.5 88.7
6 6 3 92.4 93.4 -10 4 2 93.8 89.5 3-18 5 88.4 85.6
3-18 3 95.9 96.4 2 16 2 98.2 94.3 -9 6 5 41.1 42.7
-7 10 5 40.4 39.5 8-20 2 102.6 98.7 3 12 5 40.7 41.2
5 4 5 41.2 40.9 -6 12 6 67.2 65.7 6-18 5 36.7 37.8
2-14 5 42.1 41.2 6 0 6 65.2 63.2 -11 6 2 38.1 36.1
-10 14 0 42.2 44.1 0-12 6 66.0 64.5 3 16 2 31.2 29.5
7 6 0 35.0 36.2 -11 10 0 60.8 63.8 8-22 2 35.1 33.7
3-20 0 42.6 44.3 5 12 0 66.4 69.7 -7 14 6 53.2 54.7
-10 6 0 41.7 38.1 6-22 0 67.0 71.0 7 0 6 47.6 48.6
3 14 0 32.1 29.1 -9 4 4 55.5 52.7 0-14 6 53.9 55.3
7-20 0 32.4 29.5 2 14 4 52.0 49.4 -8 6 6 82.9 82.2
-5 10 6 69.8 68.5 7-18 4 54.3 52.1 3 10 6 79.3 78.4
5 0 6 67.9 66.5 -7 6 6 82.2 79.8 5-16 6 81.5 80.9
0-10 6 66.5 65.1 3 8 6 86.5 84.6 -3 2 8 61.2 66.0
-9 4 3 38.4 40.8 4-14 6 86.8 84.9 1 4 8 60.8 65.9
2 14 3 40.0 42.5 -11 10 1 62.5 63.1 2 -6 8 61.2 66.0
7-18 3 44.9 47.5 5 12 1 65.3 66.0 -3 4 8 44.3 46.8
-10 10 2 80.0 80.3 6-22 1 65.8 66.3 2 2 8 41.5 42.9
5 10 2 77.1 77.3 -10 14 3 45.1 48.9 1 -6 8 42.8 44.7
5-20 2 84.0 84.8 7 6 3 48.6 52.2 -11 4 1 68.2 72.7
-8 14 4 48.8 50.5 3-20 3 50.3 54.2 2 18 1 67.6 71.5
7 2 4 46.6 47.9 -11 14 0 74.6 71.4 9-22 1 69.1 73.2
1-16 4 50.1 51.9 7 8 0 73.3 69.8 -10 18 3 61.3 61.9
-8 2 4 105.9 104.5 4-22 0 82.3 79.4 9 2 3 57.2 58.7
1 14 4 107.3 106.0 -11 8 0 100.9 96.3 1-20 3 58.4 59.7
7-16 4 108.4 107.4 4 14 0 103.3 99.5 -10 2 3 40.7 42.6
-3 4 7 74.4 71.5 7-22 0 110.2 106.3 1 18 3 40.0 42.6
2 2 7 72.9 70.8 -5 6 7 50.4 49.5 9-20 3 37.0 39.3
1 -6 7 73.3 71.0 3 4 7 52.1 50.7 -6 10 7 69.1 67.3
-3 2 7 68.6 67.3 2-10 7 51.4 50.2 5 2 7 66.3 64.8
1 4 7 67.8 66.1 -5 4 7 35.8 37.5 1-12 7 66.2 64.2
2 -6 7 65.4 64.0 2 6 7 35.7 36.5 -3 6 8 64.6 58.5
-6 6 6 56.7 55.1 3-10 7 36.5 37.9 3 0 8 63.5 58.0
3 6 6 56.7 55.6 -7 4 6 40.9 42.9 0 -6 8 63.9 58.4
3-12 6 59.4 58.3 2 10 6 42.1 44.0 -10 16 4 49.7 52.2
-9 18 1 49.0 51.3 5-14 6 44.9 47.2 8 4 4 46.4 48.1
9 0 1 47.6 49.6 -9 18 3 57.2 58.8 2-20 4 50.7 53.6
0-18 1 47.4 49.5 9 0 3 57.3 59.2 -12 14 1 48.1 43.1
-10 16 0 77.6 74.4 0-18 3 58.5 59.6 7 10 1 47.6 43.5
8 4 0 75.4 71.8 -11 6 0 45.2 45.4 5-24 1 44.6 40.0
2-20 0 80.1 77.0 3 16 0 51.4 51.7 -11 2 0 73.4 71.4
-10 4 0 44.9 47.0 8-22 0 45.5 44.9 1 20 0 80.4 79.5
2 16 0 46.5 49.0 -11 10 2 45.0 45.6 10-22 0 78.4 77.2
8-20 0 50.7 54.2 5 12 2 37.5 37.5 -7 8 7 51.8 54.0
-8 8 5 49.3 51.3 6-22 2 38.9 38.8 4 6 7 53.1 54.7
4 8 5 46.9 50.1 -10 4 3 33.0 31.9 3-14 7 54.2 55.9
4-16 5 51.7 54.1 2 16 3 33.9 33.6 -12 16 0 72.3 70.0
-9 18 2 78.9 75.9 8-20 3 35.7 34.9 8 8 0 80.3 77.8
9 0 2 73.9 70.6 -1 2 8 32.8 35.6 4-24 0 70.8 68.0
0-18 2 77.9 75.2 1 0 8 34.6 37.5 -11 20 1 58.5 61.8
-4 2 7 49.0 48.5 0 -2 8 32.3 35.3 10 2 1 59.4 62.4
1 6 7 49.4 48.9 -11 16 1 39.3 38.8 1-22 1 60.7 63.5
3 -8 7 50.5 50.1 8 6 1 42.8 42.3 -10 10 5 4